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Acta Phys. Chim. Sin.  2012, Vol. 28 Issue (01): 195-200    DOI: 10.3866/PKU.WHXB201228195
CATALYSIS AND SURFACE SCIENCE     
Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance
YANG Yong-Hong1,2, LI Fen-Fen1,3, YANG Cheng1, ZHANG Wen-Yu3, WU Jin-Hu1
1. Key Laboratory of Biofuels, Qindao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Shandong Polytechnic University, Jinan 250353, P. R. China
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Abstract  Various amine-functionalized CO2 adsorbents were prepared by incorporating tetraethylenepenthamine (TEPA) onto SBA-15(P) by controlling the impregnation method and its process. The materials were characterized using X-ray diffraction (XRD), N2-adsorption, elemental analysis, and Fourier transform infrared (FTIR) techniques. Their adsorptive capacities were determined by CO2-temperature programmed desorption (TPD). The results indicate that the dynamic impregnation process using a TEPA ethanol solution was successful in loading TEPA into the channels of SBA-15(P). Moreover, bonding formation between the highly dispersed TEPA and SBA-15(P) was facilitated to CO2 adsorption/desorption. Therefore, a binding mechanism is proposed. The -NH2 group of TEPA forms hydrogen bonds with -OH and C-O-C groups on SBA-15(P), which results in the better dispersion of TEPA. However, the dynamic impregnation process for the TEPA ethanol solution can effectively avoid the formation of hydrogen bonds between the intra- and inter-molecules resulting in the high adsorptive capacity of the amino groups in TEPA.

Key wordsSBA-15(P)      TEPA      CO2      Dynamic impregnation      Bond formation      Adsorptive capacity     
Received: 08 August 2011      Published: 27 October 2011
MSC2000:  O643  
Fund:  

The project was supported by the Natural Science Foundation of Shandong Province, China (2009ZRB01250) and Technology Development Program of Qingdao Government, China (1263194353127).

Corresponding Authors: YANG Cheng     E-mail: yangcheng@qibebt.ac.cn
Cite this article:

YANG Yong-Hong, LI Fen-Fen, YANG Cheng, ZHANG Wen-Yu, WU Jin-Hu. Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance. Acta Phys. Chim. Sin., 2012, 28(01): 195-200.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201228195     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2012/V28/I01/195

