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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(10)>> 2373-2378     doi: 10.3866/PKU.WHXB20111008         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation
RAO Gui-Shi1, CHENG Mei-Qin1, ZHONG Yan1, DENG Xiao-Cong1, YI Fei1, CHEN Zhi-Ren1, ZHONG Qi-Ling1, FAN Feng-Ru2, REN Bin2, TIAN Zhong-Qun2
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
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Pt hollow nanospheres with a particle diameter of 110 nm and a shell thickness of about 5 nm were synthesized in bulk using selenium colloids with a particle diameter of 100 nm as a template. Transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy dispersive X-ray spectrocopy (EDX), and scanning electron microscopy (SEM) were used to determine their morphologies and structures. The electrocatalytic activity of the Pt hollow nanospheres modifying glassy carbon electrode toward methanol oxidation was measured by using methanol as the probe molecule. We show that the multiporous Pt hollow nanospheres composited of atomic clusters have a uniform particle size, good dispersity, a stable structure, a big surface area and good mass transfer performance. Cyclic voltammetry (CV) showed that when the current density of methanol oxidation was 0.10 mA·cm-2 and upon positive scanning the methanol oxidation potential of the Pt hollow nanospheres was around 110 and 64 mV negative than that of the Pt solid nanoparticles and Pt black, respectively. Upon negative scanning the former species was about 51 and 13 mV negative than that of the latter two species, respectively. After 800 segments cyclic voltammetry scanning, upon positive scanning the peak current density of methanol oxidation on the Pt hollow nanospheres was found to be 13 and 15 times as high as that of the Pt solid nanoparticles and Pt black, respectively. Upon negative scanning the former species was about 19 and 38 times as high as that of the two latter species. Our experimental results show that the Pt hollow nanospheres have good electrocatalytic activity and stability toward methanol oxidation.

Keywords: Platinum hollow nanospheres   Selenium sphere template   Preparation   Electrocatalysis   Methanol oxidation  
Received: 2011-03-29 Accepted: 2011-07-18 Publication Date (Web): 2011-08-17
Corresponding Authors: ZHONG Qi-Ling Email: zhqiling@163.com

Fund: The project was supported by the National Natural Science Foundation of China (20663002), Foundation of State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, China (200511) and Natural Science Foundation of Jiangxi Province, China (0620025).

Cite this article: RAO Gui-Shi, CHENG Mei-Qin, ZHONG Yan, DENG Xiao-Cong, YI Fei, CHEN Zhi-Ren, ZHONG Qi-Ling, FAN Feng-Ru, REN Bin, TIAN Zhong-Qun. Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27 (10): 2373-2378.    doi: 10.3866/PKU.WHXB20111008
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63. CHEN Zhao-Yang, ZHAO Feng-Ming, MA Chun-An, QIAO Yun.Ultrasonic-Assisted Preparation of Bimodal Mesoporous HollowGlobal Tungsten Carbide and Its Electrocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2569-2574
64. GAO Guan-Dao, LI Jing, ZHANG Ai-Yong, AN Xiao-Hong, ZHOU Lei.Optimizational Preparation and Mesoporous Material Characteristics of a Novel Biomimetic Photocatalyst and Its Application to the Photocatalytic Degradation of Phenol[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2437-2442
65. XU Qun-Jie, ZHOU Xiao-Jin, LI Qiao-Xia, LI Jin-Guang.Preparation and Electrochemical Properties of Ternary Catalyst PtRuCo/C for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2135-2138
