ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(01)>> 195-200     doi: 10.3866/PKU.WHXB201228195         中文摘要
Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance
YANG Yong-Hong1,2, LI Fen-Fen1,3, YANG Cheng1, ZHANG Wen-Yu3, WU Jin-Hu1
1. Key Laboratory of Biofuels, Qindao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong Province, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Shandong Polytechnic University, Jinan 250353, P. R. China
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Various amine-functionalized CO2 adsorbents were prepared by incorporating tetraethylenepenthamine (TEPA) onto SBA-15(P) by controlling the impregnation method and its process. The materials were characterized using X-ray diffraction (XRD), N2-adsorption, elemental analysis, and Fourier transform infrared (FTIR) techniques. Their adsorptive capacities were determined by CO2-temperature programmed desorption (TPD). The results indicate that the dynamic impregnation process using a TEPA ethanol solution was successful in loading TEPA into the channels of SBA-15(P). Moreover, bonding formation between the highly dispersed TEPA and SBA-15(P) was facilitated to CO2 adsorption/desorption. Therefore, a binding mechanism is proposed. The -NH2 group of TEPA forms hydrogen bonds with -OH and C-O-C groups on SBA-15(P), which results in the better dispersion of TEPA. However, the dynamic impregnation process for the TEPA ethanol solution can effectively avoid the formation of hydrogen bonds between the intra- and inter-molecules resulting in the high adsorptive capacity of the amino groups in TEPA.

Keywords: SBA-15(P)   TEPA   CO2   Dynamic impregnation   Bond formation   Adsorptive capacity  
Received: 2011-08-08 Accepted: 2011-10-10 Publication Date (Web): 2011-10-27
Corresponding Authors: YANG Cheng Email:

Fund: The project was supported by the Natural Science Foundation of Shandong Province, China (2009ZRB01250) and Technology Development Program of Qingdao Government, China (1263194353127).

Cite this article: YANG Yong-Hong, LI Fen-Fen, YANG Cheng, ZHANG Wen-Yu, WU Jin-Hu. Grafting Morphologies of TEPA on SBA-15(P) and Its Effect on CO2 Adsorption Performance[J]. Acta Phys. -Chim. Sin., 2012,28 (01): 195-200.    doi: 10.3866/PKU.WHXB201228195
(1) Blauwhoff, P. M. M.; Versteeg, G. F.; Van Swaaij,W. P. M. Chemical Engineering Science 1984, 39, 207.  
(2) Zheng, F.; Tran, D. N.; Busche, B. J.; Fryxell, G. E.; Addleman, R. S.; Zemanian, T. S.; Aardahl, C. L. Industrial & Engineering Chemistry Research 2005, 44, 3099.  
(3) Chang, A. C. C.; Chuang, S. S. C.; Gray, M.; Soong, Y. Energy & Fuels 2003, 17, 468.  
(4) Gray, M. L.; Soong, Y.; Champagne, K. J.; Baltrus, J.; Stevens, R.W.; Toochinda, P.; Chuang, S. S. C. Separation and Purification Technology 2004, 35, 31.  
(5) Iyer, M. V.; Gupta, H.; Sakadjian, B. B.; Fan, L. S. Industrial & Engineering Chemistry Research 2004, 43, 3939.  
(6) Reddy, E. P.; Smirniotis, P. G. The Journal of Physical Chemistry B 2004, 108, 7794.  
(7) Bredesen, R.; Jordal, K.; Bolland, O. Chemical Engineering and Processing 2004, 43, 1129.  
(8) Huang, H. Y.; Yang, R. T.; Chinn, D.; Munson, C. L. Industrial & Engineering Chemistry Research 2003, 42, 2427.  
(9) Demontigny, D.; Tontiwachwuthikul, P.; Chakma, A. Journal of Membrane Science 2006, 277, 99.  
(10) Xu, X. C.; Song, C. S.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Energy & Fuels 2002, 16, 1463.  
(11) Xu, X. C.; Song, C. S.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Microporous and Mesoporous Materials 2003, 62, 29.  
(12) Yoshitake, H.; Yokoi, T.; Tatsumi, T. Chemistry of Materials 2003, 15, 1713.  
(13) Han, Y. J.; Stucky, G. D.; Butler, A. Journal of the American Chemical Society 1999, 121, 9897.  
(14) Kubota, Y.; Nishizaki, Y.; Ikeya, H.; Saeki, M.; Hida, T.; Kawazu, S.; Yoshida, M.; Fujii, H.; Sugi, Y. Microporous and Mesoporous Materials 2004, 70, 135.  
(15) Matsumoto, A.; Tsutsumi, K.; Schumacher, K.; Unger, K. K. Langmuir 2002, 18, 4014.  
(16) Kimura, T.; Saeki, S.; Sugahara, Y.; Kuroda, K. Langmuir 1999, 15, 2794.  
