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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(11)>> 2651-2658     doi: 10.3866/PKU.WHXB20111018         中文摘要
CATALYSIS AND SURFACE SCIENCE
Dimethyl Ether Synthesis from CO2 Hydrogenation over CuO-TiO2-ZrO2/HZSM-5 Catalysts
WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong
Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China
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A series of CuO-TiO2-ZrO2 mixed oxides with different CuO mass fractions (50%-80%) were prepared by co-precipitation and characterized by X-ray diffraction (XRD), N2 physisorption, temperatureprogrammed reduction of hydrogen (H2-TPR), temperature-programmed desorption of carbon dioxide (CO2-TPD) and hydrogen (H2-TPD), and reactive N2O adsorption techniques. The prepared CuO-TiO2-ZrO2 samples were mixed physically with HZSM-5 zeolite to synthesize dimethyl ether (DME) from CO2 hydrogenation in a fixed bed reactor at 250°C, 3.0 MPa, gas hourly space velocity (GHSV) of 1500 mL·g-1· h-1, and volume ratio of 2.8 for H2 to CO2. We found that the conversion of CO2 increased with an increase in CuO content, reached a maximum at a CuO content of 70% and then decreased. The selectivity of DME increased with an increase in CuO content initially and remained essentially constant when the CuO content was ≥70%. Thus, the yield of DME reached a maximum of 13.2% at 70% CuO content. The productivity of the oxygenated compounds (including methanol and DME) on the CuO-TiO2-ZrO2/HZSM-5 catalysts is closely related to the metallic copper surface area.

Keywords: Hydrogenation of CO2   Dimethyl ether   CuO-TiO2-ZrO2 mixed oxide   Zeolite HZSM-5   Bifunctional catalyst  
Received: 2011-05-09 Accepted: 2011-07-18 Publication Date (Web): 2011-08-19
Corresponding Authors: MAO Dong-Sen Email: dsmao@sit.edu.cn

Fund: The project was supported by the Science and Technology Commission of Shanghai Municipality, China (08520513600), Leading Academic Discipline Project of Shanghai Education Committee, China (J51503) and Shanghai Special Fund for Outstanding Young Teachers, China (yyy10078).

Cite this article: WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong. Dimethyl Ether Synthesis from CO2 Hydrogenation over CuO-TiO2-ZrO2/HZSM-5 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27 (11): 2651-2658.    doi: 10.3866/PKU.WHXB20111018
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