66. XU Jia-Xin, JIANG Yan-Xia, LIAO Hong-Gang, CHEN Sheng-Pei, SUN Shi-Gang.Room Temperature Synthesis of Thorn-Like Pd Nanoparticles and Their Enhanced Electrocatalytic Property for Ethanol Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2139-2143
67. ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2255-2260
68. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
69. YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan.Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1317-1322
70. SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, DING Xiao-Chun.Galvanic Replacement Strategy for a Core-Shell Like Ni-Pt Electrocatalyst with High Pt Utilization[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1219-1224
71. WU Yan-Ni, LIAO Shi-Jun.Shortened Carbon Nanotubes as Supports to Prepare High-Performance Pt/SCNT and PtRu/SCNT Catalysts for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 669-674
72. YANG Xu, ZHOU Hong, SHEN Bin, ZHANG Ling.Synthesis and Optoelectrochemical Properties of ZnS:Co Semiconductor Quantum Dots[J]. Acta Phys. -Chim. Sin., 2010,26(01): 244-248
73. YANG Gai-Xiu, CHEN Ting-Ting, TANG Ya-Wen, LU Tian-Hong.Electrocatalytic Performance of Silicotungstic Acid Modified Carbon Supported Pd Catalyst for Oxidation of Fomic Acid[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2450-2454
74. ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2050-2054
75. YANG Qiu-Yun, ZHU Yuan, TIAN Li, PEI Yan, QIAO Ming-Hua, FAN Kang-Nian.Influence of Au/TiO2 Catalyst Preparation Parameters on the Selective Hydrogenation of Crotonaldehyde[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1853-1860
76. SU Bi-Tao, SUN Jia-Xing, HU Chang-Lin, ZHANG Xiao-Hong, FEI Peng, LEI Zi-Qiang.Preparation and Characterization of Fe3+-Doped TiO2 Photocatalytic Fiber Materials[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1561-1566
77. HUANG Si-Ping, YUAN Zhong-Zhi.Electrocatalytic Performance of Binuclear Co-Mn Phthalocyanine for the Reduction of Thionyl Chloride[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1599-1604
78. HU Mei-Long, XU Sheng-Ming, BAI Chen-Guang, XU Gang, LV Xue-Wei.Preparation of Spherical TiO2 and Kinetics of Its Hydrolysis Process[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1511-1516
79. LI Lei, ZHAN Ying-Ying, CHEN Chong-Qi, SHE Yu-Sheng, LIN Xing-Yi, ZHENG Qi.Effect of CeO2 Support Preparaed with Different Methods on the Activity and Stability of CuO/CeO2 Catalysts for the Water-Gas Shift Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1397-1404
80. CHU Dao-Bao, HE Jian-Guo, HOU Yuan-Yuan, XU Mai, WANG Shu-Xi, WANG Jian, ZHA Long-Wu, ZHANG Xue-Jiao.Electrocatalytic Oxidation of Glyoxal on Ti/NanoTiO2-Pt Modified Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1434-1438
81. SUN Zhi-Quan, LU Hai-Yan, REN Xiu-Bin, HUANG Wei-Min, DONG Yan-Jie, LIN Hai-Bo.Performances of Ti/SnO2-Sb2O5 Anodes Prepared by Brush Coating Thermal Decomposition Method[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1385-1390
82. XU Hai-Qing, LIU Xiu-Ning, WANG Yu-Qiao, WANG Hua-Lin, SUN Yue-Ming.Electro-Catalytic Performance of Composite Oxide Sn-Sb-Mn/Ceramic Particle Electrode System[J]. Acta Phys. -Chim. Sin., 2009,25(05): 840-846
83. YANG Hong-Yan, GUO Pan-Pan, LI Wei-Shan.Electrodeposition Preparation and Activity of CO-Resistant Catalyst Pt-HxWO3 for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(04): 719-723
84. ZHANG Hong-Wei, ZHANG Zheng-Fu, LI Yang, YANG Xi-Hun, LIU Shuo.Structural Effects and Electrooxidation Activity of a Two-Dimensional Multilayer PtRu/PtNd Alloy Nanostructure Thin Film[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2268-2274