(17) Inagaki, S.; Guan, S.; Fukushima, Y.; Ohsuna, T.; Terasaki, O. Journal of the American Chemical Society 1999, 121, 9611.  
(18) Feng, X.; Fryxell, G. E.;Wang, L. Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science 1997, 276, 923.  
(19) Choi, S.; Drese, J. H.; Jones, C.W. ChemSusChem 2009, 2, 796.  
(20) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.  
(21) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Z. J.;Wang, Y.; Yu, Q.; Zhu, J. H. Microporous and Mesoporous Materials 2008, 114, 74.  
(22) Aronu, U. E.; Svendsen, H. F.; Hoff, K. A.; Juliussen, O. Solvent Selection for Carbon dioxide Absorption Energy Procedia 2009, 1, 1051. 9th International Conference on Greenhouse Gas Control Technologies,Washington DC, Nov. 16-20, 2008.
(23) da Silva, E. F.; Svendsen, H. F. International Journal of Greenhouse Gas Control 2007, 1, 151.  
(24) Yoshitake, H.; Koiso, E.; Horie, H.; Yoshimura, H. Microporous and Mesoporous Materials 2005, 85, 183.  
(25) Hiyoshi, N.; Yogo, K.; Yashima, T. Microporous and Mesoporous Materials 2005, 84, 357.  
(26) Yue, M. B.; Chun, Y.; Cao, Y.; Dong, X.; Zhu, J. H. Advanced Functional Materials 2006, 16, 1717.  
(27) Knowles, G. P.; Graham, J. V.; Delaney, S.W.; Chaffee, A. L. Fuel Processing Technology 2005, 86, 1435.  
(28) Wu, D. A. Novel Method to Prepare Silica Based Carbon Dioxide Capture Sorbent. Ph. D. Dissertation, The University of Akron, Akron, 2008.
(29) Stevens,W. J. J.; Mertens, M.; Mullens, S.; Thijs, I.; Van Tendeloo, G.; Cool, P.; Vansant, E. F. Microporous and Mesoporous Materials 2006, 93, 119.  
(30) Wei, J.W.; Shi, J. J.; Pan, H.; Su, Q. F.; Zhu, J. B.; Shi, Y. Microporous and Mesoporous Materials 2009, 117, 596.  
(31) Cheng, C. F.; Lin, Y. C.; Cheng, H. H.; Chen, Y. C. Chemical Physics Letters 2003, 382, 496.  
(32) Ding, Z. J.; Chen, J. H.; Guo, Y.; Gong, X. Z. Bulletn of the Chinese Ceramic Society 2009, 28, 704. [丁志杰, 陈君华, 郭雨, 公旭中. 硅酸盐通报, 2009, 28, 704.]
(33) Su, Z. H.; Chen, Q. Y.; Li, J.; Liu, S. J. Acta Phys. -Chim. Sin. 2007, 23, 1760. [苏赵辉, 陈启元, 李洁, 刘士军. 物理化学学报, 2007, 23, 1760.]
(34) Ryoo, R.; Ko, C. H.; Kruk, M.; Antochshuk, V.; Jaroniec, M. The Journal of Physical Chemistry B 2000, 104, 11465.  
(35) Yue, M. B.; Zhu, J. H. Chinese Journal of Catalysis 2008, 29, 1051. [岳明波, 朱建华. 催化学报, 2008 , 29, 1051.]
(36) Welcome toWikipedia, the free encyclopedia. bond (accessed Sep 07, 2011).
