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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(05)>> 1269-1274     doi: 10.3866/PKU.WHXB201202242         中文摘要
PHYSICAL CHEMISTRY OF MATERIALS
Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon
TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian
Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China
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Because of the chemical reaction between Cr(VI) ions and glutathione, the peak reduction current of Cr(VI) ions decreases while adding glutathione (GSH) into a K2Cr2O7/H2SO4 solution. Thus the concentration of GSH can be detected indirectly by differential pulse voltammetry (DPV) analysis. This electrochemical indirect method was used to study the adsorption of GSH on multi-walled carbon nanotubes (MWCNTs) and activated carbon (AC), and can be used to determine the equilibrium relationship between GSH adsorption and its concentration. Unlike the result obtained from the active carbon, GSH adsorption on MWCNTs agrees better with that predicted by the Freundlich equation compared to that predicted by the Langmuir equation. The morphologies of MWCNTs and activated carbon were observed with scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The abundance of aggregated pores in MWCNTs is beneficial for the diffusion and adsorption of small GSH molecules, suggesting that MWCNTs could be developed as an adsorbent for small molecular substances.

Keywords: Electrochemical indirect measurement   Glutathione   MWCNTs   Activated carbon   Adsorption mechanism  
Received: 2011-11-28 Accepted: 2012-02-08 Publication Date (Web): 2012-02-24
Corresponding Authors: TANG Jing Email: jingtang@fzu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21073038, 21173048).

Cite this article: TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian. Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28 (05): 1269-1274.    doi: 10.3866/PKU.WHXB201202242
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