ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(09)>> 2191-2199     doi: 10.3866/PKU.WHXB20110924         中文摘要
Photocatalytic Degradation of Gaseous 1,2-Dichlorobenzene over TiO2/AC Photocatalysts
LU Sheng-Yong, HUANG Yi-Long, WANG Qiu-Lin, LI Xiao-Dong, YAN Jian-Hua
State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Full text: PDF (909KB) HTML Export: BibTeX | EndNote (RIS)
Using commercially available activated carbon (AC) as a carrier, photocatalysts of activated carbon-supported TiO2 (TiO2/AC) with different specific surface areas and TiO2 loading contents were prepared by the sol-gel method. Nitrogen adsorption, X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used to obtain the performance parameters of the TiO2/AC catalysts. The photocatalytic performance of the TiO2/AC catalysts was studied by using gaseous 1,2-dichlorobenzene. The influence of catalyst dose, specific surface area, and gaseous 1,2-dichlorobenzene concentration on this photodegradation was investigated. The results show that a nano-TiO2 deposit was formed with a particle size of approximately 10 nm. The loading of TiO2 onto the AC with a large specific surface area enhanced the photocatalytic activity of TiO2 photocatalysis with regard to the degradation of gaseous 1,2- dichlorobenzene. We show that TiO2/AC catalysts have a synergetic effect on AC adsorption and TiO2 photocatalysis during the degradation of gaseous 1,2-dichlorobenzene by comparing the photocatalytic performance of a commercial P25 catalyst and TiO2/AC catalysts.

Keywords: Supported TiO2   Activated carbon support   Specific surface area   Photocatalyst   Gaseous 1,2-dichlorobenzene  
Received: 2011-05-10 Accepted: 2011-06-20 Publication Date (Web): 2011-07-15
Corresponding Authors: LU Sheng-Yong Email:

Fund: The project was supported by the National Key Basic Research Program of China (2011CB201500), National Key Technology Research and Development Program of China (2007BAC27B04-4) and NationalWater Pollution Control and Management Technology Major Projects, China (2009ZX07317-003).

Cite this article: LU Sheng-Yong, HUANG Yi-Long, WANG Qiu-Lin, LI Xiao-Dong, YAN Jian-Hua. Photocatalytic Degradation of Gaseous 1,2-Dichlorobenzene over TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2011,27 (09): 2191-2199.    doi: 10.3866/PKU.WHXB20110924
(1) Lu, S. Y.;Wu, D.;Wang, Q. L.; Yan, J. H.; Buekens, A. G.; Cen, K. F. Chemosphere 2011, 82 (9), 1215.
(2) Yu, J. G.; Zhao, X. J.; Zhao, Q. N. Thin Solid Films 2000, 379 (1-2), 7.
(3) Huang, H. H.; Tseng, D. H.; Juang, L. C. Journal of Hazarous Materials 2008, 156 (1-3), 186.
(4) Joung, S. K.; Amemiya, T.; Murabayashi, M.; Itoh, K. Applied Catalysis A: General 2006, 312, 20.  
(5) Liu, S. X.; Chen, X. Y. Acta Phys. -Chim. Sin. 2008, 24, 533. [刘守新, 陈孝云. 物理化学学报, 2008, 24, 533.]
(6) Li, C. P.; Zhao, R. H.; Guo, F.; Chen, J. F. Acta Phys. -Chim. Sin. 2007, 23, 157. [李翠平, 赵瑞红, 郭奋, 陈建峰. 物理化学学报, 2007, 23, 157.]
(7) Xu, X.;Wang, X. J.; Hu, Z. H.; Liu, Y. F.;Wang, C. C.; Zhao, G. H. Acta Phys. -Chim. Sin. 2010, 26, 79. [徐鑫, 王晓静, 胡中华, 刘亚菲, 王晨晨, 赵国华. 物理化学学报, 2010, 26, 79.]
