Please wait a minute...
Acta Phys. Chim. Sin.  2011, Vol. 27 Issue (12): 2767-2772    DOI: 10.3866/PKU.WHXB20112767
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY     
Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield
DONG Zhi-Long, DING Wei, LIU Kun, ZHANG Zhi-Wei, QU Guang-Miao, YU Tao
Chemistry and Chemical Engineering School, Northeast University of Petroleum, Daqing 163318,Helongjiang Province, P. R. China
Download:   PDF(1674KB) Export: BibTeX | EndNote (RIS)      

Abstract  Three tetradecyl aryl sulfonates of high purity were synthesized. Their static adsorption performance on oil sand from the Daqing oilfield was studied and the influence of adsorption time, adsorption temperature, concentrations of sulfonate, NaCl, NaOH, and n-butyl alcohol on the efficiency of adsorption were investigated. The experimental results show that with an increase in the concentrations of the sulfonates the adsorption capacity initially increased and then remained constant. The adsorption capacity increased with the addition of NaCl and NaOH while it decreased with the addition of n-butyl alcohol and the increase of temperature. In the structural isomer, upon moving the aryl from the terminal to the center of the long alkyl chain, the adsorption capacity decreased and the impact of the additive was reduced. Thermodynamic results show that the adsorption of tetradecyl aryl sulfonates onto oil sand could be well described by the Langmuir isotherm. The constants of each equation were calculated from the experimental data and indicated the characteristics of oil sand adsorption. The dynamic results showed that the adsorption capacity changing with time as described by the Elovich equation.

Key wordsAlkyl aryl sulfonate      Additive      Solid/liquid adsorption      Adsorption thermodynamics      Adsorption dynamics     
Received: 19 July 2011      Published: 20 September 2011
MSC2000:  O642  
  O643  
Fund:  

The project was supported by the National Major Technology Special Fund of China (2008ZX05011), National Key Basic Research Program of China (973) (2005CB221300), and Graduate Student Innovation Research Project of Heilongjiang Province, China (YJSCX2008-044HLJ).

Corresponding Authors: DING Wei     E-mail: dingwei40@126.com
Cite this article:

DONG Zhi-Long, DING Wei, LIU Kun, ZHANG Zhi-Wei, QU Guang-Miao, YU Tao. Adsorption Performance of Tetradecyl Aryl Sulfonates on Oil Sand from the Daqing Oilfield. Acta Phys. Chim. Sin., 2011, 27(12): 2767-2772.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20112767     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2011/V27/I12/2767