85. ZHAO Feng-Ming; SHEN Hai-Ping; CHEN Zhao-Yang; MA Chun-An.Electrocatalytic Reduction of Maleic Acid at Bundles of TiO2 Anodization Film[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2139-2142
86. ZHENG Yi-Xiong; YAO Shi-Bing; ZHOU Shao-Min.Electrooxidation of Ethanol at Ni-B Amorphous Alloy Electrode and Measurements of Kinetic Parameters[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1643-1649
87. GENG Shou-Hua; ZHU Wen-Qing; CHANG Peng-Mei; CHEN Ya-Shao.Preparation of Sm2O3 Nanoparticles in the Media of Reverse Microemulsions[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1609-1614
88. RUAN Xiao-Yun; FANG Yun; FAN Ye.Preparation of Ultrafine Nickel Powders in SDS-PVP Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1513-1518
89. LUO Ming-Hong; LIN Shen; ZHANG Xiao-Feng; LIN Yue-Xu; LIU Jiao-Hua.Preparation and Electrocatalytic Property of Multilayer Films Constructed from Vanadium Substituted Polyoxometalate and
Poly(amidoamine)[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1529-1534

90. WANG Bai-Qi; XIA Chun-Hui; FU Qiang; WANG Peng-Wei; SHAN Xu-Dong; YU Da-Peng.Hydrothermal Preparation and Photoluminescence Property of Co-Doped ZnO Nanorods[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1165-1168
91. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; YU Hong-Ying; FU Hua-Rong.Manganese Oxide Coating Electrodes Prepared by Pulse Anodic Electrodeposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1199-1206
92. ZHOU Jian-Hua; HE Jian-Ping; JI Ya-Jun; ZHAO Gui-Wang; ZHANG Chuan-Xiang; CHEN Xiu; WANG Tao.Influence of Hierarchical Porosity in Carbon Material on Electrocatalytic Property of Supported Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(05): 839-843
93. GAN Ning; WANG Lu-Yan; LI Tian-Hua; WANG Feng; JIANG Qian-Li.Preparaton and Electrocatalytic Activities of Nano Pt/Dimercaptosuccinic Amide Copper Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(05): 915-920
94. HU Xiao-Chun; ZHANG Tong-Lai; QIAO Xiao-Jing; YANG Li; ZHANG Jian-Guo; CUI Yan; ZHANG Jin.Crystal Structure and Thermal Decomposition of 5-Aminotetrazole Trinitrophloroglucinolate[J]. Acta Phys. -Chim. Sin., 2008,24(04): 576-580
95. DENG Zhan-Qiang; QI Jun-Jie; ZHANG Yue; LIAO Qing-Liang; HUANG Yun-Hua; CAO Jia-Wei.Synthesis, Structure and Growth Mechanism of ZnS Nanowires with High Aspect Ratio[J]. Acta Phys. -Chim. Sin., 2008,24(02): 193-196
96. SUN Li-Mei; CAO Dian-Xue; WANG Gui-Ling; LU Yan-Zhuo; ZHANG Mi-Lin.Electrocatalytic Reduction of Hydrogen Peroxide on Pd Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(02): 323-327
97. RAO Gui-Shi; FAN Feng-Ru; WANG Guo-Fu; WU Zhi-Xiang; YI Fei; ZHONG Qi-Ling; REN Bin; TIAN Zhong-Qun.In-situ SERS of Formic Acid Electro-catalytic Oxidation on Aucore@Ptshell/Pt Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(02): 345-349
98. DENG Zheng-Hua; LI Ren-Gui; WANG Lu; DENG Jia-Min; GAO Jian-Dong; MA Zhi-Gang; DU Hong-Chang; SUO Ji-Shuan.Research and Development of Separators for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 90-93
99. LI Guo-Hua; TIAN Wei; TANG Jun-Yan; MA Chun-An.Preparation and Electrocatalytic Property for Methanol Oxidation of WC/CNT Nanocomposite[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1370-1374
100. YANG Hui; SHEN Qian-Hong; GAO Ji-Wei.Morphology Control of Anatase TiO2 Films Prepared at Low Temperature Using 4,4’-isopropylidenediphenol[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1269-1274
101. JIA Ruo-Kun; HE Dong-Liang; DAI Jie; YANG Wen-Sheng; BAI Yu-Bai.Microwave-assistant Fabrication of Y2O3:Er3+ Particles[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1288-1290
