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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(12)>> 2946-2952     doi: 10.3866/PKU.WHXB20112946         中文摘要
PHYSICAL CHEMISTRY OF MATERIALS
Adjustable Synthesis and Visible-Light Responsive Photocatalytic Performance of V2O5·xH2O-BiVO4 Nanocomposites
LI Ben-Xia, WANG Yan-Fen, LIU Tong-Xuan
College of Materials Science and Engineering, Anhui University of Science & Technology, Huainan 232001,Anhui Province, P. R. China
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V2O5·xH2O-BiVO4 composite photocatalysts were synthesized using monoclinic V2O5·xH2O nanowires as a precursor under mild conditions. To determine the synthesis-time-dependent phase content, morphology, and photocatalytic performance of the products, three typical V2O5·xH2O-BiVO4 samples were obtained at 6, 12, and 24 h. These samples were investigated using X-ray diffraction, fieldemission scanning electron microscopy, UV-visible diffusion reflectance spectroscopy, and a photocatalytic property test. The results indicate that the V2O5·xH2O-BiVO4 nanocomposites are composed of V2O5·xH2O nanowires and BiVO4 nanocrystals. As the reaction time was extended, the amount of V2O5·xH2O nanowires decreased gradually and that of the BiVO4 nanocrystals increased in the composite. The results of photocatalytic performance indicated that the V2O5·xH2O-BiVO4 composite photocatalysts exhibited enhanced photocatalytic efficiency for the degradation of methylene blue (MB) under visible-light irradiation (λ>400 nm). The V2O5·xH2O-BiVO4 sample obtained at 12 h exhibited the best photocatalytic activity, which is probably because of the appropriate proportion of components and the special microstructures of the sample that were favorable for a synergistic effect between the two photocatalysis mechanisms involving the excitation of the semiconductor and the excitation of the dye, respectively.

Keywords: Composite photocatalyst   Chemical synthesis   Characterization   Photodegradation   Organic dye  
Received: 2011-07-15 Accepted: 2011-10-10 Publication Date (Web): 2011-10-18
Corresponding Authors: LI Ben-Xia Email: bxli@aust.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21001003), Natural Science Foundation of Anhui Province, China (10040606Q15), and Natural Science Research for Colleges and Universities of Anhui Province, China (KJ2010A101).

Cite this article: LI Ben-Xia, WANG Yan-Fen, LIU Tong-Xuan. Adjustable Synthesis and Visible-Light Responsive Photocatalytic Performance of V2O5·xH2O-BiVO4 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2011,27 (12): 2946-2952.    doi: 10.3866/PKU.WHXB20112946
(1) Fujishima, A.; Honda, K. Nature 1972, 238, 37.  
(2) Lu, F.; Cai,W. P.; Zhang, Y. G. Adv. Funct. Mater. 2008, 18, 1047.  
(3) Yang, D. J.; Liu, H.W.; Zheng, Z. F.; Yuan, Y.; Zhao, J. C.; Waclawik, E. R.; Ke, X. B.; Zhu, H. Y. J. Am. Chem. Soc. 2009, 131, 17885.  
(4) Li, B. X.;Wang, Y. F. J. Phys. Chem. C 2010, 114, 890.  
(5) Song, X. M.;Wu, J. M.; Tang, M. Z.; Qi, B.; Yan, M. J. Phys. Chem. C 2008, 112, 19484.  
(6) Zhang, H.; Chen, G.; Bahnemann, D.W. J. Mater. Chem. 2009, 19, 5089.  
(7) Shang, M.;Wang,W. Z.; Sun, S. M.; Ren, J.; Zhou, L.; Zhang, L. J. Phys. Chem. C 2009, 113, 20228.  
(8) Zhang, A. P.; Zhang, J. Z. Acta Phys. -Chim. Sin. 2010, 26, 1337. [张爱平, 张进治. 物理化学学报, 2010, 26, 1337.]
(9) Xiao, X.; Zhang,W. D. J. Mater. Chem. 2010, 20, 5866.  
(10) Shang, M.;Wang,W. Z.; Xu, H. L. Crystal Growth Des. 2009, 9, 991.  
(11) Wu, J.; Duan, F.; Zheng, Y.; Xie, Y. J. Phys. Chem. C 2007, 111, 12866.  
(12) Ma, D. K.; Huang, S. M.; Chen,W. X.; Hu, S.W.; Shi, F. F.; Fan, K. L. J. Phys. Chem. C 2009, 113, 4369.  
(13) Bi, J. H.;Wu, L.; Li, H.; Li, Z. H.;Wang X. X.; Fu, X. Z. Acta Mater. 2007, 55, 4699.  
(14) Zheng, Y.;Wu, J.; Duan, F.; Xie, Y. Chem. Lett. 2007, 36, 520.  
(15) Shang, M.;Wang,W. Z.; Ren, J.; Sun, S. M.; Zhang, L. CrystEngComm 2010, 12, 1754.  
