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Acta Phys. Chim. Sin.  2011, Vol. 27 Issue (11): 2587-2592    DOI: 10.3866/PKU.WHXB20111124
ELECTROCHEMISTRY AND NEW ENERGY     
Calcination Temperature Effects on the Electrochemical Performance of Li2MnSiO4/C Cathode Material for Lithium Ion Batteries
WEI Yi1, WANG Li-Juan1, YAN Ji1, SHA Ou1, TANG Zhi-Yuan1, MA Li2
1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China;
2. McNair Technology Company, Limited, Dongguan 523800, Guangdong Province, P. R. China
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Abstract  As a new potential cathode material for lithium ion batteries, Li2MnSiO4/C was synthesized by a solution method. The thermal behavior of the precursor for Li2MnSiO4/C was measured by thermogravimetric (TG) analysis and the range of calcination temperatures from 600 to 800°C was determined. X-ray powder diffraction (XRD) patterns indicated that all the Li2MnSiO4/C samples crystallized in an orthorhombic structure with space group Pmn21. The morphology and particle size of the samples were also characterized by scanning electron microscopy (SEM). The effects of calcination temperature on the electrochemical performance of Li2MnSiO4/C were studied using galvanostatic charge-discharge measurements at various current densities. The results showed that the sample prepared at 700°C exhibited a much higher coulombic efficiency and better cyclic performance than the other samples.

Key words： Lithium ion battery      Cathode material      Li2MnSiO4      Solution method      Calcination temperature     
Received: 04 July 2011      Published: 13 September 2011
MSC2000:  O646  
  TM912.9  
Fund:  

The project was supported by the National Natural Science Foundation of China (20973124).
Corresponding Authors: WEI Yi     E-mail: weiyi_777@163.com
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WEI Yi
WANG Li-Juan
YAN Ji
SHA Ou
TANG Zhi-Yuan
MA Li
Cite this article:

WEI Yi, WANG Li-Juan, YAN Ji, SHA Ou, TANG Zhi-Yuan, MA Li. Calcination Temperature Effects on the Electrochemical Performance of Li2MnSiO4/C Cathode Material for Lithium Ion Batteries. Acta Phys. Chim. Sin., 2011, 27(11): 2587-2592.

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http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20111124     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2011/V27/I11/2587

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