(8) Zhang, X.W.; Lei, L. C. Journal of Hazarous Materials 2008, 153 (1-2), 827.
(9) Wang, X. J.; Hu, Z. H.; Chen, Y. J.; Zhao, G. H.; Liu, Y. F.;Wen, Z. B. Applied Surface Science 2009, 255 (7), 3953.
(10) Chen, Y. J.; Hu, Z. H.;Wang, X. J.; Zhao, G. H.; Liu, Y. F.; Liu, W. Acta Phys. -Chim. Sin. 2008, 24, 1589. [陈玉娟, 胡中华, 王晓静, 赵国华, 刘亚菲, 刘巍. 物理化学学报, 2008, 24, 1589.]
(11) Choi,W.; Hong, S. J.; Chang, Y. S.; Cho, Y. Environmental Science and Technology 2000, 34, 4810.  
(12) Chiang, Y. C.; Chaing, P. C.; Huang, C. P. Carbon 2001, 39 (4), 523.
(13) Matos, J.; Laine, J.; Herrmann, J. M. Applied Catalysis BEnvironmental 1998, 18 (3-4), 281.
(14) Czaplicka, M. Journal of Hazarous Materials 2006, 134 (1-3), 45.
(15) Gratzel, M.; Frank, A. J. Journal of Physical Chemistry 1982, 86 (15), 2964.
(16) Subramani, A. K.; Byrappa, K.; Ananda, S.; Rai, K.; Ranganathaiah, C.; Yoshimura, M. Bulletin of Materials Science 2007, 30 (1), 37.
(17) Huang, Z. H.; Xu, D. P.; Kang, F. Y.; Hao, J. M. New Carbon Material 2004, 19 (3), 229. [黄正宏, 许德平, 康飞宇, 郝吉明. 新型炭材料, 2004, 19 (3), 229.]
1. ZUO Hui-Wen, LU Chun-Hai, REN Yu-Rong, LI Yi, ZHANG Yong-Fan, CHEN Wen-Kai.Pt4 Clusters Supported on Monolayer Graphitic Carbon Nitride Sheets for Oxygen Adsorption: A First-Principles Study[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1183-1190
2. CHANG Xiao-Xia, GONG Jin-Long.On the Importance of Surface Reactions on Semiconductor Photocatalysts for Solar Water Splitting[J]. Acta Phys. -Chim. Sin., 2016,32(1): 2-13
3. DU Xue-Lian, CONG Ye, JIANG Lu, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming, ZHANG Jiang.Preparation and Structure Regulation of Silicon Carbide-Derived Carbon/ Spherical Natural Graphite Composites[J]. Acta Phys. -Chim. Sin., 2015,31(3): 583-588
4. FENG Chang, DENG Xiao-Yan, NI Xiao-Xiao, LI Wei-Bing.Fabrication of Carbon Dots Modified Porous ZnO Nanorods with Enhanced Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2349-2357
5. YANG Wen-Chao, BI Yu-Jing, YANG Bang-Cheng, WANG De-Yu, SHI Si-Qi.Preparation and Electrochemical Characterization of Nano-LiMnPO4[J]. Acta Phys. -Chim. Sin., 2014,30(3): 460-466
6. WEI Yu-Long, BAO Chun-Xiong, GAO Hao, HUANG Huan, YU Tao, ZOU Zhi-Gang.Increasing Specific Surface Area of (110)-Oriented ZnO Nanosheets by Sulfuration-Oxidization Treatment for Photoelectrode Applications[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1975-1980
7. DU Shu-Qing, YUAN Yu-Feng, TU Wei-Xia.Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn2GeO4 Nanoribbons[J]. Acta Phys. -Chim. Sin., 2013,29(09): 2062-2068
8. SHANG Yang, CHEN Yang, SHI Zhan-Bin, ZHANG Dong-Feng, GUO Lin.Synthesis and Visible Light Photocatalytic Activities of Au/Cu2O Heterogeneous Nanospheres[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1819-1826
9. YUAN Wen-Hui, LIU Xiao-Chen, LI Li.Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn2S4 under Visible Light[J]. Acta Phys. -Chim. Sin., 2013,29(01): 151-156
10. WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang.Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2327-2335
