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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(11)>> 2641-2647     doi: 10.3866/PKU.WHXB201207181         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors
ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China
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A novel room temperature organosilicon ionic liquid (SiN1IL) was synthesized and its chemical structure and electrochemical window were characterized. The ionic conductivity of SiN1IL/propylene carbonate (PC)/acetonitrile (AN) solution was 19.6 mS·cm-1, comparable with the commercial electrolytes currently used in supercapacitors. The electrochemical performance of the cells using activated carbon as electrodes and SiN1IL-based formula with PC/AN as electrolytes was systematically evaluated. SiN1IL/PC electrolyte exhibited superior rate capability and lower impedance compared to a conventional electrolyte (tetraethylammonium tetrafluoroborate (Et4NBF4)/PC). Upon applying a working voltage of 2.7 V, the SiN1IL/PC cell had a specific capacitance of 108 F·g-1 at a current density of 1000 mA·g-1.



Keywords: Organosilicon   Ionic liquid   Supercapacitor   Electrolyte   Activated carbon  
Received: 2012-07-02 Accepted: 2012-07-18 Publication Date (Web): 2012-07-18
Corresponding Authors: Email: lzzhang@ms.giec.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (50973112); Science and Technology Plan Project of Guangzhou Municipality, China (11A44061500); Chinese Academy of Sciences -Guangdong Collaboration Program (2010(8)); and the Hundred Talents Program of Chinese Academy of Sciences (CAS).

Cite this article: ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi. Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28 (11): 2641-2647.    doi: 10.3866/PKU.WHXB201207181

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73. CHEN Qiang, NULI Yanna, YANG Jun, KAILIBINUER Kerimu, WANG Jiulin.Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2625-2631
74. ZHU Xu-Fei, HAN Hua, MA Hong-Tu, LU Chao, QI Wei-Xing, XU Chen.Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2648-2658
75. SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
76. WANG Ding, TIAN Guo-Cai.Simulation Study of the Effect ofMethanol on the Structure and Properties of 1-Butyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2558-2566
77. HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
78. REN Chun-Yan, LU Hai, JIA Ming, ZHANG Zhi-An, LAI Yan-Qing, LI Jie.Application of 1,2-Dimethoxy-4-nitro-benzene and 1,4-Dimethoxy- 2-nitro-benzene as Overcharge Protection Additives in Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2091-2096
79. SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
80. PING Li-Na, ZHENG Jia-Ming, SHI Zhi-Qiang, WANG Cheng-Yang.Electrochemical Performance of Lithium Ion Capacitors Using Li+-Intercalated Mesocarbon Microbeads as the Negative Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1733-1738
81. ZHAO Xue-Yan, CAO Yu-Rong, CAO Gui-Rong, XIAO Rui-Jie.Lamellar Liquid Crystalline Phase Formed by Triblock Copolymer L64 in 1-Butyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1411-1417
82. TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian.Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1269-1274
83. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
84. ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan.Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(04): 923-927
85. LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
86. GONG Yan-Yan, LIU Min, JIA Song-Yan, FENG Jian-Ping, SONG Chun-Shan, GUO Xin-Wen.Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(03): 686-692
87. ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping.Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28(02): 373-380
88. ZHU Ying-Hong, ZENG Hong-Yan, LI Shan-Shan, LU Zai-Xiang, MA Chun-An.Electrochemical Oxidation of p-Methoxy Toluene in BMIMBF4 Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(02): 421-426
89. SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
