过充保护添加剂1,2-二甲氧基-4-硝基苯和1,4-二甲氧基-2-硝基苯在锂离子电池中的应用

doi:10.3866/PKU.WHXB201206142

Abstract

Abstract:

1,2-Dimethoxy-4-nitro-benzene (DMNB1) and 1,4-dimethoxy-2-nitro-benzene (DMNB2) were selected as new redox shuttle additives for overcharge protection in lithium-ion batteries. The base electrolyte is 1 mol·L^-1 LiPF₆/(ethylene carbonate (EC)+diethyl carbonate (DEC)+ethyl-methyl carbonate (EMC) (1:1:1, by volume)). Cyclic voltammetry (CV), charge-discharge cycle performance, overcharge tests, electrochemical impedance spectra (EIS), and scanning electron microscopy (SEM) were used to investigate the electrochemical performances of DMNB1 and DMNB2. The overcharge protection of DMNB1 and DMNB2 on lithium-ion batteries and the compatibility of both additives with the LiNi_1/3CoMn_1/3O₂ electrode have been studied. The results show that the working potentials of the both additives are above 4.3 V (vs Li/Li⁺), and thus are suitable for overcharge protection in lithium-ion batteries. Lithium-ion batteries with DMNB1 and DMNB2 have an improved overcharging tolerance. DMNB1 shows better overcharge protective performance, in the 100% overcharge and 5 V cutoff voltage tests, than DMNB2. After 100 cycles at 0.2C rate, the capacity retention rates of the LiNi_1/3Co_1/3Mn_1/3O₂/Li cells with the base electrolyte and the electrolyte with DMNB1 and DMNB2 are 98.4%, 95.9%, and 68.1%, respectively. The electrochemical properties and the location of the nitro-group on the benzene of the overcharge protection additives are closely linked.

Key words: Overcharge, Redox, Dimethoxy-benzene, Electrolyte, Safety additive

MSC2000:

O646

REN Chun-Yan, LU Hai, JIA Ming, ZHANG Zhi-An, LAI Yan-Qing, LI Jie. Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries[J].Acta Phys. -Chim. Sin., 2012, 28(09): 2091-2096.