11. ZHENG Hua-Rong, ZHANG Jin-Shui, WANG Xin-Chen, FU Xian-Zhi.Modification of Carbon Nitride Photocatalysts by Copolymerization with Diaminomaleonitrile[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2336-2342
12. CHEN Xiao-Yun, LU Dong-Fang, HUANG Jin-Feng, LU Yan-Feng, ZHENG Jian-Qiang.Preparation and Properties of N-F Co-Doped TiO2 Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent[J]. Acta Phys. -Chim. Sin., 2012,28(01): 161-169
13. LI Ben-Xia, WANG Yan-Fen, LIU Tong-Xuan.Adjustable Synthesis and Visible-Light Responsive Photocatalytic Performance of V2O5·xH2O-BiVO4 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2946-2952
14. YU Hong-Bo, JIAWen-Zhi, PU Zhi-Ying, WANG Yue-Juan, LU Ji-Qing, TENG Bo-Tao, LUO Meng-Fei.Preparation and Application of a Cr2O3-α-AlF3 Catalyst with a High Specific Surface Area[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2677-2681
15. CHEN Ke, BAO Zhi-Hao, LIU Dong, ZHU Xiu-Rong, ZHANG Zhi-Hua, ZHOU Bin.Confined Synthesis and Properties of Porous Silicon from Silica Aerogel Templates by Magnesiothermic Reduction[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2719-2725
16. YING Hong, WANG Zhi-Yong, GUO Zheng-Duo, SHI Zu-Jin, YANG Shang-Feng.Reduced Graphene Oxide-Modified Bi2WO6 as an Improved Photocatalyst under Visible Light[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1482-1486
17. ZHENG Hai-Ying, XIE Guan-Qun, WANG Xiao-Xia, JIN Ling-Yun, LUO Meng-Fei.Selective Hydrogenation of Crotonaldehyde over ZrO2-Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3273-3277
18. ZHANG Ai-Ping, ZHANG Jin-Zhi.Syntheses and Activities of Visible-Light-Driven Cu/BiVO4 Composite Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1337-1342
19. GUO Xiang-Yun, JIN Guo-Qiang, WANG Ying-Yong.Preparations and Catalytic Applications of High Surface Area Silicon Carbide[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1143-1150
20. LIU Xiang-Zhi, PIAO Ling-Yu, MAO Li-Juan, HAO Shi-Jie, YANG Lei, JU Si-Ting.Preparation of High Specific Surface Area Nano-Alumina by Vacuum Freeze Drying[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1171-1176
21. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
22. PIAO Ling-Yu, LIU Xiang-Zhi, MAO Li-Juan, JU Si-Ting.Preparation of Nano-Alumina by Reverse Microemulsion Method[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2232-2236
23. LI Fen, XU Xian-Zhi, SONG Hui, XIONG Jin, WU Fei.Impact of Polytetrafluoroethylene Emulsion Binder Pretreatment with Ethanol on the Performance of Gas Diffusion Electrodes[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2205-2210
24. ZHOU Jing-Hong, HAN Wei-Wei, SUI Zhi-Jun, GUO Rong, FANG Xiang-Chen, ZHOU Xing-Gui.Preparation and Characterization of Tri-Lobular Alumina/Carbon Nanofiber Composites[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1455-1460
25. HU Yuan-Fang; LI Yue-Xiang; PENG Shao-Qin; LV Gong-Xuan; LI Shu-Ben.Photocatalytic Properties of Composite of SiO2 and Pt-Cd0.53Zn0.47S Solid Solutions[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2071-2076
