Please wait a minute...
Acta Phys. Chim. Sin.  2012, Vol. 28 Issue (04): 985-992    DOI: 10.3866/PKU.WHXB201202071
PHYSICAL CHEMISTRY OF MATERIALS     
Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes
ZHAO Hui-Min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-Hua
Key Laboratory of Mesoscopic Chemistry of the Ministry of Education, School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
Download:   PDF(1006KB) Export: BibTeX | EndNote (RIS)      

Abstract  Mesoporous silica SBA-15-like materials with large pores were synthesized using tri-block copolymer P123 as a structure-directing agent, tetramethoxysilane as the silicon source, and different organic solvents as swelling agents. The resulting materials were characterized by powder X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. The results showed that the introduction of swelling agents effectively enlarged the pore diameter and pore volume of the SBA-15 materials, and pore swelling with isooctane was larger than that with CCl4. When modified with tetraethylenepentamine (TEPA), all of these composite materials exhibited excellent adsorption capacities for CO2. The adsorption capacity of CO2 was independent of the pore structure, if the template was removed before modification with TEPA. By contrast, the adsorption capacity increased with the pore diameter when the as-synthesized mesoporous material was modified with TEPA. The effects of temperature and pressure on the CO2 adsorption capacity were investigated using adsorption isotherms and CO2 temperature-programmed desorption (TPD). With CO2 adsorption at higher temperature, the composite materials showed different adsorption capacities with pressure variation. As a result, the adsorption and separation of CO2 on these TEPA modified mesoporous materials in ambient air flow can be realized via pressure swing adsorption.

Key wordsSwelling agent      Mesoporous materials      CO2      Pressure swing adsorption      Template      Tetraethylenepentamine     
Received: 01 September 2011      Published: 07 February 2012
MSC2000:  O647  
Fund:  

The project was supported by the National High-Tech Research and Development Program of China (863) (2008AA06Z327), Fundamental Research Funds for the Central Universities, China (1116020503), and Testing Fund of Nanjing University, China (0205001330).

Corresponding Authors: CHUN Yuan     E-mail: ychun@nju.edu.cn
Cite this article:

ZHAO Hui-Min, LIN Dan, YANG Gang, CHUN Yuan, XU Qin-Hua. Adsorption Capacity of Carbon Dioxide on Amine Modified Mesoporous Materials with Larger Pore Sizes. Acta Phys. Chim. Sin., 2012, 28(04): 985-992.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201202071     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2012/V28/I04/985