102. ZHENG Hai-Tao; LI Yong-Liang; LIANG Jian-Ying; SHEN Pei-Kang.Methanol Oxidation on Pd-based Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 993-996
103. SHE Shi-Xiong; SU Bi-Tao; YANG Yan; MIN Shi-Xiong; LEI Zi-Qiang.Preparation of Functional Polymer Nanomaterial and Its Catalytic Property[J]. Acta Phys. -Chim. Sin., 2007,23(06): 900-904
104. LIU Yong; MENG Ming; YAO Jin-Song; ZHA Yu-Qing.Preparation and Characterization of the Multi-component Mesoporous Mixed Oxide La-Mn-Ce-O Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(05): 641-646
105. LIU Yong; WEI Zi-Dong; CHEN Si-Guo; FENG Yong-Chao; YIN Guang-Zhi; SUN Cai-Xin.PEMFC Electrodes Platinized by Modulated Pulse Current Electrodeposition[J]. Acta Phys. -Chim. Sin., 2007,23(04): 521-525
106. YAN Shan-Shan;WU Lian-Di;CHEN Feng;ZHANG Jin-Long.Low-temperature Preparation and Characterization of TiO2 Thin Films with a Bicrystalline Framework[J]. Acta Phys. -Chim. Sin., 2007,23(03): 414-418
107. MA Wei;SUN Deng-Ming.Electrocatalytical Oxidation of Dopamine and Epinephrine at Poly(L-threonine) Modified Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(03): 332-336
108. SHENG Jiang-Feng;MA Chun-An;ZHANG Cheng;LI Guo-Hua .Preparation of Tungsten Carbide-Supported Nano Platinum Catalyst and Its Electrocatalytic Activity for Hydrogen Evolution[J]. Acta Phys. -Chim. Sin., 2007,23(02): 181-186
109. LÜ Ya-Fen;YIN Ya-Jing;WU Ping;CAI Chen-Xin.Direct Electrochemistry and Bioelectrocatalysis of Myoglobin at a Carbon Nanotube-Modified Electrode[J]. Acta Phys. -Chim. Sin., 2007,23(01): 5-11
110. ZONG Ye;WANG Yu;LIN Chang-Jian .Preparation and Characterization of a High Loading Nano PtRu/C Catalysts in DMFC[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1305-1309
111. SHI Yan-Mao;WU Ping;DU Pan;CAI Chen-Xin.Solid-state Electrochemistry of Gadolinium Hexacyanoferrate Modified Electrode and Its Electrocatalytic Property[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1227-1232
112. PAN Guo-Wei.Silicon Nanowires Produced by SiO-Au Method[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1147-1150
113. HU Ji-Ming;HOU Yan-Yuan;WANG Xiao-Mei;ZHANG Jian-Qing;CAO Chun-Nan .Effect of Calcination Procedure on the Electrocatalytic Activities of Ti/IrO2 Electrodes in Acidic Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1010-1014
114. YANG Bo; YU Gang; HUANG Jun.Electrocatalytic Reductive Dechlorination of 2,4,5-PCB in Aqueous Solution by Palladium-modified Titanium Mesh as Cathode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 306-311
115. CHU Dao-Bao; ZHANG Li-Yan; ZHANG Jin-Hua; ZHANG Xiu-Mei; YIN Xiao-Juan.Heterogeneous Electrocatalytic Reduction of Furfural on Nanocrystalline TiO2-CNT Complex Film Electrode in DMF Solution[J]. Acta Phys. -Chim. Sin., 2006,22(03): 373-377
116. DENG Xiang-Hui;KAN Xian-Wen;YU Yan;ZHANG Wen-Zhi;LIU Hong-Ying;FANG Bin.Electrochemical and Catalytic Properties of Ferrocene/L-cysteine Modified Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1399-1402
117. REN Xiang-Ling; HAN Dong; CHEN Dong; XIA Hai-Long; WANG Dong; TANG Fang-Qiong.Preparation of Rodlike ZnO Particles by Direct Precipitation Reaction[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1419-1421
118. PANG Ying-Cong;GAN Li-Hua;HAO Zhi-Xian;XU Zi-Jie;CHEN Long-Wu.Preparation and Characterization of TiO2/SiO2 Aerogel Microspheres[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1363-1367
119. WANG Zhen-bo; YIN Ge-ping; SHI Peng-fei.The Influence of Three Groups of Pt-Ru/C Catalyst’s Precursors on Its Performance for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1156-1160