(1) Yu, F.; Fan,W. Y.; Duan, Y. Z.; Li, S. P.; Nan, G. Z. Oilfield Chemistry 2007, 24, 347. [于芳, 范维玉, 段友智, 李水平, 南国枝. 油田化学, 2007, 24, 347.]
(2) Jiang, X. M.; Zhang, L.; An, J. Y.; Zhao, S.; Yu, J. Y. Acta Phys. - Chim. Sin. 2005, 21, 1426. [姜小明, 张路, 安静仪, 赵濉, 俞稼镛. 物理化学学报, 2005, 21, 1426.]
(3) Zhao, Y. Synthesis and Interfacial Properties of Pure Alkylbenzenesulfonates. Ph. D. Dissertation, Dalian University of Technology, Dalian, 2006. [赵宇. 系列烷基苯磺酸盐纯化合物的合成及界面性能的研究[D]. 大连: 大连理工大学, 2006.]
(4) Yu, T.; Liu, H. J.; Ding,W.; Qu, G. M.; Guo, S. J. Chinese Journal of Applied Chemistry 2008, 25, 1107. [于涛, 刘红娟, 丁伟, 曲广淼, 国胜娟. 应用化学, 2008, 25, 1107.]
(5) Wang, L.; Gong, Q. T.;Wang, D. X.; Zhao, S.; An, J. Y.; Yu, J. Y. Petrochem Ican Tech 2004, 33, 104. [王琳, 宫清涛, 王东贤, 赵濉, 安静仪, 俞稼镛. 石油化工, 2004, 33, 104.]
(6) Gong, Q. T.; Jiang, X. M.;Wang, L.; Zhao, J. S.;Wang, D. X.; Zhang, L.; Zhao, S.; Yu, J. Y. Petrochem Ican Tech 2005, 34, 122. [宫清涛, 姜小明, 王琳, 赵金生, 王东贤, 张路, 赵濉, 俞稼镛. 石油化工, 2005, 34, 122.]
(7) Jiang, X. M.; Xu, Z. C.; Shi, F. Q.; An, J. Y.; Zhao, S.; Yu, J. Y. Fine Chemistry 2004, 21, 808. [姜小明, 徐志成, 史福强, 安静仪, 赵濉, 俞稼镛. 精细化工, 2004, 21, 808.]
(8) Zhang, S. B.; Qi, H. M.; Zhang, H.; Qiao,W. H.; Li, Z. S. Journal of Dalian Nationalities University 2005, 7, 15. [张树彪, 齐会勉, 张晗, 乔卫红, 李宗石. 大连民族学院学报, 2005, 7, 15.]
(9) Li, Z. G.; Qiao,W. H.; Li, Z. S.;Wang, X. N. Journal of Dalian University of Technology 2002, 42, 531. [李志刚, 乔卫红, 李宗石, 王秀娜. 大连理工大学学报, 2002, 42, 531.]
(10) Doe, P. H.; Emary, M. E. L.;Wade,W. H. J. Am. Oil Chem. Soc. 1978, 55, 505.  
(11) Dahanayake, M. D.; Coben, A.W.; Rosen, M. J. Phys. Chem. 1986, 90, 2413.  
(12) Hevalier, Y. Current Opinion in Colloids and Interface Science 2002, 7, 3.  
(13) Keisuke, M.; Yoshikiyo, M. Current Opinion in Colloid and Interface Science 2003, 8, 227.  
(14) Aksenenko, E. V.; Makievski, A. V.; Miller, R.; Fainerman, V. B. Colloids and Surfaces A: Physicochemical and Engineering Aspects 1998, 143, 311.  
(15) Shan, C. L.; Zong, L. P.; Xu, Y. S.; Chen, J.;Wu, X. L. China Foreign Energy 2006, 11, 45. [单存龙, 宗丽平, 徐艳姝, 陈劼, 伍晓林. 中外能源, 2006, 11, 45.]
(16) Peltonen, L. J.; Yliruusi, J. J. Colloids Interface Sci. 2000, 227, 1.  
(17) Lorenzo, M. D.; Vinagre, H. M.; Joseph, D. D. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2001, 180, 121.  
(18) Ding,W.;Wang, R.; Yu, T.; Qu, G. M.;Wen, H. Y. Acta Petrolet. Sin. 2007, 23, 75. [丁伟, 王瑞, 于涛, 曲广淼, 温海飞. 石油学报, 2007, 23, 75.]
(19) Qu, G. M.; Cheng, J. C.; Ding,W.; Yu, T.; Li, G. Q. Acta Petrolet Sinica (Petroleum Processing Section) 2010, 26, 208. [曲广淼, 程杰成, 丁伟, 于涛, 李国桥. 石油学报 (石油加工), 2010, 26, 208.]
(20) Cross, J. Marcal Dekker 1998, 45.
(21) Shinoda, K.; Masakata, H. J. Phys. Chem. 1973, 77, 378.  
(22) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; Beijing, 2003. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003.]
(23) Yu, T.; Tong,W.; Su, Y. B.; Ding,W. Chinese Journal of Applied Chemistry 2010, 27, 466. [于涛, 童维, 宿雅彬, 丁伟. 应用化学, 2010, 27, 466.]
(24) Zhao, G. Y.; Qin, Q.; Zhou, Q. Environmental Science and Technology 2006, 29, 84. [赵桂瑜, 秦琴, 周琪. 环境科学与技术, 2006, 29, 84.]
(25) Tu, C. Tropical and Subtropical Soil Science 1994, 3, 175. [涂从. 热带亚热带土壤科学, 1994, 3, 175.]
(26) Yao, T. Y.; Yao, F. Y.; Li, J. S. Oil Drilling & Production Technology 2008, 30, 82. [姚同玉, 姚风英, 李继山. 石油钻采工艺, 2008, 30, 82.]
(27) Xiao, J. X.; Zhao, Z. G. Application Principle of Surfactant; Chemical Industry Press: Beijing, 2002; pp 93-97. [肖进新, 赵振国. 表面活性剂应用原理. 北京: 化学工业出版社, 2002: 93-97.]