90. CHEN Xiao-Yun, LU Dong-Fang, HUANG Jin-Feng, LU Yan-Feng, ZHENG Jian-Qiang.Preparation and Properties of N-F Co-Doped TiO2 Photocatalyst with Wide Range Light Response and Multipore Structure from Ionic Liquid-Water Mixture Solvent[J]. Acta Phys. -Chim. Sin., 2012,28(01): 161-169
91. GAO Li-Xia, WANG Li-Na, QI Tao, YU Jiang.Preparation of Ni and Ni-Al Alloys from 2AlCl3/Et3NHCl Ionic Liquid by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2012,28(01): 111-120
92. XU San-Kui, LI Li-Min, GUO Nan-Nan, SU Yun-Lai, ZHANGPeng.Hydrogenation of Glucose Using Ru/Activated Carbon Catalysts: Effects of Modification Methods on Surface Properties of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2012,28(01): 177-183
93. LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs.Dynamic Viscosity and Conductivity of Ionic Liquids [Cnpy][NTf2] (n=2, 4, 5)[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2762-2766
94. GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
95. LIU Li, TIAN Fang-Hua, WANG Xian-You, ZHOU Meng.Electrochemical Behavior of LiV3O8 in Aqueous Li2SO4 Solution[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2600-2604
96. LIU Yan, WEI Zhong-Ling, YANG Fu-Wei, ZHANG Zhao.Anodizing of AZ91D Magnesium Alloy in Borate-Terephthalic Acid Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2385-2392
97. XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
98. LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
99. LI Wei, QI Chuan-Song, WU Xin-Min, RONG Hua, GONG Liang-Fa.Relationship between Melting Point and the Interaction Energy of Alkyl Imidazolium Tetrafluoroborate Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2059-2064
100. LU Sheng-Yong, HUANG Yi-Long, WANG Qiu-Lin, LI Xiao-Dong, YAN Jian-Hua.Photocatalytic Degradation of Gaseous 1,2-Dichlorobenzene over TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2191-2199
101. FU Su-Zhen, CHEN Qing-De, SHEN Xing-Hai.Aggregation Behavior of 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids in Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1913-1918
102. LIU Yu-Sheng, FU Hai-Ying, TANG Zhong-Feng, HUANG Wei, WU Guo-Zhong.Melting Point and Structure of Ionic Liquid [EMIM][PF6] on the Surface of Nano-SiOx Particles[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1725-1729
103. CAO Guo-Fei, LIAO Yi, ZHANG Xiao-Hua, CHEN Jin-Hua.Preparation and Characterization of Peasecod-Based Activated Carbons as Electrode Materials for Electrochemical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1679-1684
104. ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
105. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
106. LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu.Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2011,27(05): 995-999
107. SHAN Zhi-Chao, LIU Si-Yu, LI Cai-Jin, ZHU Long-Feng, MENG Xiang-Ju, XIAO Feng-Shou.High-Temperature Synthesis of Zeolite Y[J]. Acta Phys. -Chim. Sin., 2011,27(04): 959-964
108. ZHU Guang-Lai, WU Guo-Zhong, CUI Zhi-Feng, XU Xin-Sheng.Transient Absorption Spectroscopy of the Effects of the Ionic Liquid [bmim][BF4] on the Photochemical Reactions of Benzil[J]. Acta Phys. -Chim. Sin., 2011,27(04): 971-976
109. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
110. ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long.Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Phys. -Chim. Sin., 2011,27(03): 705-710
111. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
112. LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
113. ZHANG Qi-Bo, HUA Yi-Xin.Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution[J]. Acta Phys. -Chim. Sin., 2011,27(03): 655-663
114. SUN Gang-Wei, SONG Wen-Hua, LIU Xiao-Jun, QIAO Wen-Ming, LING Li-Cheng.Asymmetric Capacitance Behavior Based on the Relationship between Ion Dimension and Pore Size[J]. Acta Phys. -Chim. Sin., 2011,27(02): 449-454
115. TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
116. ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
117. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia, ZHANG Jin-Qiu.Cathodic and Thermal Stabilities of the P(VdF-HFP)-Based Ionic Liquid Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(01): 78-84
