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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(01)>> 195-200     doi: 10.3866/PKU.WHXB201228195         中文摘要
CATALYSIS AND SURFACE SCIENCE
Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance
YANG Yong-Hong1,2, LI Fen-Fen1,3, YANG Cheng1, ZHANG Wen-Yu3, WU Jin-Hu1
1. Key Laboratory of Biofuels, Qindao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Shandong Polytechnic University, Jinan 250353, P. R. China
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Various amine-functionalized CO2 adsorbents were prepared by incorporating tetraethylenepenthamine (TEPA) onto SBA-15(P) by controlling the impregnation method and its process. The materials were characterized using X-ray diffraction (XRD), N2-adsorption, elemental analysis, and Fourier transform infrared (FTIR) techniques. Their adsorptive capacities were determined by CO2-temperature programmed desorption (TPD). The results indicate that the dynamic impregnation process using a TEPA ethanol solution was successful in loading TEPA into the channels of SBA-15(P). Moreover, bonding formation between the highly dispersed TEPA and SBA-15(P) was facilitated to CO2 adsorption/desorption. Therefore, a binding mechanism is proposed. The -NH2 group of TEPA forms hydrogen bonds with -OH and C-O-C groups on SBA-15(P), which results in the better dispersion of TEPA. However, the dynamic impregnation process for the TEPA ethanol solution can effectively avoid the formation of hydrogen bonds between the intra- and inter-molecules resulting in the high adsorptive capacity of the amino groups in TEPA.

Keywords: SBA-15(P)   TEPA   CO2   Dynamic impregnation   Bond formation   Adsorptive capacity  
Received: 2011-08-08 Accepted: 2011-10-10 Publication Date (Web): 2011-10-27
Corresponding Authors: YANG Cheng Email: yangcheng@qibebt.ac.cn

Fund: The project was supported by the Natural Science Foundation of Shandong Province, China (2009ZRB01250) and Technology Development Program of Qingdao Government, China (1263194353127).

Cite this article: YANG Yong-Hong, LI Fen-Fen, YANG Cheng, ZHANG Wen-Yu, WU Jin-Hu. Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance[J]. Acta Phys. -Chim. Sin., 2012,28 (01): 195-200.    doi: 10.3866/PKU.WHXB201228195
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