120. ZHANG Li-juan; XIA Ding-guo.Electrocatalytic Activity of Ordered Intermetallic PtSb for Ethanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1006-1010
121. MA Chun-an; HUANG Ye; TONG Shao-ping; ZHANG Wei-min.The Catalytic Behavior of Tungsten Carbide for the Electroreduction of p-nitrophenol[J]. Acta Phys. -Chim. Sin., 2005,21(07): 721-724
122. HE Jian; HUANG Yun-hua; ZHANG Yue; GU You-song; JI Zhen; ZHOU Cheng.Synthesis, Growth Mechanism and Microstructure of ZnO Nanocables[J]. Acta Phys. -Chim. Sin., 2005,21(06): 637-640
123. YUAN Juan; XIAO Yao-kun; YU Gang; HU Bo-nian; YE Li-yuan.Pd-Ni Nanowires Prepared by Electrochemical Step-edge Decoration[J]. Acta Phys. -Chim. Sin., 2005,21(06): 602-606
124. ZHANG Li-Juan; XIA Ding-Guo; WANG Zhen-Yao; YUAN Rong; WU Zi-Yu.Intermetallic PtBi as Methanol-tolerant Catalysts for Oxygen Reduction[J]. Acta Phys. -Chim. Sin., 2005,21(03): 287-290
125. BAO Xing-Wang;ZHANG Jin-Long;LIANG Xue-Hai;HUANG Jia-Zhen;ZHANG Li-Zhong.Preparation of TiO2 Thin Films at Low Temperature and Characterization of Their Properties[J]. Acta Phys. -Chim. Sin., 2005,21(01): 69-73
126. QIAO Jun-Juan;MENG Xiang-Min;ZHANG Xiao-Hong;WU Shi-Kang.Nano-wire Preparation of Small Molecular Organic Compound in Solution[J]. Acta Phys. -Chim. Sin., 2005,21(01): 106-109
127. Wang Hai-Shui;Wang Yi-Bing;Xi Shi-Quan.A Review for the Preparation and Structural Characterization of Thin Films of Charge-Transfer Complexes[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1281-1286
128. Lai Yue-Kun;Sun Lan;Zuo Juan;Lin Chang-Jian.Electrochemical Fabrication and Formation Mechanism of TiO2 Nanotube Arrays on Metallic Titanium Surface[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1063-1066
129. Sun Shi-Gang.Enhanced IR Absorption and Abnormal IR Effects of Low-dimensional Nanomaterials[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1017-1023
130. Zhou Ming-Hua;Dai Qi-Zhou;Lei Le-Cheng;Wu Zu-Cheng;Ma Chun-An;Wang Da-Hui.Electrochemical Oxidation for the Degradation of Organic Pollutants on a Novel PbO2 Anode[J]. Acta Phys. -Chim. Sin., 2004,20(08): 871-876
131. Wan Li-Juan;Gao Ying;Wu Bing;Liu Chang-Peng;Xing Wei;Lu Tian-Hong.Cocatalysis of Adsorbed Eu3+ and Ho3+ at Pt-TiO2/C Electrode for Electrooxidaton of Ethanol[J]. Acta Phys. -Chim. Sin., 2004,20(06): 616-620
132. Peng Cheng;Cheng Xuan;Zhang Ying;Chen Ling;Fan Qing-Bai.Comparison of Methanol Electrooxidation on Carbon Supported Pt and PtRu Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(04): 436-439
133. Chu You-Qun;Ma Chun-An;Zhu Ying-Hong.Electrocatalytic Reduction of Oxygen on Carbon Nanotubes Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(03): 331-335
134. Chu Dao-Bao;Wang Feng-Wu;Wei Yi-Jun;Yao Wen-Li;Li Xiao-Hua.Electrocatalytic Activities and Preparation of Nanocrystalline TiO2 -Pt Modified Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(02): 182-185
135. Zhou Hai-Hui;Jiao Shu-Qiang;Chen Jin-Hua;Wei Wan-Zhi;Kuang Ya-Fei.Electrocatalytic Oxidation of Methanol on Nano-fibular Polyaniline Electrode Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 2004,20(01): 9-14
136. Ren Yi-Xia;Chen San-Ping;Gao Sheng-Li.Preparation and Standard Enthalpy of Formation of Zn(Thr) Zn(Thr)Ac2•2H2O[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1085-1088
137. Chen Long-Wu;Gan Li-Hua;Hou Xiu-Hong.Preparation of Silica Aerogels via Non-supercritical Drying and Their Formation Process[J]. Acta Phys. -Chim. Sin., 2003,19(09): 819-823
138. Liang Xin-Yi;Zhang Li-Ming;Ding Hong-Yuan;Qin Yong-Ning.Supported Catalyst LaCoO3/γ-Al2O3 Prepared by Impregnating under Ultrasound[J]. Acta Phys. -Chim. Sin., 2003,19(07): 666-669