118. ZHANG Qi-Bo, HUA Yi-Xin.Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Phys. -Chim. Sin., 2011,27(01): 149-155
119. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
120. ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
121. LI Huan-Zhi, TANG Ya-Wen, LU Tian-Hong.Effect of NH4+ on the Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3199-3202
122. ZHANG Li-Qun, LI Hao-Ran.Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2877-2889
123. PAN Shan-Fei, HU Gui-Xiang, LV Yang, ZOU Jian-Wei, YU Qing-Sen.QSPRModel Analysis on the Solubility of Organic Compounds in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2494-2502
124. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
125. CAO Hai, JIANG Jian, ZHU Xue-Feng, DUAN Peng-Fei, LIU Ming-Hua.Interfacial Assembly of Diethyl Ester Glutamic Acid Terminated Bolaamphiphile at the Air/Water Interface: Chiral Interaction and Morphology[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1842-1846
126. LIANG Rui, YANG Mei-Rong, ZHOU Qing-Xiang.Thermal Stability, Equilibrium Vapor Pressure and Standard Enthalpy of Vaporization of 1-Butyl-3-methylimidazolium Tetrafluoroborate[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1468-1472
127. LIU Qing-Shan, YANG Miao, TAN Zhi-Cheng, WELZ-BIERMANN Urs.Estimation and Prediction of the Physicochemical Properties of Imidazolium-Based Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1463-1467
128. LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
129. JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
130. ZHAO Di, HUANG Qing, JIN Xian-Bo, WEI Xian-Jun, CHEN George Z..Capacitance at the Electrode/Ionic Liquid Interface[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1239-1248
131. DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen.Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1311-1316
132. LI Xue-Liang, CHEN Jie-Jie, LUO Mei, CHEN Xiang-Ying, LI Pei-Pei.Quantum Chemical Calculation of Hydroxyalkyl Ammonium Functionalized Ionic Liquids for Absorbing SO2[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1364-1372
133. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia.Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO4 Cathode[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1233-1238
134. WANG Wei, LV Rong, YU An-Chi.Low Frequency Spectrumof Ionic Liquid [bmim][PF6] Studied by Femtosecond Optically Heterodyne-Detected Optical Kerr Effect Spectroscopy and Low Frequency Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(04): 964-970
135. YUAN Li-Yong, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin.Radiation-Induced Changes of Phase Behavior and Fluorescence Properties of the Ionic Liquids [C4mim][PF6] and [C4mim][NTf2][J]. Acta Phys. -Chim. Sin., 2010,26(04): 981-987
136. YUAN Xiao, LOU Shu-Jie, KOU Yuan.Ionic Liquid and Water: Making Nanoparticle Catalysis More Efficient and Greener[J]. Acta Phys. -Chim. Sin., 2010,26(04): 908-914
137. ZHANG Tian-Yong, YANG Qiu-Sheng, SHI Hui-Xian, HAN Cong, LIU Xu.Adsorption of Naphthalene on a Viscose-Based Activated Carbon Fiber[J]. Acta Phys. -Chim. Sin., 2010,26(02): 367-372
138. ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
139. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
140. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
141. WANG Wei-Bin, YIN Jian-Zhong, SUN Li-Hua, FENG En-Min.Molecular Dynamics Simulation of Thermodynamic Properties for CO2/Ionic Liquid Systems[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2291-2295
142. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
143. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
144. FU Mao-Hua, HUANG Ke-Long, LIU Su-Qin, LIU Jian-Sheng, LI Yong-Kun.Effect of Lithium Difluoro(oxalato)borate on the High-Temperature Performance of LiFePO4/Graphite Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1985-1990
145. TAN Xiao-Lan, CHENG Xin-Qun, MA Yu-Lin, ZUO Peng-Jian, YIN Ge-Ping.Film Formation and Cycleability of LiBOB-Based Electrolyte[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1967-1971
