Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(02)>> 373-380     doi: 10.3866/PKU.WHXB201112021         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials
ZHU Jian-Bo1,2, XU You-Long1,2, WANG Jie1,2, WANG Jing-Ping1,2
1. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi'an 71004 9. P.R. China;
2. International Center for Dielectric Research, Xi'an Jiaotong University, Xi'an 71004 9. P.R. China
Full text: PDF (3650KB) HTML Export: BibTeX | EndNote (RIS)
Fast charge-discharge composite materials of conducting polypyrrole and functionalized single-walled carbon nanotubes doped with p-toluenesulfonate (PPy-TOS/F-SWNTs) were prepared by galvanostatic electrochemical polymerization. Scanning Electron Microscope (SEM) images showed that the composite had a nano-rod structure with a diameter of about 70 nm. Nitrogen adsorption-desorption experinents were used to characterize the specific surface area (BET) (up to 12.64 m2·g-1) and pore sizes of the composite. Electrochemical properties of the composites were studied by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge (GC) measurements. The specific capacitance of this composite is about 211 F·g-1 (energy density: 18.7 Wh·kg-1) at a current density of 2.5 A·g-1, and 141.8 F·g-1 (energy density: 12.6 Wh·kg-1) at large current density of 80 A·g-1. The composite had excellent cyclability with a capacity retention of about 95.2% after 10000 cycles at a current density of 10 A·g-1. All these results indicate that this new composite material has a very rapidly charge-discharge ability

Keywords: Supercapacitor   Electropolymerization   Polypyrrole   SWNTs  
Received: 2011-09-26 Accepted: 2011-11-21 Publication Date (Web): 2011-12-02
Corresponding Authors: XU You-Long Email: ylxu@mail.xjtu.edu.cn

Fund: The project was supported by the National High-Tech Research and Development Program of China (863) (2007AA03Z249) and National Natural Science Foundation of China (20804030).

Cite this article: ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping. Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28 (02): 373-380.    doi: 10.3866/PKU.WHXB201112021
(1) Simon, P.; Gogotsi, Y. Nature Materials 2008, 7, 845.  
(2) Winter, M.; Brodd, R. J. Chemical Reviews 2004, 104, 4245.  
(3) Kalaji, M.; Murphy, P. J.;Williams, G. O. Synthetic Metals 1999, 102, 1360.  
(4) Bredas, J. L.; Street, G. B. Accounts of Chemical Research 1985, 18, 309.  
(5) Iroh, J. O.; Levine, K. Journal of Power Sources 2003, 117, 267.  
(6) Ingram, M. D.; Staesche, H.; Ryder, K. S. Solid State Ionics 2004, 169, 51.  
(7) Mastragostino, M.; Arbizzani, C.; Soavi, F. Solid State Ionics 2002, 148, 493.  
(8) Il Cho, S.; Lee, S. B. Accounts of Chemical Research 2008, 41, 699.  
(9) Groenendaal, B. L.; Jonas, F.; Freitag, D.; Pielartzik, H.; Reynolds, J. R. Advanced Materials 2000, 12, 481.  
(10) Burke, A. Journal of Power Sources 2000, 91, 37.  
(11) Rudge, A.; Raistrick, I.; Gottesfeld, S.; Ferraris, J. P. Electrochimica Acta 1994, 39, 273.  
(12) Zhang, L. L.; Zhao, S. Y.; Tian, X. N.; Zhao, X. S. Langmuir 2010, 26, 17624.  
(13) Biswas, S.; Drzal, L. T. Chemistry of Materials 2010, 22, 5667.  
(14) Frackowiak, E.; Khomenko, V.; Jurewicz, K.; Lota, K.; Beguin, F. Journal of Power Sources 2006, 153, 413.  
(15) Liu, J.; Rinzler, A. G.; Dai, H. J.; Hafner, J. H.; Bradley, R. K.; Boul, P. J.; Lu, A.; Iverson, T.; Shelimov, K.; Huffman, C. B.; Rodriguez-Macias, F.; Shon, Y. S.; Lee, T. R.; Colbert, D. T.; Smalley, R. E. Science 1998, 280, 1253.  