References

(1) Chen, Y. S.; Hu, C. C.; Li, Y. Y. J. Power Sources 2008, 181, 69.doi: 10.1016/j.jpowsour.2008.03.015
(2) Chen, L.; Buhrmester, C.; Dahn, J. R. Electrochem. Solid-State Lett. 2005, 8, A59.
(3) Balakrishnan, P. G.; Ramesh, R. T.; Kumar, P. J. Power Sources2006, 155, 401. doi: 10.1016/j.jpowsour.2005.12.002
(4) Lan, X.; Li, S. L.; Ai, X. P.; Yang, H. X.; Cao, Y. L. Energy Environ. Sci. 2011, 4, 2845. doi: 10.1039/c0ee00590h
(5) Kise, M.; Yoshioka, S.; Hamano, K.; Kuriki, H.; Nishimura, T.;Urushibata, H.; Yoshiyasu, H. J. Electrochem. Soc. 2005, 152,A1516.
(6) Chen, Z.; Amine, K. Electrochem Commun. 2007, 9, 703. doi: 10.1016/j.elecom.2006.11.002
(7) Watanabe, Y.; Yamazaki, Y.; Yasuda, K.; Morimoto, H.;Tobishima, S. I. J. Power Sources 2006, 160, 1375. doi: 10.1016/j.jpowsour.2006.03.007
(8) Zhang, S. S. J. Power Sources 2006, 162, 1379. doi: 10.1016/j.jpowsour.2006.07.074
(9) Guo, Y. J.; Chen, H.; Qi, L. Acta Phys. -Chim. Sin. 2007, 23 (supp.), 80. [郭营军, 晨辉, 其鲁. 物理化学学报, 2007,23 (supp.), 80.] doi: 10.3866/PKU.WHXB2007Supp17
(10) Wang, B.; Xia, Q.; Zhang, P.; Li, G. C.;Wu, Y. P.; Luo, H. J.;Zhao, S. Y.; Ree, T. Electrochem. Commun. 2008, 10, 727.doi: 10.1016/j.elecom.2008.02.011
(11) Xiong, L. Q.; Zhang, Y. J.; Dong, P.; Yang, R. M.; Xia, S. B.Chem. Ind. Eng. Prog. 2011, 30, 1198. [熊琳强, 张英杰, 董鹏, 杨瑞明, 夏书标. 化工进展, 2011, 30, 1198.]
(12) Xu, M. Q.; Xing, L. D.; Li,W. S.; Zuo, X. X.; Shu, D.; Li, G. L.J. Power Sources 2008, 184, 427. doi: 10.1016/j.jpowsour.2008.03.036
(13) Guo, Y. X.; Yin, Z. G.; Tao, Z. Y.; Li, X. H. Trans. Nonferrous Met. Soc. China 2008, 18, 2025. [郭永兴, 殷振国, 陶芝勇, 李新海. 中国有色金属学报, 2008, 18, 2025.]
(14) Zhang, Q. Y.; Qiu, C. C.; Fu, Y. B.; Ma, X. H. Chin. J. Power Sources 2009, 33, 774. [张千玉, 秋沉沉, 付延鲍, 马晓华. 电源技术, 2009, 33, 774.]
(15) Xiao, L.; Ai, X.; Cao, Y.; Yang, H. Electrochim. Acta 2004, 49,4189. doi: 10.1016/j.electacta.2004.04.013
(16) Buhrmester, C.; Moshurchak, L.;Wang, R. L.; Dahn, J. R.J. Electrochem. Soc. 2006, 153, A288.
(17) Wang, R. L.; Buhrmester, C.; Dahn, J. R. J. Electrochem. Soc.2006, 153, A445.
(18) Luo, H. J.; Zhang, X. G.; Chen, L. Chin. J. Power Sources 2012,36, 172. [骆宏钧, 张校刚, 陈黎. 电源技术, 2012, 36, 172]
(19) Feng, J. K.; Ai, X. P.; Cao, Y. L.; Yang, H. X. Electrochem. Commun. 2007, 9, 25. doi: 10.1016/j.elecom.2006.08.033
(20) Moshuchak, L. M.; Bulinski, M.; Lamanna,W. M.;Wang, R. L.;Dahn, J. R. Electrochem. Commun. 2007, 9, 1497. doi: 10.1016/j.elecom.2007.01.059
(21) Han, Y. K.; Jung, J.; Yu, S.; Lee, H. J. Power Sources 2009, 187,581. doi: 10.1016/j.jpowsour.2008.10.137
(22) Chen, Z.; Qin, Y.; Amine, K. Electrochim. Acta 2009, 54, 5605.doi: 10.1016/j.electacta.2009.05.017
(23) Li, T. T.;Wang, C. Y.; Xing, L. D.; Li,W. S.; Peng, B.; Xu, M.Q.; Gu, F. L.; Hu, S. J. Acta Phys. -Chim. Sin. 2012, 28, 818.[李田田, 王朝阳, 刑丽丹, 李伟善, 彭彬, 许梦清, 顾凤龙,胡社军. 物理化学学报, 2012, 28, 818.] doi: 10.3866/PKU.WHXB201201132
(24) Dahn, J. R.; Jiang, J.; Moshurchak, L. M.; Fleischauer, M. D.;Buhrmester, C.; Krause, L. J. Electrochem. Soc. 2005, 152,A1283.
(25) Weng,W.; Zhang, Z.; Redfern, P. C.; Curtiss, L. A.; Amine, K.J. Power Sources 2011, 196, 1530. doi: 10.1016/j.jpowsour.2010.08.049
(26) Zhang, S. S.; Xu, K.; Jow, T. R. Electrochim. Acta 2004, 49,1057. doi: 10.1016/j.electacta.2003.10.016
(27) Zhang, S. S. J. Power Source 2007, 163, 713. doi: 10.1016/j.jpowsour.2006.09.040