(1) Lacis, A. A.; Schmidt, G. A.; Rind, D.; Ruedy, R. A. Science 2010, 330, 356.  
(2) Melillo, J. M.; Mcguire, A. D.; Kicklighter, D.W.; Moore, B.; Vorosmarty, C. J.; Schloss, A. L. Nature 1993, 363, 234.  
(3) Millward, A. R.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 17998.  
(4) Kim, J.; Yang, S. T.; Choi, S. B.; Sim, J.; Kim, J.; Ahn,W. S. J. Mater. Chem. 2011, 21, 3070.  
(5) An, J.; Rosi, N. L. J. Am. Chem. Soc. 2010, 132, 5578.  
(6) Veawab, A.; Tontiwachwuthikul, P.; Chakma, A. Ind. Eng. Chem. Res. 1999, 38, 3917.  
(7) Xu, X.; Song, C.; Andresen, J. M.; Miller, B. G.; Scaroni, A.W. Energy Fuels 2002, 16, 1463.  
(8) Xu, X.; Song, C.; Miller, B. G.; Scaroni, A.W. Ind. Eng. Chem. Res. 2005, 44, 8113.  
(9) Liu, Y. M.; Shi, J. J.; Chen, J.; Ye, Q.; Pan, H.; Shao, Z. H.; Shi, Y. Microporous Mesoporous Mat. 2010, 134, 16.  
(10) Choi, S.; Drese, J. H.; Jones, C.W. ChemSusChem 2009, 2, 796.  
(11) Peter, J. E.; Harlick, Abdelhamid, S. Ind. Eng. Chem. Res. 2006, 45, 3248.  
(12) Sayari, A.; Belmabkhout, Y. J. Am. Chem. Soc. 2010, 132, 6312.  
(13) Zhao, H. L.; Hu, J.;Wang, J. J.; Zhou, L. H.; Liu, H. L. Acta Phys. -Chim. Sin. 2007, 23, 801. [赵会玲, 胡军, 汪建军, 周丽绘, 刘洪来. 物理化学学报, 2007, 23, 801.]  
(14) Chen, C.; Yang, S. T.; Ahn,W. S.; Ryoo, R. Chem. Commun. 2009, 3627.
(15) Qi, G.;Wang, Y.; Estevez, L.; Duan, X.; Anako, N.; Park, A. A.; Li,W.; Jones, C.W.; Giannelis, E. P. Environ. Sci. Technol. 2011, 4, 444.
(16) Yue, M. B.; Chun, Y.; Cao, Y.; Dong, X.; Zhu, J. H. Adv. Funct. Mater. 2006, 16, 1717.  
(17) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Y.;Wang, Z. J.; Zhu, J. H. Chem. Eur. J. 2008, 14, 3442.  
(18) Yue, M. B.; Sun, L. B.; Cao, Y.;Wang, Z. J.;Wang, Y.; Yu, Q.; Zhu, J. H. Microporous Mesoporous Mat. 2008, 114, 74.  
(19) Wen, J. J.; Gu, F. N.;Wei, F.; Zhou, Y.; Lin,W. G.; Yang, J.; Yang, J. Y.;Wang, Y.; Zou, Z. G.; Zhu, J. H. J. Mater. Chem. 2010, 20, 2840.  
(20) Ma, L.; Han, K. K.; Ding, X. H.; Chun, Y.; Zhu, J. H. J. Nanosci. Nanotechnol. 2011, 11, 4079.  
(21) Beck, J. S.; Vartuli, J. C.; Roth,W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T.W.; Olson, D. H.; Sheppard, E.W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Chem. Soc. 1992, 114, 10834.  
(22) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.  
(23) Liu, J.; Li, C.; Yang, Q.; Yang, J.; Li, C. Langmuir 2007, 23, 7255.  
(24) Sun, R. Q.; Zhou, X.; Sun, L. B.;Wu, H.; Chun, Y.; Xu, Q. H. Chem. J. Chin. Univ. 2007, 28, 2333. [孙瑞琴, 周徐, 孙林兵, 吴昊, 淳远, 须沁华. 高等学校化学学报, 2007, 28, 2333.]
(25) Hiyoshi, N.; Yogo, K.; Yashima, T. Microporous Mesoporous Mat. 2005, 84, 357.  
(26) Yan, X.; Zhang, L.; Zhang, Y.; Yang, G.; Yan, Z. Ind. Eng. Chem. Res. 2011, 50, 3220.  
(27) Cavenati, S.; Grande, C. A.; Rodrigues, A. E. J. Chem. Eng. Data 2004, 49, 1095.  
[1] GUO Yun-Peng, FENG Jie, LI Wen-Ying. Effect of Ni Doping on Electron Transfer in Ni/MgO Catalysts[J]. Acta Phys. Chim. Sin., 2017, 33(9): 1796-1802.
