温度对多硫电解质及量子点敏化太阳能电池性能的影响

doi:10.3866/PKU.WHXB20111023

Abstract

Abstract: We studied the influence of temperature on the conductivity of a polysulfide electrolyte and the photovoltaic performance of quantum dot sensitized solar cells by electrochemical methods. The results indicate that the conductivity of the electrolyte increases and the diffusion impedance of the polysulfide ions in the electrolyte decreases with an increase in the temperature. Moreover, the photoelectric conversion efficiency of the quantum dot sensitized solar cells decreases when the temperature increases. This phenomenon is mainly caused by a more serious back reaction and the desorption of quantum dots at higher temperatures.

Key words: Quantum dot sensitized solar cell, Temperature, Electrolyte, Conductivity, Impedance

MSC2000:

O646

SHI Ji-Fu, WAN Qing-Cui, XU Gang, XU Xue-Qing, FAN Ye. Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells[J].Acta Phys. -Chim. Sin., 2011, 27(10): 2360-2366.

References

(1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.

(2) Liao, J. Y.; Lei, B. X.;Wang, Y. F.; Liu, J. M.; Su, C. Y.; Kuang, D. B. Chem. Eur. J. 2011, 17, 1352.

(3) Pei, J.; Liang, M.; Chen, J.; Tao, Z. L.; Xu,W. Acta Phys. -Chim. Sin. 2008, 24, 1950. [裴娟, 梁茂, 陈军, 陶占良, 许炜. 物理化学学报, 2008, 24, 1950.]

(4) Shi, J. F.; Peng, S. J.; Pei, J.; Liang, Y. L.; Cheng, F. Y.; Chen, J. ACS Appl. Mater. Interfaces 2009, 1, 944.

(5) Tao, L.; Yang, Y. Z.; Shi, C.W.;Wu, Y. C.;Wu, X. Y. Acta Phys. -Chim. Sin. 2010, 26, 578. [桃李, 杨燕珍, 史成武, 吴玉程, 吴小燕. 物理化学学报, 2010, 26, 578.]
(6) Shi, J. F.; Xu, G.; Miao, L.; Xu, X. Q. Acta Phys. -Chim. Sin. 2011, 27, 1287. [史继富, 徐刚, 苗蕾, 徐雪青. 物理化学学报, 2011, 27, 1287.]
(7) Yu, Q.;Wang, Y.; Yi, Z.; Zu, N.; Zhang, J.; Zhang, M.;Wang, P. ACS Nano 2010, 4, 6032.

(8) Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Nazeeruddin, M. K.; Sekiguchi, T.; Grätzel, M. Nat. Mater. 2003, 2, 402.

(9) Ruhle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11, 2290.

(10) Zhang, Q.; Zhang, Y.; Huang, S.; Huang, X.; Luo, Y.; Meng, Q.; Li, D. Electrochem. Commun. 2010, 12, 327.

(11) Lee, H.; Yum, J. H.; Leventis, H. C.; Zakeeruddin, S. M.; Haque, S; A.; Chen, P.; Seok, S.; Grätzel, M. Nazeeruddin, M. K. J. Phys. Chem. C 2008, 112, 11600.

(12) Gonzalez-Pedro, V.; Xu, X.; Mora-Sero, I.; Bisquert, J. ACS Nano 2010, 4, 5783.

(13) Lee, H. J.;Wang, M.; Chen, P.; Gamelin, D. R.; Zakeeruddin, S. M.; Grätzel, M.; Nazeeruddin, M. K. Nano Lett. 2009, 9, 4221.

(14) Shi, J. F.; Peng, B.; Pei, J.; Peng, S. J.; Chen, J. J. Power Sources 2009, 193, 878.

(15) Yu, Z.; Zhang, Q.; Qin, D.; Luo, Y.; Li, D.; Shen, Q.; Toyoda, T.; Meng, Q. Electrochem. Commun. 2010, 12, 1776.
(16) Wu, J.; Hao, S.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Fang, L.; Yin, S.; Sato, T. Adv. Funct. Mater. 2007, 17, 2645.

(17) Fan, S. Q.; Fang, B.; Kim, J. H.; Jeong, B.; Kim, C.; Yu, J. S.; Ko, J. Langmuir 2010, 26, 13644.

(18) Deng, M.; Huang, S.; Zhang, Q.; Li, D.; Luo, Y.; Shen, Q.; Toyoda, T.; Meng, Q. Chem. Lett. 2010, 39, 1168.

(19) Berginc, M.; Krasovec, U. O.; Jankovec, M. Topic, M. Sol. Energy Mater. Sol. Cells 2007, 91, 821.

(20) Huang, S. Y.; Schlichthorl, G.; Nozik, A. J.; Grätzel, M.; Frank, A. J. J. Phys. Chem. B 1997, 101, 2576.