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2. HU Hai-Feng, HE Tao.Controllable Modulation of Morphology and Photocatalytic Performance of ZnO Nanomaterials via pH Adjustment[J]. Acta Phys. -Chim. Sin., 2016,32(2): 543-550
3. JIN Zhen-Yu, LI Tong, LU An-Hui.Nitrogen-Enriched Hierarchical Porous Carbon for Carbon Dioxide Adsorption and Separation[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1602-1608
4. HUANG Yan, FU Min, HE Tao.Synthesis of g-C3N4/BiVO4 Nanocomposite Photocatalyst and Its Application in Photocatalytic Reduction of CO2[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1145-1152
5. ZHAO Yi, LIU Yong-Jun, ZHUO Shu-Ping.Reaction Mechanism and Regioselectivity of Cu(I)-Catalyzed Hydrocarboxylation of 1-Phenyl-propyne with Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2015,31(2): 237-244
6. ZHAO Yi, ZHOU Jin, LIU Hui, ZHUO Shu-Ping.Reaction Mechanism and the Regioselectivity of Cu-Catalyzed Silacarboxylation of Internal Alkynes: a Density Functional Theory Study[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1864-1871
7. HU Jing-Xiu, ZHANG Jing, ZOU Jian-Feng, XIAO Qiang, ZHONG Yi-Jun, ZHU Wei-Dong.Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO2 Adsorption[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1169-1174
8. LI Li, HU Zhong-Ai, YANG Yu-Ying, WU Hong-Ying, CUI Lu-Juan.Synthesis of a MnO2/NiCo2O4 Composite by Electrostatic Self-Assembly and Its Electrochemical Performance[J]. Acta Phys. -Chim. Sin., 2014,30(5): 899-907
9. ZHANG Chen, ZHAO Jing-Mao.Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO2 System[J]. Acta Phys. -Chim. Sin., 2014,30(4): 677-685
10. YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei.Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption[J]. Acta Phys. -Chim. Sin., 2014,30(4): 789-796
11. WANG Wen-Qing, ZHANG Yu-Feng, GONG Yan.Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N+H…O- Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices[J]. Acta Phys. -Chim. Sin., 2014,30(4): 608-622
12. HU Zhi, HUANG Xiao-Wei, CHEN Yang-Hui.Synthesis and Properties of SmBaCo2O5+δ Cathode Material via EDTA-Glycine Process[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2585-2591
13. LIN Xue-Qiang, LIU Wei, ZHANG Jing, DONG Shuai, ZHANG Hai-Long, LI Xiao-Bo, XU Chuan-Chuan, LU Min-Xu.Characteristics of Corrosion Scale of 3Cr Steel at High Temperature and Pressure in an O2 and CO2 Environment[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2405-2414
14. GUO Li-Mei KUANG Yuan-Jiang YANG Xiao-Dan YU Yan-Long YAO Jiang-Hong CAO Ya-An.Investigation on Photocatalytic Reduction of CO2into CH4 Using SrB2O4/SrCO3Composite Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1558-1565
15. FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei.Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1266-1272
16. CAI Feng, LIU Wei, FAN Xue-Hua, ZHANG Jing, LU Min-Xu.Electrochemical Corrosion Behavior of X70 Pipeline Steel in Turbulence Zone under Jet Impingement at High Temperature and High Pressure CO2 Environment[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1003-1012
17. WANG Sen-Lin, WANG Li-Pin, ZHANG Zhen-Hong.Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo2O4 Electrode[J]. Acta Phys. -Chim. Sin., 2013,29(05): 981-988
18. GUO Li-Mei, KUANG Yuan-Jiang, YANG Xiao-Dan, YU Yan-Long, YAO Jiang-Hong, CAO Ya-An.Photocatalytic Reduction of CO2 into CH4 Using SrB2O4 Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(02): 397-402
19. ZHU Fu-Liang, ZHAO Jing-Xin, CHENG Yong-Liang, LI Hai-Bao, YAN Xing-Bin.Magnetic and Electrochemical Properties of NiCo2O4 Microbelts Fabricated by Electrospinning[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2874-2878
20. ZHOU En-Nian, YU Zhi-Hui, QU Jing-Kui, Qi Tao, Han Xiao-Ying, ZHANG Guo-Qing.Equilibrium Solubility Modeling of CO2 in Na2Cr2O7 Solutions[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2567-2573
21. YANG Xiao-Yan, SUN Song, DING Jian-Jun, ZHANG Yi, ZHANG Man-Man, GAO Chen, BAO Jun.Preparation, Structure and Performance of [CuO-ZnO-Al2O3]/ [HZSM-5] Core-Shell Bifunctional Catalysts for One-Step Synthesis of Dimethyl Ether from CO2+H2[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1957-1963
22. YE Qing, ZHANG Yu, LI Ming, SHI Yao.Adsorption of Low Concentration CO2 by Modified Carbon Nanotubes under Ambient Temperature[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1223-1229
23. ZHAO Hui-Min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-Hua.Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes[J]. Acta Phys. -Chim. Sin., 2012,28(04): 985-992
24. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
25. BAO Jin-Zhen, WANG Sen-Lin.Preparation of the Ni/NiCo2O4 Composite Electrode and Its Properties toward the Oxygen Evolution Reaction in Alkaline Media[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2849-2856
26. WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong.Dimethyl Ether Synthesis from CO2 Hydrogenation over CuO-TiO2-ZrO2/HZSM-5 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2651-2658
27. LI Gan, LUO Wen-Hua, CHEN Hu-Chi.Adsorption and Dissociation of CO2on the α-U(001) Surface[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2319-2325
28. CUI Bai, LIN Hong, ZHAO Xiao-Chong, LI Jian-Bao, LI Wen-Di.Visible Light Induced Photocatalytic Activity of ZnCo2O4 Nanoparticles[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2411-2415
29. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
30. WANG Bin, DU Min, ZHANG Jing.Inhibition Performance of an Imidazoline Derivative as a Gas-Liquid Two-Phase Inhibitor for Q235 Steel against CO2 Corrosion[J]. Acta Phys. -Chim. Sin., 2011,27(01): 120-126
31. SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao.Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3023-3029
32. DU Xiao-Ming, WU Er-Dong.Behavior of Adsorbed Hydrogen Molecules on Zeolites[J]. Acta Phys. -Chim. Sin., 2009,25(03): 549-554
33. MA Zhong-Yi;YANG Cheng;DONG Qing-Nian;WEI Wei;LI Wen-Huai;SUN Yu-Han.A Study of CO2/H2 Adsorption on Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2005,21(02): 225-228
34. Li Chun-Lin;Fu Yi-Lu.Effect on the Carbon Deposit in CO2 Reforming of CH4 over Ni/Ce-Zr-Al-Ox Catalyst by Adding Steam[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 906-910
35. Wang Yin-Jie;Qi-Lu.The Influencing Factor for CO2 Absorption of Li2ZrO3 at High Temperature[J]. Acta Phys. -Chim. Sin., 2004,20(04): 364-367
36. Li Chun-Lin;Fu Yi-Lu;Bian Guo-Zhu.Surface Basicity and Catalytic Performance on Ni/Ce-Zr-Al-O Catalyst for CO2+CH4 Reforming[J]. Acta Phys. -Chim. Sin., 2003,19(10): 902-906
37. Zheng Qing-Rong;Gu An-Zhong;Lin Wen-Sheng;Li Ming;Lu Xue-Sheng.Theoretical Study on the Adsorbed Hydrogen Molecules on Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2003,19(02): 139-143
38. Ren Li;Kong Fan-Ao.A Study of the Reaction of OH radical with CO by Time-resolved FTIR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2002,18(06): 486-489
39. Yang Yong-Lai;Xu Heng-Yong;Li Wen-Zhao.Promotion Effects of CeO2 and Pd on Ni/γ-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(04): 321-325
40. Cao Wei-Liang;Liu Xin;Zhang Jing-Chang.Phase Behavior of Polymer-solvent-supercritical CO2 Ternary System[J]. Acta Phys. -Chim. Sin., 2001,17(08): 757-760
41. Xue Wei-Dong;Zhang Guang-Feng;Zhu Zheng-He;Wang Xiao-Lin;Luo De-Li;Zou Le-Xi;Sun Ying.Calculation on Weakly Bound Carbon Dioxide Dimer by DFT[J]. Acta Phys. -Chim. Sin., 2001,17(06): 501-506
42. Tian Yi-Ling;Han Ming;Chen Li;Feng Ji-Jun;Qin Ying.Study on Vapor-Liquid Phase Equilibria for CO2-C2H5OH System[J]. Acta Phys. -Chim. Sin., 2001,17(02): 155-160
43. Liu Zhen-Lin, Tu Jing, Fu Yi-Lu.Correlation of the Basicity with the Adsorption of NO on Supporte Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2000,16(08): 753-757
44. Jiang De-En, Zhao Bi-Ying, Xie You-Chang.Thermal Decomposition Behavior of Mg(NO3)2 on γ-Al2O3 and Basicity of MgO/γ-Al2O3[J]. Acta Phys. -Chim. Sin., 2000,16(02): 105-110
45. Ke Jie,Lu Jie,Zhong Ming-Hong,Zou Lei,Han Bu-Xing,Yan Hai-Ke.Effect of Ethanol on the Tautomerism of Ethyl Acetoacetate in Supercritical CO2[J]. Acta Phys. -Chim. Sin., 1997,13(04): 351-353
46. Zhong Ming-Hong,Ke Jie,Han Bu-Xing,Yan Hai-Ke.Densities of CO2-Ethanol,CO2-Acetone,CO2-Heptane Binary Mixtures and Partial Molar Volumes of the Solutes[J]. Acta Phys. -Chim. Sin., 1996,12(09): 816-824
47. Fan Ye-Mei, Xu Heng-Yong, Shi Ke-Ying, Shang Yong-Chen, Ye Qing, Xu Guo-Lin, Huang Ren-Cai, Guo Wei-Song, Zhou Pei-Heng.A New Route for the Chemical Utilization of CO2[J]. Acta Phys. -Chim. Sin., 1995,11(03): 283-286
48. Xu Bai-Qing, Yamaguchi Tsutomu, Tanabe Kozo, Liang Juan, Zheng Lu-Bin.Characterization of Acid-Base Property of ZrO2 by Thermal Desorption: II. Dual Adsorption of NH3 and CO2[J]. Acta Phys. -Chim. Sin., 1994,10(02): 114-120
49. LI Ji-Hong, LIN Chang-Feng, QIN Wu, XIAO Xian-Bin, WEI Li.Synergetic Effect of Mercury Adsorption on Catalytic Decomposition of CO over Perfect and Reduced Fe2O3[001][J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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