139. Mu Shao-Lin;Yang Yi-Fei;Tan Zhi-An.The Electrocatalytic Oxidation of Hydrogen Peroxide on Polyaniline Doped with Ferrocenesulfonic Acid[J]. Acta Phys. -Chim. Sin., 2003,19(07): 588-592
140. Gan Li-Hua;Chen Long-Wu;Zhang Yu-Xing.Preparation of Silica Aerogels by Nonsupercritical Drying[J]. Acta Phys. -Chim. Sin., 2003,19(06): 504-508
141. Chen Wei;Sun Shi-Gang;Si Di;Chen Sheng-Pei.Electrocatalytic Properties of Agglomerates of Pt Nanoparticles in Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2003,19(05): 441-444
142. Li Xu-Guang;Han Fei;Xing Wei;Tang Ya-Wen;Lu Tian-Hong.Influence of Methanol on the Kinetics of Oxygen Reduction on Pt/C and CoPcTc/C[J]. Acta Phys. -Chim. Sin., 2003,19(04): 380-384
143. Zhu Shi-Guo;Tang Ke;Xiang Juan-Juan;Lü Hong-Bin;Li Xiao-Ling;Nie Xin-Min;Zhou Hou-De;Shen Shou-Rong;Li Gui-Yuan.Synthesis and Applications of Florescence-Doped Silica Nanoparticles[J]. Acta Phys. -Chim. Sin., 2003,19(04): 311-314
144. Liang Huan-Zhen;Kim Dong-Jin;Chung Hun S.;Zhang Jie;Yu Ke-Ning;Li Shao-Hua;Li Rui-Xing.Mechanism for the Formation of Flake Silver Powder Synthesized by Chemical Reduction in Ethylene Glycol[J]. Acta Phys. -Chim. Sin., 2003,19(02): 150-153
145. Wei Zi-Dong;Miki Atsushi;Ohmori Tadayoshi;Osawa Masatoshi.Methanol Electroxidation on Upd - Sn Modified Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1120-1124
146. Gao Sheng-Li;Yang Xu-Wu;Chen San-Ping;Ju Zhan-Feng.Synthesis and Standard Enthalpy of Formation of Magnesium L-Threonate[J]. Acta Phys. -Chim. Sin., 2002,18(11): 994-997
147. Zhang Yu-Zhong;Zhao Hong;Yuan Zhuo-Bin.Electrochemical Characteristics and Catalytic Properties of Poly (ferulic acid) Glassy Carbon Modified Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(09): 841-845
148. Liang Xin-Yi;Ma Zhi;Bai Zheng-Chen;Qin Yong-Ning.Properties and Sonochemical Preparation of Nanostructured LaNiO3[J]. Acta Phys. -Chim. Sin., 2002,18(06): 567-571
149. Wang Feng-Bin;Jiang Hui-Jun;Xing Wei;Lu Tian-Hong;Chen Hui-Lan.Electrochemical and Electrocatalytic Properties of Microperoxidase-11 Adsorbed on the Poly-L-Lysine Modified Ag Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(05): 404-408
150. Kong Jing-Lin;Xue Kuan-Hong;Shao Ying;He Chun-Jian;Chen Qiao-Ling.Measurements for the Kinetic Parameters of Electrocatalytic Oxidation of Ethanol at the Nickel Nanowire Electrode[J]. Acta Phys. -Chim. Sin., 2002,18(03): 268-271
151. Wei Ji-Ying;Zhu Yue-Xiang;Xie You-Chang.Preparation of Tin Dioxide Powder with High Specific Surface Area and Stability at High Temperature[J]. Acta Phys. -Chim. Sin., 2001,17(07): 577-581
152. Wang Yu-Ling;Cai Nai-Cai;Huo Yao-Dong;Chen Hao.Electrochemical Oxidation for the Degradation of Aniline on the SnO2/Ti Anode[J]. Acta Phys. -Chim. Sin., 2001,17(07): 609-613
153. Li Dong-Sheng;Lu Gong-Xuan.Synthesis of Conductive Polymer/Semiconductor Nanocomposite Films by Layerbylayer Assembly Techniques[J]. Acta Phys. -Chim. Sin., 2001,17(03): 252-256
154. Xia Sheng-Qing;Chen Sheng-Pei;Sun Shi-Gang.Electrocatalytic Reduction of Oxalic Acid on Platinum Based PbSb Surface Alloy Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(02): 140-143
155. Liu Shu-Qing;Xu Ji-Qing;Sun Hao-Ran;Li Dong-Mei;Zeng Qing-Xin;Song Yu-Jiang.Spectra and Electrocatalytic Reduction of Dioxygen of Mesotetrakis (4Nbenzylpyridyl)porphyrinmetaloxo Cluster Supramolecular Complex[J]. Acta Phys. -Chim. Sin., 2001,17(02): 128-133
156. Qi Hang, Zhu Tao, Liu Zhong-Fan.Gold Nanorods Sol Prepared by Electrolysis[J]. Acta Phys. -Chim. Sin., 2000,16(10): 956-960