(21) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.; Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010, 26, 2927.]
(22) Hore, S.; Kern, R. Appl. Phys. Lett. 2005, 87, 263504.

(23) Shi, J.; Liang, J.; Peng, S.; Xu,W.; Pei, J.; Chen, J. Solid State Sci. 2009, 11, 433.

(24) Zhang, Z.; Zakeeruddin, S. M.; O'Regan, B. C.; Humphry- Baker, R.; Grätzel, M. J. Phys. Chem. B 2005, 109, 21818.

(25) Wang, Q.; Ito, S.; Grätzel, M.; Fabregat-Santiago, F.; Mora- Sero, I.; Bisquert, J.; Bessho, T. B.; Imai, H. J. Phys. Chem. B 2006, 110, 25210.

(26) Shalom, M.; Dor, S.; Ruhle, S.; Grinis, L.; Zaban, A. J. Phys. Chem. C 2009, 113, 3895.

(27) Samadpour1, M.; Irajizad, A.; Taghavinia, N.; Molaei, M. J. Phys. D-Appl. Phys. 2011, 44, 045103.

[1]	Zhenjie CHENG, Yayun MAO, Qingyu DONG, Feng JIN, Yanbin SHEN, Liwei CHEN. Fluoroethylene Carbonate as an Additive for Sodium-Ion Batteries: Effect on the Sodium Cathode [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 868-875.
[2]	Yizhou WANG,Yehong LIU,Shouhong XU,Honglai LIU. Design and Synthesis of Multi-Responsive Copolymers for Drug Carrier [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 876-884.
[3]	Dong CHEN,Xinyang YUE,Xunlu LI,Xiaojing WU,Yongning ZHOU. Research Progress of Cathode Materials for Lithium-Selenium Batteries [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 667-683.
[4]	Kang YANG,Xiaorui SHUAI,Huachao YANG,Jianhua YAN,Kefa CEN. Electrochemical Performance of Activated Graphene Powder Supercapacitors Using a Room Temperature Ionic Liquid Electrolyte [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 755-765.
[5]	Wangying SHI, Chuan JIA, Yongliang ZHANG, Zewei Lü, Minfang HAN. Differentiation and Decomposition of Solid Oxide Fuel Cell Electrochemical Impedance Spectra [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 509-516.
[6]	Kangjie LYU,Yanqiu PENG,Li XIAO,Juntao LU,Lin ZHUANG. Atomistic Understanding of the Peculiar Dissolution Behavior of Alkaline Polymer Electrolytes in Alcohol/Water Mixed Solvents [J]. Acta Phys. -Chim. Sin., 2019, 35(4): 378-384.
[7]	Junjiang GUO,Shiyun TANG,Rui LI,Ningxin TAN. Mechanism Construction and Simulation for Combustion of Large Hydrocarbon Fuels Applied in Wide Temperature Range [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 182-192.
[8]	Fan ZHANG,Zhe REN,Shenghui ZHONG,Mingfa YAO,Zhijun PENG. Role of Low-Temperature Fuel Chemistry on Turbulent Flame Propagation [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 158-166.
[9]	Hui LI,Shuangyu LIU,Huiming WANG,Bo WANG,Peng SHENG,Li XU,Guangyao ZHAO,Huitao BAI,Xin CHEN,Yuliang CAO,Zhongxue CHEN. Improved Sodium Storage Performance of Na_0.44MnO₂ Cathode at a High Temperature by Al₂O₃ Coating [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1357-1364.
[10]	Feng JIN,Jing LI,Chenji HU,Houcai DONG,Peng CHEN,Yanbin SHEN,Liwei CHEN. High Performance Solid-state Battery with Integrated Cathode and Electrolyte [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1399-1403.
[11]	Paul W. AYERS,Mel LEVY. Levy Constrained Search in Fock Space: An Alternative Approach to Noninteger Electron Number [J]. Acta Phys. -Chim. Sin., 2018, 34(6): 625-630.
[12]	Shuang LIU,Lianyi SHAO,Xuejing ZHANG,Zhanliang TAO,Jun CHEN. Advances in Electrode Materials for Aqueous Rechargeable Sodium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2018, 34(6): 581-597.
[13]	Marco FRANCO-PÉREZ,José L. GÁZQUEZ,W. AYERS Paul,Alberto VELA. Thermodynamic Dual Descriptor [J]. Acta Phys. -Chim. Sin., 2018, 34(6): 683-391.
[14]	Ágnes NAGY. Phase Space View of Ensembles of Excited States [J]. Acta Phys. -Chim. Sin., 2018, 34(5): 492-496.
[15]	Qiang MA,Yongsheng HU,Hong LI,Liquan CHEN,Xuejie HUANG,Zhibin ZHOU. An Sodium Bis (trifluoromethanesulfonyl) imide-based Polymer Electrolyte for Solid-State Sodium Batteries [J]. Acta Phys. -Chim. Sin., 2018, 34(2): 213-218.

Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10