ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(06)>> 1467-1473     doi: 10.3866/PKU.WHXB201203312         中文摘要
Effect of Surface Acidity of CuO-SBA-15 on Adsorptive Desulfurization of Fuel Oils
SHAO Xin-Chao1, DUAN Lin-Hai1, WU Yu-Ye1, QIN Yu-Cai2, YU Wen-Guang1, WANG Yuan1, LI Huai-Lei1, SUN Zhao-Lin1, SONG Li-Juan1,2
1. Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning ShiHua University, Fushun 113001, Liaoning Province, P. R. China;
2. College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 257061, Shandong Province, P. R. China
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Solid-state grinding is a simple and effective technique to incorporate active species into the channels of mesoporous materials with different degrees of filling. Using this method, different concentrations of CuO were loaded into the mesochannels of as-prepared mesoporous silica (APS) and calcined SBA-15 (CS). The samples were prepared and characterized using X-ray diffraction (XRD), N2 physisorption, and Fourier transform infrared (FTIR) spectroscopy. The relative number of hydroxyl groups was studied by in situ FTIR spectroscopy, and the total surface acidity of the adsorbents was monitored by FTIR spectroscopy at 423 K using pyridine as a probe. Desulfurization of fluid catalytic cracking (FCC) fuel oils using these materials was investigated. The results suggest that CuO interacts directly with support hydroxyl groups to form [Si-O-Cu-O-Si] linkages in the mixtures, which can effectively constrain the condensation of hydroxyl groups in SBA-15 to improve the mesostructure of the adsorbents during calcination. Saturated coverage of the surface of APS is reached using 3 mmol·g-1 CuO. However, using CS, aggregation of CuO is observed in the material containing 3 mmol·g-1 of CuO. Both the surface acidity and desulfurization performance significantly increase upon modification of SBA-15 with CuO, and then decrease slowly as the concentration of CuO is increased. The sample containing 3 mmol·g-1 CuO shows the highest Lewis acidity and desulfurization performance. The Lewis acidity of the adsorbents matches the adsorptive desulfurization performance. It is also demonstrated that reduction of charge density around copper atoms helps to form Lewis acid sites.

Keywords: SBA-15 mesoporous material   Surface acidity   Hydroxyl group   Adsorptive desulfurization   Lewis acid  
Received: 2012-02-27 Accepted: 2012-03-29 Publication Date (Web): 2012-03-31
Corresponding Authors: SONG Li-Juan Email:

Fund: The project was supported by the National Natural Science Foundation of China (20976077, 21076100), National Key Basic Research Program of China (973) (2007CB216403), and Innovation Team of Liaoning Province Colleges, China.

Cite this article: SHAO Xin-Chao, DUAN Lin-Hai, WU Yu-Ye, QIN Yu-Cai, YU Wen-Guang, WANG Yuan, LI Huai-Lei, SUN Zhao-Lin, SONG Li-Juan. Effect of Surface Acidity of CuO-SBA-15 on Adsorptive Desulfurization of Fuel Oils[J]. Acta Phys. -Chim. Sin., 2012,28 (06): 1467-1473.    doi: 10.3866/PKU.WHXB201203312
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66. WANG Xiao-Hua; TAO Guo-Hong; WU Xiao-Mu; KOU Yuan.Investigation of the Acidity of Ionic Liquids by IR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2005,21(05): 528-533
67. HU Ren;SHI Hai-Yan;LIN Li-Wen;ZHUANG Yan-Yan;LIN Chang-Jian.The Crystal Growth Behavior of Hydroxyapatite Coating on Titanium Substrate under Electrochemical Deposition Conditions[J]. Acta Phys. -Chim. Sin., 2005,21(02): 197-201
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