157. Yu Jia-Guo, Zhao Xiu-Jian, Zhao Qing-Nan.Preparation and Characterization of TiO2 Nnometer Thin Films by Sol-gel Process[J]. Acta Phys. -Chim. Sin., 2000,16(09): 792-797
158. Yang Qiu-Xia, Gao Gui-Lian, Wang Xue-Lin.Electropolymerized Hemin Film Electrode and its Catalytic Reuction of Oxygen[J]. Acta Phys. -Chim. Sin., 2000,16(08): 741-745
159. Zhang Xin-Tong, Zhuang Jia-Qi, Ren Yu-Lin, Xu Jin-Jie, Wang De-Jun, Bai Yu-Bai, Li Tie-Jin, Yao Jian-Nian.Preparation and Characterization of Quantum-sized ZnO Nanoparticles[J]. Acta Phys. -Chim. Sin., 2000,16(07): 636-642
160. Yang Hui, Huang Zhi-Zhong, Jiang Hui-Jun, Zhou Jia-Hong, Lu Tian-Hong, Wang Feng-Bin, Xing Wei.Electrocatalytic Reduction of O2 and H2O2 at the Glass Carbon Electrode Modified with Microperoxidase-11[J]. Acta Phys. -Chim. Sin., 2000,16(06): 527-532
161. She Pei-Liang, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ethanol on Palladium and Platinum Electrodes Prepared by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2000,16(01): 22-26
162. Bian Guo-Zhu, Han Bo, Fu Yi-Lu.Sol-gel Method Preparation and Characterization of NiMoO4 Ultrafine Particle Catalyst[J]. Acta Phys. -Chim. Sin., 1999,15(11): 1001-1004
163. Xiao Xiu-Feng, Liu Rong-Fang, Zhu Ze-Shan.Ni-W-WC Composite Coating Electrode for Hydrogen Evolution in Alkaline Solution[J]. Acta Phys. -Chim. Sin., 1999,15(08): 742-746
164. Gan Li-Hua, Li Guang-Ming, Yue Tian-Yi, Zhang Ming, Wu Jian-Wen, Chen Long-Wu.Preparation of Fe2O3-SiO2 Aerogels by Supercritical Drying Technique[J]. Acta Phys. -Chim. Sin., 1999,15(07): 588-592
165. Liu Yu, Yang Xiang-Guang, Liu Yu-Min, Wu Yue.Study on the Synthesis of Mixed Oxide La2CuO4 and the Effect on the Catalytic Activity to Catalytic Removal of NO[J]. Acta Phys. -Chim. Sin., 1999,15(06): 506-511
166. Pan Zhan-Chang, Zeng Zhang-Yi, Li Qiong.Catalytic Reduction of Oxygen on Glassy Carbon Electrode Modefied with Dyestuff Direct Light Turquoise GL[J]. Acta Phys. -Chim. Sin., 1999,15(05): 462-466
167. Zhao Wen-Kuan, Fang You-Ling, Dong Qing-Hua, Wang Yi-Zhong.Preparation of High Photocatalytic Activity Nano-crystalline Titanium Dioxide by High Temperature Thermo-Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 1998,14(05): 424-428
168. Si Yong-Chao, Han Zuo-Qing, Chen Yan-Xi.Effect of Catalyst Fabrication Method on the Performance of Oxygen Electrode in PEMFC[J]. Acta Phys. -Chim. Sin., 1998,14(04): 361-364
169. Gan Li-Hua, Yue Tian-Yi, Chen Long-Wu, Li Guang-Ming, Zhu Da-Zhang, Zhou En-Xuan.Studies on the Preparation of Cupric Oxalate Uniform Colloidal Particles by the Method of Microemulsion Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(02): 97-102
170. Zheng Hua-Gui,Li Ya-Dong,Li Cheng-Wei,Zhao Hua-Zhang,Liu Yuan-Hui,Qian Yi-Tai.Prepration of Copper Colloid and it's Absorption Spectrum[J]. Acta Phys. -Chim. Sin., 1997,13(11): 974-977
171. Zheng Dong-Hong,Lu Tian-Hong,Zhang Cun-Zhong,Li Guo-Zheng.Study on the Property of Vitamin B12-Modified Electrode and its Electrocatalysis for the Reduction of Oxygen[J]. Acta Phys. -Chim. Sin., 1997,13(09): 797-801
172. Wang Yuan-Yang,Wu Dong,Fan Yan-Zhen,Sun Yu-Han,Chen Song-Ying.Mechanistic Study on the Effects of Preparation Parameters on the Structure Property of ZrO2 Aerogels[J]. Acta Phys. -Chim. Sin., 1997,13(07): 580-585
173. Yang Hui,Li Chang-Zhi,Lu Tian-Hong,Xue Kuan-Hong,Sun Shi-Gang,Lu Guo-Qiang,Chen.Electrocatalytic Oxidation of Methanol on Polythionine Film Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 1997,13(06): 542-547
174. Li Jing,Wang Jing-Chun,Dou Bo-Sheng,Wu Yue.Preparation of Cu-Co Catalyst for Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 1997,13(03): 278-282