[1]	Hao-Tian Teng, Wen-Tao Wang, Xiao-Feng Han, Xiang Hao, Ruizhi Yang, Jing-Hua Tian. Recent Development and Perspectives of Flexible Zinc-Air Batteries [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2107017-0.
[2]	Nanxiang Zhang, Zhuangzhuang Wei, Tao Feng, Feng Wu, Teng Zhao, Renjie Chen. Voltage-Sensitive Polytriphenylamine-Modified Separator for Over-Charge Protection in Li-S Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2107009-.
[3]	Guangtao Cong, Yi-Chun Lu. Strategies to Improve the Energy Density of Non-Aqueous Organic Redox Flow Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2106008-.
[4]	Zheng Bo, Jing Kong, Huachao Yang, Zhouwei Zheng, Pengpeng Chen, Jianhua Yan, Kefa Cen. Ultra-Low-Temperature Supercapacitor Based on Holey Graphene and Mixed-Solvent Organic Electrolyte [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2005054-.
[5]	Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912061-.
[6]	Zixu He, Yawei Chen, Fanyang Huang, Yulin Jie, Xinpeng Li, Ruiguo Cao, Shuhong Jiao. Fluorinated Solvents for Lithium Metal Batteries [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2205005-.
[7]	Yuanhao Shen, Qingyu Wang, Jie Liu, Cheng Zhong, Wenbin Hu. Spontaneous Reduction and Adsorption of K₃[Fe(CN)₆] on Zn Anodes in Alkaline Electrolytes: Enabling a Long-Life Zn-Ni Battery [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2204048-0.
[8]	Liliang Tian, Weiqi Zhang, Zheng Xie, Kai Peng, Qiang Ma, Qian Xu, Sivakumar Pasupathi, Huaneng Su. Enhanced Performance and Durability of High-Temperature Polymer Electrolyte Membrane Fuel Cell by Incorporating Covalent Organic Framework into Catalyst Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009049-.
[9]	Jujia Zhang, Jin Zhang, Haining Wang, Yan Xiang, Shanfu Lu. Advancement in Distribution and Control Strategy of Phosphoric Acid in Membrane Electrode Assembly of High-Temperature Polymer Electrolyte Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2010071-.
[10]	Bingyan Xu, Ying Zhang, Yecan Pi, Qi Shao, Xiaoqing Huang. Research Progress of Nickel-Based Metal-Organic Frameworks and Their Derivatives for Oxygen Evolution Catalysis [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009074-.
[11]	Yongli Heng, Zhenyi Gu, Jinzhi Guo, Xinglong Wu. Research Progresses on Vanadium-Based Cathode Materials for Aqueous Zinc-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(3): 2005013-.
[12]	Gaolong Zhu, Chenzi Zhao, Hong Yuan, Haoxiong Nan, Bochen Zhao, Lipeng Hou, Chuangxin He, Quanbing Liu, Jiaqi Huang. Liquid Phase Therapy with Localized High-Concentration Electrolytes for Solid-State Li Metal Pouch Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2005003-.
[13]	Chen Wu, Ying Zhou, Xiaolong Zhu, Minzhi Zhan, Hanxi Yang, Jiangfeng Qian. Research Progress on High Concentration Electrolytes for Li Metal Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008044-.
[14]	Zhida Wang, Yuancheng Feng, Songtao Lu, Rui Wang, Wei Qin, Xiaohong Wu. Improvement in Performance of Three-Dimensional SnLi/Carbon Paper Anode in Lean Electrolyte with In Situ Fluorinated Protection Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008082-.
[15]	Guangbin Hua, Yanchen Fan, Qianfan Zhang. Application of Computational Simulation on the Study of Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008089-.

Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0