(28) Wang, P. Y.; Xu, B. C.;Wang, J. The Synthes, Property and Use of Surfactants; Chemical Industry Press: Beijing, 2007; pp 174-179. [王培义, 徐宝才, 王军. 表面活性剂——合成· 性能·应用. 北京: 化学工业出版社, 2007: 174-179.]
[1] ZHOU Ping-Ping, XI Xi, SONG Bing-Lei, PEI Xiao-Mei, CUI Zheng-Gang. Rheological Behavior of Trimeric Anionic Surfactant/Cationic Additive Mixed Systems[J]. Acta Phys. Chim. Sin., 2016, 32(9): 2309-2317.
[2] WANG Jing-Lun, YAN Xiao-Dan, YONG Tian-Qiao, ZHANG Ling-Zhi. Nitrile-Modified 2,5-Di-tert-butyl-hydroquinones as Redox Shuttle Overcharge Additives for Lithium-Ion Batteries[J]. Acta Phys. Chim. Sin., 2016, 32(9): 2293-2300.
[3] ZHENG Xiao-Di, ZHU Yan-Li, DONG Rui, JIAO Qing-Jie. Effect of Alkyl Imidazole Ionic Liquids CnmimCl (n= 4, 6, 8) on CL-20 Recrystallization[J]. Acta Phys. Chim. Sin., 2016, 32(8): 1950-1959.
[4] WAN Zhao-Min, WEI Xing, PENG Wei, YIN Zheng-Lei, XIAO Li, ZHUANG Lin. On-Line Electrochemical Transmission Infrared Spectroscopic Study of Pb2+ Enhanced C―C Bond Breaking in the Ethanol Oxidation Reaction[J]. Acta Phys. Chim. Sin., 2016, 32(6): 1467-1472.
[5] LI Yan, CHAI Jin-Ling. Dilational Viscoelasticity of Imidazole-Based Surface Active Ionic Liquids at the Air/Water Interface[J]. Acta Phys. Chim. Sin., 2016, 32(5): 1227-1235.
[6] LI Jing-Zhe, KONG Fan-Tai, WU Guo-Hua, HUANG Yang, CHEN Wang-Chao, DAI Song-Yuan. TiO2/Dye/Electrolyte Interface Modification for Dye-Sensitized Solar Cells[J]. Acta Phys. Chim. Sin., 2013, 29(09): 1851-1864.
[7] DUAN Bao-Gen, LI Yan, LI Jie, CHENG Tie-Jun, WANG Ren-Xiao. An Empirical Additive Model for Aqueous Solubility Computation: Success and Limitations[J]. Acta Phys. Chim. Sin., 2012, 28(10): 2249-2257.
[8] REN Chun-Yan, LU Hai, JIA Ming, ZHANG Zhi-An, LAI Yan-Qing, LI Jie. Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries[J]. Acta Phys. Chim. Sin., 2012, 28(09): 2091-2096.
[9] LI Tian-Tian, WANG Chao-Yang, XING Li-Dan, LI Wei-Shan, PENG Bin, XU Meng-Qing, GU Feng-Long, HU She-Jun. Reaction Mechanism of 1,4-Dimethoxy Benzene as an Overcharge Protection Additive[J]. Acta Phys. Chim. Sin., 2012, 28(04): 818-822.
[10] JIA Fei, WANG Zhou-Cheng. Electrochemical Study on Electroless Nickel Plating Using Sodium Borohydride as the Reductant[J]. Acta Phys. Chim. Sin., 2011, 27(03): 633-640.
[11] LIU Guo-Yu, GU Da-Ming, LIU Hai-Yan, DING Wei, LI Zhong, CHENG Jie-Cheng. Free Energy Perturbation of Enthalpy-Entropy Compensation for the Micellization of Alkyl Aryl Sulfonates[J]. Acta Phys. Chim. Sin., 2011, 27(01): 11-16.
[12] ZHANG Qi-Bo, HUA Yi-Xin. Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Phys. Chim. Sin., 2011, 27(01): 149-155.
[13] WU Li-Na, HUANG Yu-Dong, WANG Zhi-Jiang, LIU Li. Preparation and Characterization of Monolithic Silica Fiber/Al2O3 Aerogel Composites by Non-Supercritical Drying[J]. Acta Phys. Chim. Sin., 2010, 26(06): 1717-1721.
[14] YU Tao, LI Zhong, DING Wei, LUO Shi-Qiong, LUAN Huo-Xin, TONG Wei, QU Guang-Miao, LI An-Jun, CHENG Jie-Cheng. Enthalpy-Entropy Compensation of Micellization of Alkyl Aryl Sulfonates in Aqueous Solutions[J]. Acta Phys. Chim. Sin., 2010, 26(03): 638-642.
[15] DING Wei, LIU Guo-Yu, YU Tao, QU Guang-Miao, CHENG Jie-Cheng, WU Jun-Zheng. Molecular Dynamics Simulations and Free Energy Perturbation Calculations of Alkyl Aryl Sulfonate[J]. Acta Phys. Chim. Sin., 2010, 26(03): 727-734.