175. Gan Li-Hua,Yue Tian-Yi,Chen Long-Wu,Li Guang-Ming,Zhou Bin.Preparation and Characterization of β-FeOOH Aerogels[J]. Acta Phys. -Chim. Sin., 1997,13(01): 48-51
176. Hou Wen-Hua,Wang Nan-Ping,Yan Qi-Hao.Preparation of Layered Ferrititanate Pillared by Silica[J]. Acta Phys. -Chim. Sin., 1996,12(10): 933-936
177. Chen Wei-Xiang,Tang Zhi-Yuan,Liu Zhao-Lin,Guo He-Tong.Chemical Activation of Metal Hydride Electrodes[J]. Acta Phys. -Chim. Sin., 1996,12(08): 704-708
178. Yang Hui,Lu Tian-Hong,Xue Kuan-Hong,Zhou Yi-Ming,Sun Shi-Gang,Chen Sheng-Pei.Cyclic Voltammetry and in-situ FTIR Spectroscopic Studies on Electro-oxidation of Formaldehyde at a Gold Electrode[J]. Acta Phys. -Chim. Sin., 1996,12(06): 527-531
179. Wei Yu,Liu Xiao-Lin,Zheng Xue-Zhong.Preparation of Ultrafine Monodispersed α-Fe2O3 Hydrosol[J]. Acta Phys. -Chim. Sin., 1996,12(06): 551-554
180. Shen Yong,Zhang Zong-Tao,Zhao Bin,Zhu Yu-Zhen,Hu Li-Ming.Preparation of Spherical Ultrafine Nickel Powder by Chemical Reduction in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1996,12(05): 460-463
181. He Qing-Lin, Hu Chang-Wen, Zhang Yun-Feng, Zhang Ji-Yu, Wang En-Bo, Wang Feng-Zhi, Zhao Yong-Zhi.Study on the Synthesis,Characterization and Catalysis of Pillared Anion Clay(V)[J]. Acta Phys. -Chim. Sin., 1996,12(04): 368-371
182. Wang Wen-Tao,Zhong Bang-Ke.The Preparation and Characterization of Alumina Membranes Supported by Porous Titanium Plate[J]. Acta Phys. -Chim. Sin., 1996,12(01): 85-90
183. Jin Shi-Xiong,Wang Lan,Sun Feng.Electrocatalytic Effect of Oxygen by Anodic Evlution Ag(I) Co(II) and Ni(II) Ions[J]. Acta Phys. -Chim. Sin., 1995,11(07): 654-658
184. Fan Ye-Mei, Xu Heng-Yong, Shi Ke-Ying, Shang Yong-Chen, Ye Qing, Xu Guo-Lin, Huang Ren-Cai, Guo Wei-Song, Zhou Pei-Heng.A New Route for the Chemical Utilization of CO2[J]. Acta Phys. -Chim. Sin., 1995,11(03): 283-286
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188. Li Can, Zhang Hui, Wang Kai-Li, Xin Qin.FT-IR Emission Spectroscopic Studies of Surface Structure of V2O5/TiO2 Catalyst[J]. Acta Phys. -Chim. Sin., 1994,10(01): 33-37
189. Zhang Ai-Qiang; Chen Yan-Zhen; Tian Zhao-Wu.The Electrocatalytic Effect of POAP-Cu+ Film Electrode[J]. Acta Phys. -Chim. Sin., 1993,9(04): 523-527
190. Wu Zhong-Da; Li Song-Mei; Lin Wen-Lian; Ding Xiao-Ji.The Electrocatalytic Activity of Nickel and Molybdenum Implanted in Mild Steel Substrates[J]. Acta Phys. -Chim. Sin., 1992,8(03): 401-404
191. Dong Shao-Jun; Song Fa-Yi.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Film Modified Glassy Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 1992,8(01): 82-86
192. Wang Guang-Xin; Zhao Chang-Gui; Chen Zong-Qi; Zhang Yu-Ling.Study on Monodispersed Colloid I. Formation of Monodispersed Colloidal Yttrium Compound System[J]. Acta Phys. -Chim. Sin., 1991,7(06): 655-661
193. Wang Guang-Xin; Chen Zong-Qi; Zhang Yu-Ling; Yin Shi-Gang.Study on Monodispersed Colloid III. Preparation of Monodispersed Particles of Fe2O3[J]. Acta Phys. -Chim. Sin., 1991,7(06): 699-702
194. JIANG Tao, TIAN Jie, WANG Ning, PENG Shu-Ming, LI Mei, HAN Wei, ZHANG Mi-Lin.Study on Preparation of Mg-Zr Alloy in Molten KCl-K2ZrF6-KF-ZrO2[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
195. XU Han, TONG Ye-Xiang, LI Gao-Ren.Controllable Synthesis of Pd Nanocrystals for Applications in Fuel Cells[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
196. QIU Wei-Tao, HUANG Yong-Chao, WANG Zi-Long, XIAO Shuang, JI Hong-Bing, TONG Ye-Xiang.Effective Strategies towards High-Performance Photoanode for Photoelectrochemical Water Splitting[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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