(16) Iijima, S.; Yudasaka, M.; Nihey, F. Nec Technical Journal 2007, 2, 52.
(17) Lee, S.W.; Kim, B. S.; Chen, S.; Shao-Horn, Y.; Hammond, P. T. Journal of the American Chemical Society 2009, 131, 671.  
(18) Zhang, L. L.; Zhao, X. S. Chemical Society Reviews 2009, 38, 2520.  
(19) Tsang, S. C.; Chen, Y. K.; Harris, P. J. F.; Green, M. L. H. Nature 1994, 372, 159.  
(20) Chen, Z. Y.; Kobashi, K.; Rauwald, U.; Booker, R.; Fan, H.; Hwang,W. F.; Tour, J. M. Journal of the American Chemical Society 2006, 128, 10568.  
(21) Wang, J.; Xu, Y. L.; Chen, X.; Sun, X. F. Composites Science and Technology 2007, 67, 2981.  
(22) Wang, J.; Xu, Y. L.; Sun, X. F.; Xiao, F.; Mao, S. C. Acta Phys.-Chim. Sin. 2007, 23, 877. [王杰, 徐友龙, 孙孝飞, 毛胜春. 物理化学学报, 2007, 23, 877.]
(23) Dresselhaus, M. S.; Jorio, A.; Hofmann, M.; Dresselhaus, G.; Saito, R. Nano Letters 2010, 10, 751.  
(24) Montesa, I.; Munoz, E.; Benito, A. M.; Maser,W. K.; Martinez, M. T. Journal of Nanoscience and Nanotechnology 2007, 7, 3473.  
(25) Li, Y. F. Journal of Electroanalytical Chemistry 1997, 433, 181.  
(26) Li, S.; Qiu, Y. B.; Guo, X. P. Acta Phys.-Chim. Sin. 2010, 26, 601. [李胜, 岳于兵, 郭兴蓬. 物理化学学报, 2010, 26, 601.]
(27) Naoi, K.; Simon, P. Electrochemical Society Interface 2008, 34.
1. HU Bin, WANG Pei, Lü Xiao-Jing, WANG Ping-Jing, DAI Yu-Yu, OUYANG Mi.Effects of Monomer Molar Ratio on the Electrochemical and Electrochromic Properties of Copolymers[J]. Acta Phys. -Chim. Sin., 2016,32(4): 961-968
2. ZHOU Xiao, SUN Min-Qiang, WANG Geng-Chao.Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2016,32(4): 975-982
3. WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
4. LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu.Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Phys. -Chim. Sin., 2016,32(2): 474-480
5. LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei .Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 493-502
6. LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping.Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Phys. -Chim. Sin., 2015,31(4): 676-684
7. LI Yang, XIE Hua-Qing, LI Jing.Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2015,31(4): 693-699
8. YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang.Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2015,31(4): 685-692
9. OUYANG Mi, HUANG Sen-Biao, HAN Yan-Gang, Lü Xiao-Jing, YANG Yuan, DAI Yu-Yu, Lü Yao-Kang, ZHANG Cheng.Enhanced Electrochromic Performance of Ordered Porous Monolayer PBTB Film Using Amine-Modified Polystyrene Spheres as a Template[J]. Acta Phys. -Chim. Sin., 2015,31(3): 476-482
10. WU Yan-Bo, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers[J]. Acta Phys. -Chim. Sin., 2015,31(2): 315-321
11. LU Jian-Jian, YING Zong-Rong, LIU Xin-Dong, ZHAO Shuang-Sheng.Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2099-2108
12. HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2220-2228
13. YI Chao, XIONG Xin-Bo, ZOU Zhi-Biao, LI Jun-Jie, HUANG Tuo, LI Bin, MA Jun, ZENG Xie-Rong.Fabrication of Nickel-Based Composite Film Electrode for Supercapacitors by a New Method of Anodization/GCD[J]. Acta Phys. -Chim. Sin., 2015,31(1): 99-104
14. WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan.Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1659-1666
15. YANG Peng, TAN Fu-Rui, ZHANG Jing, JIN He-Hua, LI Hong-Bo, LIU Chun-Hua, LI Qing-Wen.Effects of Pore-Size Range and Composition of Polysaccharide Gels on Flow Behaviors and Selective Sorting of Single-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1764-1770