146. WU Yang, ZHANG Tian-Tian, YU Ning.Interaction between 1-Ethyl-3-Methyl-Imidazolium Cation and Asparagine Anion[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1689-1696
147. ZHAI Cui-Ping, LIU Xue-Jun, ZHAO Yang, WANG Jian-Ji.NMR Study on the Aggregation of [C4mim][BF4] in D2O and CDCl3[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1185-1189
148. GAO Hong-Quan, LAI Yan-Qing, ZHANG Zhi-An, LIU Ye-Xiang.Electrochemical Behaviors of New Lithium Salt LiBC2O4F2 in EC+DMC Solvents[J]. Acta Phys. -Chim. Sin., 2009,25(05): 905-910
149. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
150. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
151. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
152. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
153. YAN Chao-Qun, WAN Hui, GUAN Guo-Feng.Prediction of Melting Points for 1,3-Disubstituent Imidazolium Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2198-2202
154. WANG Xiao-Lu; WAN Hui; GUAN Guo-Feng.Structure and Interaction of Ion-Pairs of [EPy]Cl and [EPy]Br in Gas and Liquid Phases[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2077-2082
155. YANG Pei-Xia; AN Mao-Zhong; SU Cai-Na; WANG Fu-Ping.Electrodeposition Behaviors of Pure Cobalt in Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2032-2036
156. ZHENG Yong-Jun; ELI Wumanjiang.Phase Behavior of Tween80/BmimPF6/Alcohol/Toluene Systems[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2143-2148
157. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
158. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
159. ZHANG Xu-Zhi; JIAO Kui.Single-Walled Carbon Nanotubes and RoomTemperature Ionic Liquid Composite Film Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1439-1444
160. LI Fan-Qun; LAI Yan-Qing; ZHANG Zhi-An; GAO Hong-Quan; YANG Juan.Electrochemical Behaviors of Et4NBF4+LiPF6/EC+PC+DMC Electrolyte on Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1302-1306
161. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
162. GAO Li-Xia; WANG Li-Na; QI Tao; LI Yu-Ping; CHU Jing-Long; QU Jing-Kui.Electrodeposition of Aluminium from AlCl3/Et3NHCl Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2008,24(06): 939-944
163. GUO Liang; WU Zhan-Song.Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24(05): 737-742
164. LI Wei; RONG Hua; WU Xin-Min; CHEN Zhong-Yuan.Microwave Synthesis, Characterization and Theoretical Study of para-Toluenesulfonic Acid Threonine Salt and Its Ester Derivatives[J]. Acta Phys. -Chim. Sin., 2008,24(05): 868-872
165. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
166. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
167. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
168. SUN Guo-Hua; LI Kai-Xi; FAN Hui; GU Jian-Yu; LI Qiang; LIU Yue.Eelectrochemical Performance of Capacitors Using [BMIm]BF4/Fc as Electrolyte[J]. Acta Phys. -Chim. Sin., 2008,24(01): 103-108
169. GUO Ying-Jun; LI Qi-Qi-Ge; NING Ying-Kun; QI Lu; TANG Hong-Wu.Performance of Liquid Electrolyte for Lithium-ion Battery at Elevated-temperature[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 1-4
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171. LEI Sheng; ZHANG Jing; HUANG Jian-Bin.Promotion of the Surface Activity and Aggregation Ability of Sodium Dodecylsulfate in Aqueous Solution by Ionic Liquid 1-butyl-3-methyl-imidazolium Tetrafluoroborate[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1657-1661
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174. WANG Jin-Bo; MING Fang-Yong; JIANG Wei-Dong; FAN Guang-Yin; LIU De-Rong; CHEN Hua; LI Xian-Jun.Asymmetric Hydrogenation of Acetophenone and Its Derivatives Catalyzed by Ruthenium Nanoparticles in Ionic Liquid Media[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1381-1386
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177. YAN Zhi-Ying; WU Li-Yan; SUN Gui-Xiang; ZHANG Ning; ZHENG Wen-Jun.Structural Characterization of Nanocrystalline TiO2 fromIonic Liquid-Water Solvent Mixture and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1032-1036
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