准二维无定形碳结构的制备和结构表征

doi:10.3866/PKU.WHXB201205093

Abstract

Abstract:

Quasi-2-dimensional total amorphous and half-amorphous carbon structures are fabricated from single-layer or few-layer of graphene via high-energy electron beam irradiation. Sample structures before and after electron beam irradiation are recorded by high resolution imaging and coherent nano-area electron diffraction using transmission electron microscopy (TEM). The atomic pair distribution functions of the sample are obtained from electron diffraction patterns. In the quasi-2-dimensional amorphous carbon material, the carbon hexagonal ring structure is not the main structural feature anymore, and the low order nearest distances between carbon atoms are slightly different from that in perfect graphene. Although the sample shows a long-range disordered atomic arrangement, it still holds short-range order and even middle-range order extending to 0.5 nm, as many zigzag carbon chains remain after electron beam irradiation.

Key words: Graphene, Quasi-2 dimensional amorphous structure, Electron beam irradiation, High resolution imaging, Electron diffraction, Atomic pair distribution function

MSC2000:

O641

RAN Ke, CHEN Qing, ZUO Jian-Min. Fabrication and Structure Characterization of Quasi-2-Dimensional Amorphous Carbon Structures[J].Acta Phys. -Chim. Sin., 2012, 28(07): 1551-1555.

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Fabrication and Structure Characterization of Quasi-2-Dimensional Amorphous Carbon Structures

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