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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(10)>> 2327-2335     doi: 10.3866/PKU.WHXB201207303         中文摘要
CATALYSIS AND SURFACE SCIENCE
Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials
WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
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Many organic compounds will spontaneously disperse on the surface of a solid support to form monolayers, in a manner similar to that of inorganic salts and oxides, and numerous materials with useful properties can be designed and prepared based on this phenomenon. The dispersion behavior and orientation of organic compounds in monolayers depend not only on the molecular structure of organic compounds but also on the surface features and pore structure of the support. This short review summarizes the applications of monolayer-dispersed organic compounds in the preparation and texture control of related materials, including carbon/oxide composites, various other oxides, and mesoporous carbon with thin pore walls. Pyrolysis of organic monolayers can be used to prepare carbon/oxide composites with a uniformly thin carbon layer for use as photocatalysts, catalyst supports, and adsorbents for dyes. During the sol-gel preparation of porous oxides, organic monolayers can also prevent the aggregation of sol particles, thus producing oxides with high specific surface areas and adjustable pore volumes; γ-Al2O3 with a specific surface area as high as 506 m2·g-1 can be prepared in this manner. During calcining under an inert atmosphere, the carbon layer in the aforementioned carbon/oxide composites can significantly inhibit the phase transformation of oxides. Calcining carbon/γ-Al2O3 in oxygen at high temperatures, however, results in a rapid γ to α phase transformation. The oxides in these composites can also act as templates for the preparation of carbon materials. Dissolving the support oxides is a convenient method for the preparation of mesoporous carbon materials with high specific surface areas, large pore volumes, high mesopore ratios, and thin pore walls. The morphology and size distribution of pores in these carbon materials can be controlled by choosing oxides with different textures.



Keywords: Monolayer dispersion   Material preparation   Carbon/oxide composites   High-surface -area oxides   Phase transformation inhibition   Mesoporous carbon materials  
Received: 2012-06-28 Accepted: 2012-07-27 Publication Date (Web): 2012-07-30
Corresponding Authors: Email: zhuyx@pku.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (20773004) and National Key Basic Research Program of China (2011CB808702).

Cite this article: WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang. Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials[J]. Acta Phys. -Chim. Sin., 2012,28 (10): 2327-2335.    doi: 10.3866/PKU.WHXB201207303

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40. Guo Hui-Fen;Zhang Zhong-Suo;Liu Bing;Zhang Xing-Tang;Li Yun-Cai;Huang Ya-Bin;Du Zu-Liang.Preparation and Structure Phase Transition of Ba1-xSrxTiO3 by Sol-gel Technique[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1005-1009
41. Chen Dong-Liang;Hu Yu-Hai;Chen Yi;Zhang Xin-Yi;Wei Shi-Qiang.Monolayer Dispersive CuO/γ-Al2O3 Catalyst Studied by XAFS[J]. Acta Phys. -Chim. Sin., 2003,19(06): 519-522
42. Liang Jian;Huang Hui-Zhong;Xie You-Chang.The Phases of ZrO2-Al2O3 Composites with High Specific Surface Prepared by Co-precipitation[J]. Acta Phys. -Chim. Sin., 2003,19(01): 30-34
43. Wang Wen-Qing;Sun Lin;Min Wei;Wang Zhe-Ming.A Debate on the Parity-Violating Energy Difference of D-and L-Alanine[J]. Acta Phys. -Chim. Sin., 2002,18(10): 871-877
44. Wang Wen-Qing;Liang Zhi.From Parity to Chirality——Experimental Search for Parity-viola-ting Energy Difference of Alanine and Valine Enantiomers[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1077-1085
45. Wang Gong-Ming;Ai Hui;Liu Xiu;Wang Wen-Jun;Tao Feng-Gang.Investigation of Suitable LangmuirBlodgett Multilayers Structure for Optical Double Frequency Waveguide Application[J]. Acta Phys. -Chim. Sin., 2001,17(11): 995-999
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47. Wang Li, Bian Xiu-Fang, Li Hui.Liquid-Solid Transition and Crystal Growth of Metal Cu by Molecular Dynamics Simulation[J]. Acta Phys. -Chim. Sin., 2000,16(09): 825-829
48. Xu Hua, Shao Jun.Molecular Dynamics Simulation of the Phase Transition of α-berlinite under High Pressure[J]. Acta Phys. -Chim. Sin., 2000,16(06): 512-516
49. Wei Wei, Duan Lian-Yun, Xie You-Chang.Dispersion of Urea in Natural Clinoptilolite[J]. Acta Phys. -Chim. Sin., 2000,16(05): 472-475
50. Wei Qing-Li, Hou Zhe, Li Yan-Ni, Chen Lan, Cai Zun-Sheng, Zhao Xue-Zhuang.Modulation Induced Nonlinear Phase Transitions of Small Amplitude Oscillation in CSTR-BZ Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(04): 338-344
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52. Wang Bang-Ning, Han Bu-Xing, Tan Fu.Effects of Sugars on the Hydrated DHPE Phsae Transitions[J]. Acta Phys. -Chim. Sin., 1999,15(06): 545-549
53. He Xu, Zhu Bu-Yao, Zhao Guo-Xi.Influence of pH on the Properties of the Vesicles and Foams in the Aqueous Dispersion of 2RNC2[J]. Acta Phys. -Chim. Sin., 1998,14(10): 932-935
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55. Wu Fu-Gen, Zhan Ye-Hong, Wu Ting-Wan, Ou Fa.The Fluctuation of Bistability in Chemical Reactions[J]. Acta Phys. -Chim. Sin., 1998,14(07): 659-663
56. Wang Bang-Ning, Tan Fu.DSC Study of the Interactions of Phospholipid DHPC and Gramicidin D[J]. Acta Phys. -Chim. Sin., 1998,14(06): 548-551
57. Zeng Jian-Qing, Zhang Jing-Cheng, Zhong Bing.Monte Carlo Simulation of the Phase Transition and Self-oscillation in A+B2 Surface Catalytic Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(02): 103-108
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59. Wang Bang-Ning,Tan Fu.Homologous Linear Rules of Thermodynamic Parameters of Phase Transitions of Phosphatidylcholines[J]. Acta Phys. -Chim. Sin., 1997,13(05): 473-476
60. Chen Ke-Zheng,Zhang Zhi-Kun,Cui Zuo-Lin,Yang Da-Zhi.Study on the Phase-transformation of Nono-fibre[J]. Acta Phys. -Chim. Sin., 1997,13(04): 311-316
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