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Acta Phys. Chim. Sin.
ELECTROCHEMISTRY AND NEW ENERGY     
Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors
ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China
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Abstract  

A novel room temperature organosilicon ionic liquid (SiN1IL) was synthesized and its chemical structure and electrochemical window were characterized. The ionic conductivity of SiN1IL/propylene carbonate (PC)/acetonitrile (AN) solution was 19.6 mS·cm-1, comparable with the commercial electrolytes currently used in supercapacitors. The electrochemical performance of the cells using activated carbon as electrodes and SiN1IL-based formula with PC/AN as electrolytes was systematically evaluated. SiN1IL/PC electrolyte exhibited superior rate capability and lower impedance compared to a conventional electrolyte (tetraethylammonium tetrafluoroborate (Et4NBF4)/PC). Upon applying a working voltage of 2.7 V, the SiN1IL/PC cell had a specific capacitance of 108 F·g-1 at a current density of 1000 mA·g-1.



Key wordsOrganosilicon      Ionic liquid      Supercapacitor      Electrolyte      Activated carbon     
Received: 02 July 2012      Published: 18 July 2012
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (50973112); Science and Technology Plan Project of Guangzhou Municipality, China (11A44061500); Chinese Academy of Sciences -Guangdong Collaboration Program (2010(8)); and the Hundred Talents Program of Chinese Academy of Sciences (CAS).

Cite this article:

ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi. Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors. Acta Phys. Chim. Sin., 2012, 28(11): 2641-2647.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201207181     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2012/V28/I11/2641

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