(16) Ruan, Q. J.; Zhang,W. D. J. Phys. Chem. C 2009, 113, 4168.  
(17) Shang, M.;Wang,W. Z.; Zhou, L.; Sun, S. M.; Yin,W. Z. J. Hazard. Mater. 2009, 172, 338.  
(18) Jiang, H.Y.; Dai, G. X.; Meng, X.; Ji, K. M.; Zhang, L.; Deng, J. G. Appl. Catal. B-Environ. 2011, 105, 326.  
(19) Iwase, A.; Kudo, A. J. Mater. Chem. 2010, 20, 7536.  
(20) Wang, D. E.; Jiang, H. F.; Zong, X.; Xu, Q.; Ma, Y.; Li, G. L.; Li, C. Chem. Eur. J. 2011, 17, 1275.  
(21) Zhang, X.; Udawa, K.; Liu, Z.; Nishimoto, S.; Xu, C.; Lu, Y.; Sakai, H.; Ave, M.; Marakoi, T.; Kujishima, A. J. Photochem. Photobiol. A 2009, 202, 39.  
(22) Yang, D.; Liu, H.; Zheng, Z.; Yuan, Y.; Zhao, J.;Waclawik, E. R.; Ke, X.; Zhu, H. J. Am. Chem. Soc. 2009, 131, 17885.  
(23) Du, H.;Wang, S.; Liu, L. L.; Liu, Z. X.; Li, Z.; Lu, N.; Liu, F. S. Acta Phys. -Chim. Sin. 2010, 26, 2726. [杜欢, 王晟, 刘恋恋, 刘忠祥, 李振, 卢南, 刘福生. 物理化学学报, 2010, 26, 2726.]
(24) Chen, P.; Gu, L.; Cao, X. B. CrystEngComm 2010, 12, 3950.  
(25) Shang, M.;Wang,W. Z.; Zhang, L.; Sun, S. M.;Wang, L.; Zhou, L. J. Phys. Chem. C 2009, 113, 14727.  
(26) Lu, M. Y.; Song, J. H.; Lu, M. P., Lee, C. Y.; Chen, L. J.;Wang, Z. L. ACS Nano 2009, 3, 357.  
(27) Xu, F.; Volkov, V.; Zhu, Y. M.; Bai, H. Y.; Rea, A.; Valappil, N. V.; Su,W.; Gao, X. Y.; Kuskovsky, I. L.; Matsui, H. J. Phys. Chem. C 2009, 113, 19419.  
(28) Su, J.; Zou, X. X.; Li, G. D.;Wei, X.; Yan, C.Wang, Y. N.; Zhao, J.; Zhou, L. J.; Chen, J. S. J. Phys. Chem. C 2011, 115, 8064.  
(29) Wang, Z. Y.; Huang, B. B.; Dai, Y.; Qin, X. Y.; Zhang, X. Y.; Wang, P.; Liu, H. X.; Yu, J. X. J. Phys. Chem. C 2009, 113, 4612.  
(30) Zou, C.W.; Rao, Y. F.; Alyamani, A.; Chu,W.; Chen, M. J.; Patterson, D. A.; Emanuelsson, E. A. C.; Gao,W. Langmuir 2010, 26, 11615.  
(31) Lalitha, K.; Sadanandam, G.; Kumari, V. D.; Subrahmanyam, M.; Sreedhar, B.; Hebalkar, N. Y. J. Phys. Chem. C 2010, 114, 22181.  
(32) Ma, T. Y.; Yuan, Z. Y.; Cao, J. L. Eur. J. Inorg. Chem. 2010, 716.
(33) Jiang, H. Q.; Nagai, M.; Kobayashi, K. J. Alloy. Compd. 2009, 479, 821.  
(34) Su, J. Z.; Guo, L. J.; Bao, N. Z.; Grimes, C. A. Nano Lett. 2011, 11, 1928.  
(35) Guan, M. L.; Ma, D. K.; Hu, S.W.; Chen, Y. J.; Huang, S. M. Inorg. Chem. 2011, 50, 800.  
(36) Li, B. X.; Xu, Y.; Rong, G. X.; Jing, M.; Xie, Y. Nanotechnology 2006, 17, 2560.  
(37) Zhao, Y.; Xie, Y.; Zhu, X.; Yan, S.;Wang, S. X. Chem. Eur. J. 2008, 14, 1601.  
(38) Fujishima, A.; Zhang, X. T.; Tryk, D. A. Surf. Sci. Rep. 2008, 63, 515.  
(39) Wu, Y.; Tamaki, T.; Volotinen, T.; Belova, L.; Rao, K. V. J. Phys. Chem. Lett. 2010, 1, 89.  
(40) Zhai, X. H.; Long, H. J.; Dong, J. Z.; Cao, Y. A. Acta Phys.-Chim. Sin. 2010, 26, 663. [翟晓辉, 龙绘锦, 董江舟, 曹亚安, 物理化学学报, 2010, 26, 663.]
