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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(09)>> 2214-2220     doi: 10.3866/PKU.WHXB201206122         中文摘要
PHYSICAL CHEMISTRY OF MATERIALS
Fabrication, Formation Mechanism and the Photocatalytic Properties of Hierarchical Porous Hematite Networks
FAN Hai-Bin, ZHANG Dong-Feng, GUO Lin
School of Chemistry and Environment, Beihang University, Beijing 100191, P. R. China
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Hierarchical porous hematite (HPH) network structures were successfully constructed using an improved polymerization induced colloid aggregation process with Fe(NO3)3·9H2O as the raw material. The polymerization between urea and formaldehyde into urea-formaldehyde (UF) resin is the key factor for this construction. The UF resins appear to be advantageous in two respects: the UF oligomer hybrids with ferric hydroxide (Fe-UF) and UF polymer formed microcapsules (UFM) acted as templates to induce the aggregation of Fe-UF hybrids into mesoporous spheres. The further crosslink reactions among the hybrid spheres generate the network structure. After calcination, the decomposition of the UF resin and the UFM produces nanopores in the nanorod subunits and macropores in the network structure, respectively. The photodegradation activity of the unique structured HPH is four times that of the commercial hematite nanoparticles with rhodamine B (RhB) as pollutant.



Keywords: α-Fe2O3   Hierarchical porous structure   Polymerization induced colloid aggregation method   Photodegradation  
Received: 2012-05-02 Accepted: 2012-06-11 Publication Date (Web): 2012-06-12
Corresponding Authors: ZHANG Dong-Feng, GUO Lin Email: dfzhang@buaa.edu.cn;guolin@buaa.edu.cn

Fund: The project was supported by the National Key Basic Research Program of China (973) (2010CB934700), National Natural Science Foundation of China (21173015), and Fundamental Research Funds for the Central Universities, China (YWF-11-03-Q-085).

Cite this article: FAN Hai-Bin, ZHANG Dong-Feng, GUO Lin. Fabrication, Formation Mechanism and the Photocatalytic Properties of Hierarchical Porous Hematite Networks[J]. Acta Phys. -Chim. Sin., 2012,28 (09): 2214-2220.    doi: 10.3866/PKU.WHXB201206122

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