[2] ZHOU Liang, ZHANG Xue-Hua, LIN Lin, LI Pan, SHAO Kun-Juan, LI Chun-Zhong, HE Tao. Visible-Light Photocatalytic Reduction of CO2 by CoTe Prepared via a Template-Free Hydrothermal Method[J]. Acta Phys. Chim. Sin., 2017, 33(9): 1884-1890.
[3] FAN Qi-Tang, ZHU Jun-Fa. Controlling the Topology of Low-Dimensional Organic Nanostructures with Surface Templates[J]. Acta Phys. Chim. Sin., 2017, 33(7): 1288-1296.
[4] QIU Jian-Ping, TONG Yi-Wen, ZHAO De-Ming, HE Zhi-Qiao, CHEN Jian-Meng, SONG Shuang. Electrochemical Reduction of CO2 to Methanol at TiO2 Nanotube Electrodes[J]. Acta Phys. Chim. Sin., 2017, 33(7): 1411-1420.
[5] HUANG Xue-Hui, SHANG Xiao-Hui, NIU Peng-Ju. Surface Modification of SBA-15 and Its Effect on the Structure and Properties of Mesoporous La0.8Sr0.2CoO3[J]. Acta Phys. Chim. Sin., 2017, 33(7): 1462-1473.
[6] ZHEN Xu, GUO Xue-Jing. Synthesis and Lithium Storage Performance of Three-Dimensional Mesostructured ZnCo2O4 Cubes[J]. Acta Phys. Chim. Sin., 2017, 33(4): 845-852.
[7] QUAN Quan, XIE Shun-Ji, WANG Ye, XU Yi-Jun. Photoelectrochemical Reduction of CO2 Over Graphene-Based Composites:Basic Principle,Recent Progress,and Future Perspective[J]. Acta Phys. Chim. Sin., 2017, 33(12): 2404-2423.
[8] XIONG Wen-Hui, ZHANG Wen-Chao, YU Chun-Pei, SHEN Rui-Qi, CHENG Jia, YE Jia-Hai, QIN Zhi-Chun. Preparation of Nanoporous CoFe2O4 and Its Catalytic Performance during the Thermal Decomposition of Ammonium Perchlorate[J]. Acta Phys. Chim. Sin., 2016, 32(8): 2093-2100.
[9] WANG Juan, LI Shi-Kun, ZHAO Zhen-Chao, ZHOU Dan-Hong, LU An-Hui, ZHANG Wei-Ping. Density Functional Theory Study of CO2 Adsorption in Amine-Functionalized Carbonaceous Materials[J]. Acta Phys. Chim. Sin., 2016, 32(7): 1666-1673.
[10] GUO Xing-Zhong, DING Li, YU Huan, SHAN Jia-Qi, YANG Hui. Construction and Preparation Mechanism of Hierarchically Porous SiO2 Monoliths[J]. Acta Phys. Chim. Sin., 2016, 32(7): 1727-1733.
[11] CHEN Feng-Feng, DONG Yan, SANG Xiao-Yan, ZHOU Yan, TAO Duan-Jian. Physicochemical Properties and CO2 Solubility of Tetrabutylphosphonium Carboxylate Ionic Liquids[J]. Acta Phys. Chim. Sin., 2016, 32(3): 605-610.
[12] HU Hai-Feng, HE Tao. Controllable Modulation of Morphology and Photocatalytic Performance of ZnO Nanomaterials via pH Adjustment[J]. Acta Phys. Chim. Sin., 2016, 32(2): 543-550.
[13] ZHAO Shu-Heng, LANG Lin, JIANG Jun-Fei, YIN Xiu-Li, WU Chuang-Zhi. Synthesis and Low-Temperature Detemplation of High-Silica MFI Zeolite Membranes[J]. Acta Phys. Chim. Sin., 2016, 32(2): 519-526.
[14] LIU Dan, HU Yan-Yan, ZENG Chao, QU De-Yu. Soft-Templated Ordered Mesoporous Carbon Materials: Synthesis, Structural Modification and Functionalization[J]. Acta Phys. Chim. Sin., 2016, 32(12): 2826-2840.
[15] LI Ji-Hong, LIN Chang-Feng, QIN Wu, XIAO Xian-Bin, WEI Li. Synergetic Effect of Mercury Adsorption on the Catalytic Decomposition of CO over Perfect and Reduced Fe2O3[001] Surface[J]. Acta Phys. Chim. Sin., 2016, 32(11): 2717-2723.