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Acta Phys. Chim. Si.n  2011, Vol. 27 Issue (09): 2178-2184    DOI: 10.3866/PKU.WHXB20110904
CATALYSIS AND SURFACE SCIENCE     
Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation
MIN Shi-Xiong, Lü Gong-Xuan
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
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Abstract  CdS/graphene composite photocatalysts were prepared by photocatalytically reducing graphene oxide with CdS nanoparticles in an aqueous ethanol solution. The structure and photoelectrical properties of the resulted materials were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and transient photocurrent measurements. The photocatalytic activities of the CdS/graphene composites for hydrogen evolution were evaluated under visible light irradiation (λ≥420 nm). The results show that the graphene oxide can be efficiently reduced by the photogenerated electrons of CdS and thus CdS/graphene composite is formed and it shows strong interactions between CdS and graphene. Compared with CdS, the enhanced photocurrent generation and photocatalytic activity toward hydrogen evolution for the CdS/ graphene composite photocatalysts could be attributed to the ability of graphene to capture and transport electrons, and to promote charge separation.

Key wordsCdS      Graphene      Photoelectrical property      Hydrogen generation      Visible light     
Received: 22 April 2011      Published: 04 July 2011
MSC2000:  O643.32  
Fund:  

The project was supported by the National Key Basic Research Program of China (973) (2007CB613305, 2009CB22003), National High-Tech Research and Development Program of China (863) (2009AA05Z117) and Solar Energy Project of Chinese Academy of Sciences (KGCX2-YW-390-1, KGCX2-YW-390-3).

Corresponding Authors: LV Gong-Xuan     E-mail: gxlu@lzb.ac.cn
Cite this article:

MIN Shi-Xiong, Lü Gong-Xuan. Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation. Acta Phys. Chim. Si.n, 2011, 27(09): 2178-2184.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20110904     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2011/V27/I09/2178

(1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Science 2004, 306, 666.  
(2) Geim, A. K.; Novoselov, K. S. Nat. Mat. 2007, 6, 183.  
(3) Stoller, M. D.; Park, S.; Zhu, Y.W.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8, 3498.  
(4) Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.; Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008, 146, 351.  
(5) Geng, X. M.; Niu, L.; Xing, Z. Y.; Song, R. S.; Liu, G. T.; Sun, M. T.; Cheng, G. S.; Zhong, H. J.; Liu, Z. H.; Zhang, Z. J.; Sun, L. F.; Xu, H. X.; Lu, L.; Liu, L.W. Adv . Mater. 2010, 22, 638.  
(6) Lin, Y.; Zhang, K.; Chen,W. F.; Liu, Y. D.; Geng, Z, G.; Zeng, J.; Pan, N.; Yan, L. F.;Wang, X. P.; Hou, J. G. ACS Nano 2010, 4, 3033.  
(7) Guo, C. X.; Yang, H. B.; Sheng, Z. M.; Lu, Z. S.; Song, Q. L.; Li, C. M. Angew . Chem . Int . Edit. 2010, 49, 3014.  
(8) Kim, S. R.; Parvez, M. K.; Chhowalla, M. Chem . Phys . Lett. 2009, 483, 124.  
(9) Zhang, Y. H.; Tang, Z. R.; Fu, X. Z.; Xu, Y. J. ACS Nano 2010, 4, 7303.  
(10) Du, J.; Zhang, H.; Lv, X. J.; Li, Y. M.;Wang, Y.; Li, J. H. ACS Nano 2010, 4, 380.  
(11) Akhavan, O.; Ghaderi, E. J . Phys . Chem . C 2009, 113, 20214.  
(12) Chen, C.; Cai,W. M.; Long, M. C.; Zhou, B. X.;Wu, Y. H.;Wu, D. Y.; Feng, Y. J. ACS Nano 2010, 4, 6425.  
(13) Xu, T. G.; Zhang, L.W.; Cheng, H. Y.; Zhu, Y. F. Appl . Catal . B 2011, 101, 382.  
(14) Lightcap, I. V.; Kosel, T. H., Kamat, P. V. Nano Lett. 2010, 10, 577.  
(15) Ng, Y. H.; Lightcap, I. V.; Goodwin, K.; Matsumura, M.; Kamat, P. V. J . Phys . Chem . Lett. 2010, 1, 2222.  
(16) Kamat, P. V. J . Phys . Chem . Lett. 2010, 1, 520.  
(17) Zhang, X. Y.; Li, H. P.; Cui, X. L.; Lin, Y. H. J . Mater . Chem. 2010, 20, 2801.  
(18) Ng, Y. H.; Iwase, A.; Kudo, A.; Amal, R. J . Phys . Chem . Lett. 2010, 1, 2607.  
(19) Hummers,W. S.; Offeman, R. E. J . Am . Chem . Soc. 1958, 80, 1339.  
(20) Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E. V.; Gorchinskiy, A. D. Chem . Mater. 1999, 11, 771.  
(21) Yan, H. J.; Yang, J. H.; Ma, G. J.;Wu, G. P.; Zong, X.; Lei, Z. B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266, 165.  
(22) Yang, Y. H.; Sun, H. J.; Peng, T. J.; Huang, Q. Acta Phys. -Chim. Sin. 2011, 27, 736. [杨勇辉, 孙红娟, 彭同江, 黄桥. 物理化学学报, 2011, 27, 736.]
(23) Szabó, T.; Berkesi, O.; Forgó, P.; Josepovits, K.; Sanakis, Y.; Petridis, D.; Dékány, I. Chem . Mater. 2006, 18, 2740.  
(24) Lee, D.W.; De Los Santos, V. L.; Seo, J.W.; Felix, L. L.; Bustamante, D. A.; Cole, J. M.; Barnes, C. H.W. J . Phys . Chem . B 2010, 114, 5723.  
(25) Xi, Y. Y.; Zhou, J. Z.; Zhang, Y.; Dong, P.; Cai, C. D.; Huang, H. G.; Lin, Z. H. Chem. J. Chin. Univ. 1999, 20, 937. [席燕燕, 周剑章, 张彦, 董平, 蔡成东, 黄怀国, 林仲华. 高等学校化学学报, 1999, 20, 937.]
(26) Zhang, H. Q.; Chen, K. X.; Jin, Z. S. Chin. J. Appl. Chem. 1999, 14, 98. [张虎勤, 陈开勋, 金振声. 应用化学, 1999, 14, 98.]
(27) Xiong, Z. G.; Zhang, L. L.; Ma, J. Z.; Zhao, X. S. Chem . Commun. 2010, 46, 6099.  
(28) Jin, Z. L.; Lü, G. X. J . Mol . Catal. (China) 2004, 18, 310. [靳治良, 吕功煊. 分子催化, 2004, 18, 310.]
(29) Zhang, X. J.; Tang, C. Q.; Jin, Z. L.; Lü, G. X.; Li, S. B. Acta Phys. -Chim. Sin. 2011, 27, 1143. [张晓杰, 汤长青, 靳治良, 吕功煊, 李树本. 物理化学学报, 2011, 27, 1143.]
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