26. LI Xiao-Hui, LIU Shou-Xin.Characterization of Visible Light Response N-F Codoped TiO2 Photocatalyst Prepared by Acid Catalyzed Hydrolysis[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2019-2024
27. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
28. LIU Fu-Sheng; JI Ren; WU Min; SUN Yue-Ming.Hydrogen Production from Water Splitting Using Perylene Dye-Sensitized Pt/TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1899-1904
29. LI Hong-Jian; CHEN Gang; LI Zhong-Hua; ZHOU Chao.Synthesis and Photocatalytic Decomposition of Water under Visible Light Irradiation of La2Ti2-xCoxO7 with Pyrochlore Structure[J]. Acta Phys. -Chim. Sin., 2007,23(05): 761-764
30. CHEN Xiao-Yun; LIU Shou-Xin.Preparation and Characterization of S-doped Ti1-xSyO2 Photocatalyst withWide Range Light Response[J]. Acta Phys. -Chim. Sin., 2007,23(05): 701-708
31. FANG Shu-Mei; OU Yan; LIN Jing-Dong; LIAO Dai-Wei.Preparation of Cu/Sr3Ti2O7 and Its Photocatalytic Activity of Watersplitting for Hydrogen Evolution[J]. Acta Phys. -Chim. Sin., 2007,23(04): 601-604
32. TIAN Meng-Kui; JIANG Li; SHANGGUAN Wen-Feng; WANG Shi-Jie2;OUYANG Zi-Yuan.Electronic Structures of the Visible-light Driven Photocatalysts K4Ce2Ta10O30, K4Ce2Nb10O30 and Their Solid Solution Compounds[J]. Acta Phys. -Chim. Sin., 2007,23(04): 466-472
33. GUAN Hong-Bo;WANG Pei;WANG Hui;ZHAO Bi-Ying;ZHU Yue-Xiang;XIE You-Chang.Preparation of Nanometer Magnesia with High Surface Area and Study on the Influencing Factors of the Preparation Process[J]. Acta Phys. -Chim. Sin., 2006,22(07): 804-808
34. CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin.Characterization and Activity of TiO2 /wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 517-522
35. JIANG Qi; LU Xiao-ying; ZHAO Yong; ZHU Xiao-tong; CAI Yu-dong; QIAN Lan.Effects of Activation Conditions on the Specific Surface Area of Activated Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(01): 43-47
36. Zhang Jin-Long;Zhao Wen-Juan;Chen Hai-Jun;Xu Hua-Sheng;Chen Ai-Ping;Anpo Masa-Kazu.Study of Loaded Photocatalysts by Precious Metals on the Photocatalytic Reactivity[J]. Acta Phys. -Chim. Sin., 2004,20(04): 424-427
37. Zeng Li;Wang Chun-Ming;Wei Ji-Ying;Zhu Yue-Xiang;Xie You-Chang.Preparation and Characterization of CrOx/ZrO2 with High Thermal Stability and High Specific Surface Area[J]. Acta Phys. -Chim. Sin., 2004,20(03): 251-255
38. Liu Zhen-Yu;Zheng Jing-Tang;Wang Mao-Zhang;Zhang Bi-Jiang.Study for Nitrogen Adsorption of PAN-based Activated Carbon Fibers[J]. Acta Phys. -Chim. Sin., 2001,17(07): 594-599
39. Zhao Wen-Kuan, Fang You-Ling, Dong Qing-Hua, Wang Yi-Zhong.Preparation of High Photocatalytic Activity Nano-crystalline Titanium Dioxide by High Temperature Thermo-Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 1998,14(05): 424-428
40. He Chong-Min,Zhang Wen-Min,Wang Ren.Surface Area Stability of Aluminas Modified by Rare Earths[J]. Acta Phys. -Chim. Sin., 1996,12(11): 971-975
41. Lv Gong-Xun, Li Shu-Ben, Savinov , E N, Parmon V N.Composite Sulfide Photocatalyst of CuχS·CdS Interface-Modified with Cobalt Phthalocyanine[J]. Acta Phys. -Chim. Sin., 1994,10(09): 790-795
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top