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Acta Phys. Chim. Sin.
CATALYSIS AND SURFACE SCIENCE     
Fabrication of Bi2O3/Bi2O3 Nanotube Arrays with High Visible-Light Photocatalytic Activity by Impregnation-Decomposition Method
DAI Gao-Peng, LIU Su-Qin, PENG Rong, LUO Tian-Xiong
School of Chemical Engineering and Food Science, Hubei University of Arts and Science, Xiangyang 441053, Hubei Province, P. R. China
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Abstract  

Bi2O3/TiO2 nanotube arrays (NTs) were prepared by depositing Bi2O3 nanoparticles (NPs) onto the tube wall of self-organized TiO2 NTs using an impregnation-decomposition method. Chemical composition of the resulting Bi2O3/TiO2 NTs was determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and UV-visible (UV-Vis) diffuse reflectance spectroscopy. Photocatalytic activity was evaluated by degradation of aqueous methyl orange (MO) solution under visible-light irradiation (λ>400 nm). The Bi2O3 nanoparticles were found to be uniformly deposited into the nanotubes. Bi2O3/TiO2 NTs exhibited much higher visible-light activity than pure Bi2O3 films and N-TiO2 NTs, which was attributed to synergistic effects of the strong visible-light absorption of Bi2O3/TiO2 NTs and the heterojunction formed between Bi2O3 and TiO2.



Key wordsBi2O3/TiO2 nanotube array      Visible light      Photocatalysis      Heterojunction      Synergetic effect     
Received: 28 May 2012      Published: 04 July 2012
MSC2000:  O644  
Fund:  

The project was supported by the Research Program of Hubei Province Department of Education, China (T201215, Q20122507).

Cite this article:

DAI Gao-Peng, LIU Su-Qin, PENG Rong, LUO Tian-Xiong. Fabrication of Bi2O3/Bi2O3 Nanotube Arrays with High Visible-Light Photocatalytic Activity by Impregnation-Decomposition Method. Acta Phys. Chim. Sin., 2012, 28(09): 2169-2174.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201207041     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2012/V28/I09/2169

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