16. SU Jia, LU Shan, WANG Sha-Sha, ZHANG Xue-Hua, FU Yu-Bin, HE Tao.Influence of pH Values on the Structure and Performance of a Polypyrrole Counter Electrode for Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1487-1494
17. FAN Ren-Jie, LIN Rui, HUANG Zhen, ZHAO Tian-Tian, MA Jian-Xin.Preparation and Characterization of Pt Catalysts Supported on Cobalt-Polypyrrole-Carbon for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1259-1266
18. ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long.Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO2 Composites[J]. Acta Phys. -Chim. Sin., 2014,30(5): 881-890
19. SUN Xian-Zhong, ZHANG Xiong, HUANG Bo, MA Yan-Wei.Effects of Separator on the Electrochemical Performance of Electrical Double-Layer Capacitor and Hybrid Battery-Supercapacitor[J]. Acta Phys. -Chim. Sin., 2014,30(3): 485-491
20. CHEN Chan-Juan, HU Zhong-Ai, HU Ying-Ying, LI Li, YANG Yu-Ying, AN Ning, LI Zhi-Min, WU Hong-Ying.SnO2/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2256-2262
21. WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan.Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2077-2084
22. TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
23. MA Guo-Fu, MU Jing-Jing, ZHANG Zhi-Guo, SUN Kan-Jun, PENG Hui, LEI Zi-Qiang.Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2385-2391
24. HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
25. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
26. SHI Qin, MEN Chun-Yan, LI Juan.Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1691-1697
27. WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
28. OUYANG Mi, FU Zhi-Yan, Lü Xiao-Jing, CHEN Huan-Le, HU Bin, XIA Xu-Feng, ZHANG Cheng.Enhanced Film-Forming and Electrochromic Properties by Incorporating Bithiophene into Triphenylamine[J]. Acta Phys. -Chim. Sin., 2013,29(05): 996-1002
29. WANG Sha-Sha, LU Shan, SU Jia, GUO Zheng-Kai, LI Xue-Min, ZHANG Xue-Hua, HE Sheng-Tai, HE Tao.Influences of Polymerization Time on Structure and Properties of Polyaniline Counter Electrodes in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2013,29(03): 516-524
30. HU Ying-Ying, HU Zhong-Ai, ZHANG Ya-Jun, LU Ai-Lian, XU Huan, ZHANG Zi-Yu, YANG Yu-Ying, LI Li, WU Hong-Ying.Synthesis and Electrochemical Characterization of RuO2·xH2O/Graphite Nanosheet Composite Array Electrodes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(02): 305-310
31. LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang.Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Phys. -Chim. Sin., 2013,29(01): 111-116
32. ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
33. SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
34. LI Hong-Bo, ZHANG Jing, JIN He-Hua, LI Qing-Wen.Separation Techniques of Single-Walled Carbon Nanotubes with Single Electrical Type and Chirality[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2447-2455
35. HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
36. TAN Fu-Rui, LI Hong-Bo, GUI Hui, ZHANG Jing, LI Ru, JIN He-Hua.Effects of Ultrasonic Dispersion on the Separation of Single-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1790-1796
37. SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
38. LÜ Yong-Jun, CHEN Min.Molecular Transport through Finite-Length Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1070-1076
39. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
40. LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
41. JIN Yu, CHEN Hong-Yuan, CHEN Ming-Hai, LIU Ning, LI Qing-Wen.Carbon Nanotube/Polyaniline/Graphene Composite Paper and Its Electrochemical Capacitance Behaviors[J]. Acta Phys. -Chim. Sin., 2012,28(03): 609-614
42. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
43. GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
44. XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
45. LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
46. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
47. ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
48. TIAN Ying, WANG Jing-Ri, LIU Ming, SHI Kun, YANG Feng-Lin.Redox Stability of Polypyrrole in Aqueous Electrolyte Solutions by a Recurrent Potential Pulse Technique[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1116-1121
49. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
50. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
51. LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
52. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
53. ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
54. HUANG Rong, CHEN Ming-An, LU Xue-Bin.Chemical Oxidative Polymerization of Polypyrrole and Its Corrosion Resistance on the AZ31 Magnesium Alloy[J]. Acta Phys. -Chim. Sin., 2011,27(01): 113-119
55. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
56. ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
57. LI Mei-Chao, WANG Wu-Yang, ZHU Wan-Xia, MA Chun-An.Electrocatalytic Oxidation of Ascorbic Acid on a PPy-HEImTfa/Pt Electrode and Its Mechanism[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3212-3216
58. WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua.Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2951-2956
59. WEN Xiao-Nan, ZHANG Jing, GU Wen-Xiu, JIN He-Hua, LI Hong-Bo, LI Qing-Wen.Effects of NaCl on the Separation of Single-Walled Carbon Nanotubes by Agarose Gel Electrophoresis[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2757-2762
60. LI Jian-Ling, GAO Fei, ZHANG Ya-Kun, HE Li-Zhi, HAN Gui-Mei, WANG Xin-Dong.Electropolymerization of Nickel Complexes with Schiff Bases: Effect of Sweep Rate on Anodic Polymerization[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2647-2652
61. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
62. ZHANG Jing, KONG Ling-Bin, CAI Jian-Jun, YANG Zhen-Sheng, LUO Yong-Chun, KANG Long.Novel Polypyrrole/Mesoporous Carbon Nanocomposite Electrode for an Electrochemical Hybrid Capacitor[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1515-1520
63. LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
64. JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
65. XIE Li-Ming, YU Xue-Chun, FENG Chao-Qun, ZHANG Jin, LIU Zhong-Fan.Raman Characterization of a Highly Folded Individual Serpentine (7,5) Single-Walled Carbon Nanotube[J]. Acta Phys. -Chim. Sin., 2010,26(04): 801-804
66. GAN Lin, LIU Song, LI Dan-Na, GU Hang, CAO Yang, SHEN Qian, WANG Zhen-Xing, WANG Qing, GUO Xue-Feng.Facile Fabrication of the Crossed Nanotube-Graphene Junctions[J]. Acta Phys. -Chim. Sin., 2010,26(04): 1151-1156
67. WANG Hong-Jie, HU Fan, LI Shen-Min.Mixed Quantum-Classical Dynamics Simulations on the Vibrational Spectral Probe in a SWCT Confined Solvent[J]. Acta Phys. -Chim. Sin., 2010,26(03): 714-720
68. LI Sheng, QIU Yu-Bing, GUO Xing-Peng.Electrochemical Impedance of Polypyrrole Films under Different Conditions[J]. Acta Phys. -Chim. Sin., 2010,26(03): 601-609
69. ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
70. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
71. TIAN Ying, WU Yan-Bo, WANG Jing-Ri, YANG Feng-Lin.Catalytic Reduction of Cu(II) by Polypyrrole[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2249-2255
72. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
73. LI Zhen-Hua, JIANG Yuan, ZHAO Pei, SHANG Xue-Fu, YANG Hui, WANG Miao.Synthesis of Single-Walled Carbon Nanotube Films with Large Area and High Purity by Arc-Discharge[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2395-2398
74. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
75. CAO You-Ming, WANG Zhi-Yong, SHI Zu-Jin, GU Zhen-Nan.Preparation and Catalytic Properties of SWNTs-Supported Pd Catalyst[J]. Acta Phys. -Chim. Sin., 2009,25(05): 825-828
76. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
77. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
78. WANG Rui; ZHANG Tong; HE Yuan; GENG Wang-Chang; NIU Li-Gang; LI Xiao-Tian.Complex Impedance Analysis of the Humidity Sensing Properties of Polypyrrole[J]. Acta Phys. -Chim. Sin., 2009,25(02): 327-330
79. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
80. ZHU Yu-Zhen; WANG Sheng; WEI Xian-Long; DING Li; ZHANG Zhi-Yong; LIANG Xue-Lei; CHEN Qing; PENG Lian-Mao.Frequency Response of SWCNT Field-Effect Transistors with MWCNT Interconnects[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2122-2127
81. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
82. TIAN Ying; LI Zhe-Qi; XU Hong-Feng; WU Yan-Bo; YANG Feng-Lin.Effects of Different Electrolyte Solutions on Characteristics of Polypyrrole-Modified Films[J]. Acta Phys. -Chim. Sin., 2008,24(04): 612-618
83. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
84. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
85. YAN Na; ZHANG Cun-Zhong; WU Feng; LIU Jing-Jing; CHEN Jun-Zheng.Influence of Electropolymerized Current Density on Polypyrrole Electrode of Lithium Ion Cells[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1747-1752
86. YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu.Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1365-1369
87. WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
88. WANG Rui; XU Hua-Ming; LI Dan; LIANG Ji.Growth of Single-walled Carbon Nanotubes on the Given Locations for AFM Tips[J]. Acta Phys. -Chim. Sin., 2007,23(04): 565-568
89. JIN Wei-Hong; NI Jing; LAI Yee-Hing; PEI Jian.Photophysical Properties and Electropolymerization of Regioregular Head-to-Tail Oligothiophenes-Functionalized 9,9'-spirobifluorene Derivatives[J]. Acta Phys. -Chim. Sin., 2007,23(04): 459-465
90. WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
91. LI Rui-Fang;SHANG Zhen-Feng;XU Xiu-Fang;WANG Gui-Chang .Theoretical Studies on the Growth Mechanism of Armchair Single-walled Carbon Nanotube[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1388-1392
92. LIU Ling; ZHAO Yao-Min; YANG Jie; ZHAO Chong-Jun; JIANG Zhi-Yu.Photoeletrochemical Behavior of Polypyrrole Nanofiber Array Electrodes[J]. Acta Phys. -Chim. Sin., 2006,22(03): 261-264
93. ZHANG Zeng-Fu; LUO Guo-Hua; FAN Zhuang-Jun; XIANG Rong; ZHOU Li; WEI Fei.Complex Permittivity and Permeability Spectra of Different Kinds of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(03): 296-300
94. YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
95. Wang Hai-Fang;Deng Xiao-Yong;Wang Jing;Gao Xing-Fa;Xing Geng-Mei;Shi Zu-Jin;Gu Zhen-Nan;Liu Yuan-Fang;Zhao Yu-Liang.XPS Study of C-I Covalent Bond on Single-walled Carbon Nanotubes (SWNTs)[J]. Acta Phys. -Chim. Sin., 2004,20(07): 673-675
96. Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
97. Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
98. Li Huan-Jun;Guan Lun-Hui;Shi Zu-Jin;Gu Zhen-Nan.Synthesis and Characterization of C60@SWNTs[J]. Acta Phys. -Chim. Sin., 2004,20(04): 373-376
99. Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
100. Niu Jia-Li;Zou Hong-Ling;Zhang Jin;Liu Zhong-Fan.Tracing the Chemical Oxidation Process of Single-walled Carbon Nanotubes by Silver Nanoparticles[J]. Acta Phys. -Chim. Sin., 2004,20(01): 1-4
101. Liu Ji-Xin;Xie You-Chang.Single-wall Carbon Nanotubes Produced by Decomposition of CH4 on W-Fe-MgO Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1093-1096
102. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
103. Zuo Yan-Jun;Yu Jian-Hua;Huang Qi-Bin;Zhao Jian-Jun;Pan Yong;Lin Yuan.The Preparation of Poly(ophenylenediamine) Sarin Acid Imprinting Nanometer Layer and Its Structural Characterization[J]. Acta Phys. -Chim. Sin., 2003,19(06): 528-532
104. Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
105. Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288
106. Zou Hong-Ling;Yang Yan-Lian;Wu Bin;Qing Quan;Li Qing-Wen;Zhang Jin;Liu Zhong-Fan.Purification and Characterization of SingleWalled Carbon Nanotubes Synthesized by Chemical Vapor Deposition[J]. Acta Phys. -Chim. Sin., 2002,18(05): 409-413
107. Kan Jin-Qing;Li Xiang;Li Yong-Fang.Synthesis and Properties of Poly-2-aminopyridine[J]. Acta Phys. -Chim. Sin., 2002,18(02): 106-111
108. Yan Wei;Wei Zhi-Xiang;Wang Li-Li;Dai Li-Zong;Tian Zhong-Qun.Electrochemical and insitu Raman Spectroscopic Studies of Poly{(pyrrole-2,5-diyl)[(p-N,N-dimethylamino)benzylidene]}[J]. Acta Phys. -Chim. Sin., 2001,17(10): 908-912
109. Wei Zhong;Chen Yan;Liu Zhong-Fan.CVD Synthesis and Diameter Distribution of SingleWalled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2001,17(08): 718-722
110. Wei Zhong;Chen Yan;Liu Zhong-Fan.Preparation of Short Single Walled Carbon Nanotubes by CVDGrowth and by Chemical Oxidation[J]. Acta Phys. -Chim. Sin., 2001,17(08): 687-691
111. Nan Xiao-Lin;Zhang Jin;Liu Zhong-Fan;Shi Zu-Jin;Gu Zhen-Nan.Patterned Assembly of Shortened SingleWalled Carbon Nanotubes on Gold Surface[J]. Acta Phys. -Chim. Sin., 2001,17(05): 393-396
112. Kong Yong;Mu Shao-Lin.Electrochemical Polymerization of Thionine and Properties of Polythionine[J]. Acta Phys. -Chim. Sin., 2001,17(04): 295-299
113. Tang Jie-Yuan, Zhang Wen-Gong, Gao Feng.Study on the Coordination Polymer of Electropolyurushiol and Rare Earth[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1086-1092
114. Li Shu-Jin, Cao Yang, Feng Jian-Wen, Shi Wei-Ping, Zhou Wei-Qun.Calculation of Band Structures of PPY and PMPY[J]. Acta Phys. -Chim. Sin., 1999,15(10): 890-894
115. Li Yi-Jun,Liu Jun-Li,Dong Shao-Jun.Electrocatalytic Oxidation of Dihydric Phenol on Polypyrrole Film Modified Electrodes[J]. Acta Phys. -Chim. Sin., 1995,11(05): 460-464
116. Jin Wen, Dong Shao-Jun.Characterization of 1:12 Phosphomolybdic Anions Doped Polypyrrole (PMo12/PPy) Film Electrode[J]. Acta Phys. -Chim. Sin., 1994,10(02): 183-187
117. Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun.Photoelectrochemical Polymerization of Conducting Polymer Monomers[J]. Acta Phys. -Chim. Sin., 1993,9(02): 277-280
118. Chen Yan-Zhen; Xu Ke-Yang; Tian Zhao-Wu.The Stury of Photoelectrochemical Polymerization of Pyrrole on Metal Substractes[J]. Acta Phys. -Chim. Sin., 1991,7(05): 589-592
119. Chen Yan-Zhen; Li Rong-Fen; Tian Zhao-Wu.The Studies of Poly-Ni(II) Film Electrode[J]. Acta Phys. -Chim. Sin., 1991,7(02): 158-162
120. Zheng Zhi-Min; Wu Hui-Huang; Zhou Shao-Min.Biofunctional Electrodes III. Study on Electrochemical Immobilization of Glucose Oxidase[J]. Acta Phys. -Chim. Sin., 1991,7(02): 163-168
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top