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Acta Phys. -Chim. Sin.  2011, Vol. 27 Issue (08): 1881-1885    DOI: 10.3866/PKU.WHXB20110827
Preparation of Mesoporous Carbon at Different Temperatures as a Catalyst Support for Direct Methanol Fuel Cells
XU Qun-Jie, LI Jin-Guang, LI Qiao-Xia
Department of Thermal Power and Environmental Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R.China
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Using mesoporous SiO2 (SBA-15) as templates and sugar as a carbon precursor, mesoporous carbon (CMK-3) was prepared at different temperatures (600-900 °C). 20%(w) Pt/CMK-3 was then prepared by impregnation reduction with sodium borohydride as a reductant. Cyclic voltammetry (CV) and chronoamperometry were applied to study the catalytic performance and stability toward methanol oxidation for the as-prepared catalyst. CO striping voltammetry was used to determine its anti-poisoning capability toward CO. The results show that the Pt/CMK-3 prepared at 900 °C had the best catalytic performance and stability toward methanol but at a carbonization temperature of 700 °C the Pt catalyst had a lower stripping potential to CO.

Key wordsMesoporous carbon      Methanol      Pt      CO striping     
Received: 17 March 2011      Published: 23 June 2011
MSC2000:  O643  

The project was supported by the National Natural Science Foundation of China (20873031), Innovation Program of Shanghai Municipal Education Commission, China (10ZZ116), Key Project of Shanghai Committee of Science and Technology, China (09230501400, 10160502300) and Talent Development Fund of Shanghai, China.

Corresponding Authors: XU Qun-Jie     E-mail:
Cite this article:

XU Qun-Jie, LI Jin-Guang, LI Qiao-Xia. Preparation of Mesoporous Carbon at Different Temperatures as a Catalyst Support for Direct Methanol Fuel Cells. Acta Phys. -Chim. Sin., 2011, 27(08): 1881-1885.

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(1) Wang, R. H.; Tian, C. G.;Wang, L.;Wang, B. L.; Zhang, H. B.; Fu, H. G. Chem. Commun. 2009, 3104.
(2) Sun, Z. P.; Zhang, X. G.; Liang, Y. Y.; Tong, H.; Xue, R. L.; Yang, S. D.; Li, H. L. J. Electroanal. Chem. 2009, 633, 1.  
(3) Reshetenko, T. V.; Kim, H. T.; Kweon, H. J. Electrochim. Acta 2008, 53, 3043.  
(4) Zhou, C.;Wang, H.; Peng, F.; Liang, J.; Yu, H.; Yang, J. Langmuir 2009, 25, 7711.  
(5) Liu, H. J.;Wang, X. M.; Cui,W. J.; Dou, Y. Q.; Zhao, D. Y.; Xia, Y. Y. J Mater. Chem. 2010, 20, 4223.  
(6) Xu, Q. J.; Zhou, X. J.; Li, Q. X.; Li, J. G. Acta Phys. -Chim. Sin. 2010, 26, 2135. [徐群杰, 周小金, 李巧霞, 李金光. 物理化学学报, 2010, 26, 2135.]
(7) Salgado, J. R. C.; Alcaide, F.; álvarez, G.; Calvillo, L.; Lázaro, M. J.; Pastor, E. J. Power Sources 2010, 195, 4022.  
(8) Salgado, J. R. C.; Quintana, J. J.; Calvillo, L.; Lazaro, M. J.; Cabot, P. L.; Esparbe, I.; Pastor, E. Phys. Chem. Chem. Phys. 2008, 10, 6796.
(9) Chen, M. H.; Jiang, Y. X.; Chen, S. R.; Huang, R.; Lin, J. L.; Chen, S. P.; Sun, S. G. J. Phys. Chem. C 2010, 114, 19055.  
(10) Ryoo, R.; Joo, S. H.; Jun, S. J. Phys. Chem. B 1999, 103, 7743.  
(11) Shanahan, P. V.; Xu, L. B.; Liang, C. D.;Waje, M.; Dai, S.; Yan, Y. S. J. Power Sources 2008, 185, 423.  
(12) Zhao, D. Y.; Feng, J. L.; Huo, Q. S.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.  
(13) Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.; Ohsuna, T.; Terasaki, O. J. Am. Chem. Soc. 2000, 122, 10712.  
(14) Parsons, R.; VanderNoot, T. J. Electroanal. Chem. 1988, 257, 9.  
(15) Sirk, A. H. C.; Hill, J. M.; Kung, S. K. Y.; Birss, V. I. J. Phys. Chem. B 2004, 108, 689.  
(16) Liu, Z. L.; Ling, X. Y.; Su, X. D.; Lee, J. Y. J. Phys. Chem. B 2004, 108, 8234.  
(17) Howard Fairbrother, D.; Peng, X. D.; Viswanathan, R.; Stair, P. C.; Trenary, M.; Fan, J. Surface Science Letters 1993, 285, L455.
(18) Cui, X. Z.; Cui, F. M.; He, Q. J.; Guo, L. M.; Ruan, M. l.; Shi, J. l. Fuel 2010, 89, 372.  
(19) Lee, E. P.; Peng, Z.; Cate, D. M.; Yang, H.; Campbell, C. T.; Xia, Y. J. Am. Chem. Soc. 2007, 129, 10634.  
(20) Pozio, A.; De Francesco, M.; Cemmi, A.; Cardellini, F.; Giorgi, L. J. Power Sources 2002, 105, 13.  

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