(41) Li, B. J.; Cao, H. Q. J. Mater. Chem. 2011, 21, 3346.  
(42) Clifford, J. N.; Palomares, E.; Nazeeruddin, M. K.; Thampi, R.; Grätzel, M.; Durrant, J. R. J. Am. Chem. Soc. 2004, 126, 5670.  
(43) Kamat, P. V. Chem. Rev. 1993, 93, 267.  
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68. Fu Jin-Zhou, Liu Yue-Ying, Gu Ping-Ying, Shang Ding-Liang, Lin Zhong-Yu, Yao Bing-Xin, Weng Sheng-Zhou.Spectroscopic Charcterization on the Biosorption and Bioreduction of Ag(I) by Lactobacillus sp.A09*[J]. Acta Phys. -Chim. Sin., 2000,16(09): 779-782
69. Chen Hong-Shan, Niu Jian-Zhong, Xia Chun-Gu, Li Shu-Ben.Raman Spectroscopy Characterization of Na-W-Mn/SiO2 Catalyst for Oxidative Coupling of Methane[J]. Acta Phys. -Chim. Sin., 2000,16(06): 543-546
70. Zhang Xiao-Xin, Ma Ai-Zeng, Mu Xu-Hong, Min En-Ze, Huang Xiao-Xi, Wang Rong.Structure Characterization of the Supported Amorphous Ni-B/SiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2000,16(02): 180-183
71. Liu Xing-Yun, Liu Hui, Li Xuan-Wen, Xu Xiao-Jie.Quantitative Characterization of "Hydroxyl Nests"Concentration for the Dealuminated Y Zeolite[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1094-1097
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73. Ji Shi-Shan, Weng Duan, Tan Rui-Qin, Zhang Zhi-Qiang, Cao Li-Li.Studies of SO2 Poisoning Mechanism on La-Ce-Cu Catalysts[J]. Acta Phys. -Chim. Sin., 1998,14(06): 527-533
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75. Zhao Wen-Kuan, Fang You-Ling, Dong Qing-Hua, Wang Yi-Zhong.Preparation of High Photocatalytic Activity Nano-crystalline Titanium Dioxide by High Temperature Thermo-Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 1998,14(05): 424-428
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78. Gan Li-Hua,Yue Tian-Yi,Chen Long-Wu,Li Guang-Ming,Zhou Bin.Preparation and Characterization of β-FeOOH Aerogels[J]. Acta Phys. -Chim. Sin., 1997,13(01): 48-51
79. Cao Nai-Zhen,Shen Wan-Ci,Wen Shi-Zhu.The Characterization of the Porous Structure of Expanded Graphite[J]. Acta Phys. -Chim. Sin., 1996,12(08): 766-768
80. Li Xu-Yuan,Zhao Ke-Hao,Meng Yan-fa,Tu Wei-Xia.Purification and Characterization of β-galactosidases from Cicer Arietinum[J]. Acta Phys. -Chim. Sin., 1996,12(07): 629-634
81. Gao Zi, Hua Wei-Ming, Chen Jian-Min, Tang Yi.Characterization of Solid Superacidity by Pentane Isomerization Reaction[J]. Acta Phys. -Chim. Sin., 1994,10(10): 897-902
82. Gao Zi, Chen Jian-Min, Tang Yi, Hua Wei-Ming.Characterization of Solid Superacidity by Butane Isomerization Reaction at Ambient Temperature[J]. Acta Phys. -Chim. Sin., 1994,10(08): 698-703
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84. Hou Wen-Hua, Yan Qi-Jie, Fu Xian-Cai.Preparation and Characterization of Alumina-pillared Layered Titanate with a High Interlayer Spacing[J]. Acta Phys. -Chim. Sin., 1994,10(02): 100-102
85. Li Can, Zhang Hui, Wang Kai-Li, Xin Qin.FT-IR Emission Spectroscopic Studies of Surface Structure of V2O5/TiO2 Catalyst[J]. Acta Phys. -Chim. Sin., 1994,10(01): 33-37
86. Bian Guo-Zhu; Jiang Ming; Fu Yi-Lu; Ji Ming-Rong.Chemical States and Composition of the Surface Species of K-MoO3/γ-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 1993,9(05): 650-656
87. Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Chen Heng-Rong; Xin Qin; Wang Guo-Jia.Preparation,Characterization and Surface Acidity of Hydroxy-Fe-Al Pillared Clays Containing Mixed-matal Complexes(II)[J]. Acta Phys. -Chim. Sin., 1993,9(03): 336-344
88. Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia.Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)[J]. Acta Phys. -Chim. Sin., 1993,9(02): 193-199
89. Li Can; Wang Kai-Li; Xin Qin; Guo Xie-Xian.FT-IR Emission Spectroscopic Studies of Metal Oxide Catalysyts I. Experimental Respects and Reduction-reoxidation of Molybdenum Trioxide[J]. Acta Phys. -Chim. Sin., 1992,8(01): 64-69
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