(1) Blauwhoff, P. M. M.; Versteeg, G. F.; Van Swaaij,W. P. M. Chemical Engineering Science 1984, 39, 207.  
(2) Zheng, F.; Tran, D. N.; Busche, B. J.; Fryxell, G. E.; Addleman, R. S.; Zemanian, T. S.; Aardahl, C. L. Industrial & Engineering Chemistry Research 2005, 44, 3099.  
(3) Chang, A. C. C.; Chuang, S. S. C.; Gray, M.; Soong, Y. Energy & Fuels 2003, 17, 468.  
(4) Gray, M. L.; Soong, Y.; Champagne, K. J.; Baltrus, J.; Stevens, R.W.; Toochinda, P.; Chuang, S. S. C. Separation and Purification Technology 2004, 35, 31.  
(5) Iyer, M. V.; Gupta, H.; Sakadjian, B. B.; Fan, L. S. Industrial & Engineering Chemistry Research 2004, 43, 3939.  
(6) Reddy, E. P.; Smirniotis, P. G. The Journal of Physical Chemistry B 2004, 108, 7794.  
(7) Bredesen, R.; Jordal, K.; Bolland, O. Chemical Engineering and Processing 2004, 43, 1129.  
(8) Huang, H. Y.; Yang, R. T.; Chinn, D.; Munson, C. L. Industrial & Engineering Chemistry Research 2003, 42, 2427.  
(9) Demontigny, D.; Tontiwachwuthikul, P.; Chakma, A. Journal of Membrane Science 2006, 277, 99.  
(10) Xu, X. C.; Song, C. S.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Energy & Fuels 2002, 16, 1463.  
(11) Xu, X. C.; Song, C. S.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Microporous and Mesoporous Materials 2003, 62, 29.  
(12) Yoshitake, H.; Yokoi, T.; Tatsumi, T. Chemistry of Materials 2003, 15, 1713.  
(13) Han, Y. J.; Stucky, G. D.; Butler, A. Journal of the American Chemical Society 1999, 121, 9897.  
(14) Kubota, Y.; Nishizaki, Y.; Ikeya, H.; Saeki, M.; Hida, T.; Kawazu, S.; Yoshida, M.; Fujii, H.; Sugi, Y. Microporous and Mesoporous Materials 2004, 70, 135.  
(15) Matsumoto, A.; Tsutsumi, K.; Schumacher, K.; Unger, K. K. Langmuir 2002, 18, 4014.  
(16) Kimura, T.; Saeki, S.; Sugahara, Y.; Kuroda, K. Langmuir 1999, 15, 2794.  
(17) Inagaki, S.; Guan, S.; Fukushima, Y.; Ohsuna, T.; Terasaki, O. Journal of the American Chemical Society 1999, 121, 9611.  
(18) Feng, X.; Fryxell, G. E.;Wang, L. Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science 1997, 276, 923.  
(19) Choi, S.; Drese, J. H.; Jones, C.W. ChemSusChem 2009, 2, 796.  
(20) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.  
(21) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Z. J.;Wang, Y.; Yu, Q.; Zhu, J. H. Microporous and Mesoporous Materials 2008, 114, 74.  
(22) Aronu, U. E.; Svendsen, H. F.; Hoff, K. A.; Juliussen, O. Solvent Selection for Carbon dioxide Absorption Energy Procedia 2009, 1, 1051. 9th International Conference on Greenhouse Gas Control Technologies,Washington DC, Nov. 16-20, 2008.
(23) da Silva, E. F.; Svendsen, H. F. International Journal of Greenhouse Gas Control 2007, 1, 151.  
(24) Yoshitake, H.; Koiso, E.; Horie, H.; Yoshimura, H. Microporous and Mesoporous Materials 2005, 85, 183.  
(25) Hiyoshi, N.; Yogo, K.; Yashima, T. Microporous and Mesoporous Materials 2005, 84, 357.  
(26) Yue, M. B.; Chun, Y.; Cao, Y.; Dong, X.; Zhu, J. H. Advanced Functional Materials 2006, 16, 1717.  
(27) Knowles, G. P.; Graham, J. V.; Delaney, S.W.; Chaffee, A. L. Fuel Processing Technology 2005, 86, 1435.  
(28) Wu, D. A. Novel Method to Prepare Silica Based Carbon Dioxide Capture Sorbent. Ph. D. Dissertation, The University of Akron, Akron, 2008.
(29) Stevens,W. J. J.; Mertens, M.; Mullens, S.; Thijs, I.; Van Tendeloo, G.; Cool, P.; Vansant, E. F. Microporous and Mesoporous Materials 2006, 93, 119.  
(30) Wei, J.W.; Shi, J. J.; Pan, H.; Su, Q. F.; Zhu, J. B.; Shi, Y. Microporous and Mesoporous Materials 2009, 117, 596.  
(31) Cheng, C. F.; Lin, Y. C.; Cheng, H. H.; Chen, Y. C. Chemical Physics Letters 2003, 382, 496.  
(32) Ding, Z. J.; Chen, J. H.; Guo, Y.; Gong, X. Z. Bulletn of the Chinese Ceramic Society 2009, 28, 704. [丁志杰, 陈君华, 郭雨, 公旭中. 硅酸盐通报, 2009, 28, 704.]
(33) Su, Z. H.; Chen, Q. Y.; Li, J.; Liu, S. J. Acta Phys. -Chim. Sin. 2007, 23, 1760. [苏赵辉, 陈启元, 李洁, 刘士军. 物理化学学报, 2007, 23, 1760.]
(34) Ryoo, R.; Ko, C. H.; Kruk, M.; Antochshuk, V.; Jaroniec, M. The Journal of Physical Chemistry B 2000, 104, 11465.  
(35) Yue, M. B.; Zhu, J. H. Chinese Journal of Catalysis 2008, 29, 1051. [岳明波, 朱建华. 催化学报, 2008 , 29, 1051.]
(36) Welcome toWikipedia, the free encyclopedia. http://en.wikipedia.org/wiki/Hydrogen_ bond (accessed Sep 07, 2011).
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