基于稀土金属离子配位超分子聚合物的荧光微囊

doi:10.3866/PKU.WHXB201208131

Acta Phys. -Chim. Sin. ›› 2012, Vol. 28 ›› Issue (10): 2291-2297.doi: 10.3866/PKU.WHXB201208131

• SOFT MATTER • Previous Articles Next Articles

Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions

WANG Jia-Rui, YANG Yang, YAN Yun, HUANG Jian-Bin

Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received:2012-07-20 Revised:2012-08-07 Published:2012-09-26
Supported by:
The project was supported by the President Foundation of Peking University and National Natural Science Foundation of China (20903005, 21173011, 51121091, 21073006).

Abstract

Abstract:

Fluorescent microcapsules based on coordination supramolecular polymers of rare earth metal ions were prepared via a layer-by-layer technique that used electrostatic interaction. The holes in the capsule walls were very small, which reduced leakage of small molecular payloads. The capsules remained intact at salt concentrations as high as 500 mmol·L^-1, which shows they have potential in practical applications. Multicolored capsules were obtained simply using a mixture of terbium and europium ions.

Key words: Layer-by-layer assembly, Fluorescent capsule, Metallic coordination supramolecular polymer

MSC2000:

O648

WANG Jia-Rui, YANG Yang, YAN Yun, HUANG Jian-Bin. Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2291-2297.

References

(1) Manners, I. Science 2001, 294, 1664. doi: 10.1126/science.1066321
(2) Takae, S.; Miyata, K.; Oba, M.; Nishiyama, N.; Itaka, K.;Yamasaki, Y.; Koyama, H.; Kataoka, K. J. Am. Chem. Soc.2008, 130, 6001. doi: 10.1021/ja800336v
(3) Berret, J. F.; Schonbeck, N.; Gazeau, F.; Kharrat, D. E.; Sandre,O.; Vacher, A.; Airiau, M. J. Am. Chem. Soc. 2006, 128, 1755.doi: 10.1021/ja0562999
(4) Schubert, U. S.; Newkome, G. R.; Manners, I. Metal-Containing and Metallo-Supramolecular Polymers and Materials, Vol. 928;ACS:Washington DC, 2006.
(5) Burnworth, M.; Knapton, D.; Rowan, S. J.;Weder, C. J. Inorg. Org. Polym. Mater. 2007, 17, 97.
(6) Kurth, D. G.; Higuchi, M. Soft Matter 2006, 2, 915. doi: 10.1039/b607485e
(7) Yan, Y.; Huang, J. B. Coord. Chem. Rev. 2010, 254, 1072. doi: 10.1016/j.ccr.2009.12.024
(8) Caruso, F.; Schuler, C.; Kurth, D. G. Chem. Mater. 1999, 11,3394. doi: 10.1021/cm9911058
(9) Schutte, M.; Kurth, D. G.; Linford, M. R.; Colfen, H.;Mohwald, H. Angew. Chem. Int. Edit. 1998, 37, 2891. doi: 10.1002/(ISSN)1521-3773
(10) Song,W. X.; He, Q.; Mohwald, H.; Yang, Y.; Li, J. B.J. Controlled. Release 2009, 139, 160. doi: 10.1016/j.jconrel.2009.06.010
(11) Yang, L.; Ding, Y.; Yang, Y.; Yan, Y.; Huang, J. B.; de Keizer,A.; Cohen Stuart, M. A. Soft Matter 2011, 7, 2720.
(12) Vermonden, T. Macromolecules 2003, 36, 735.
(13) Antipov, A. A.; Shchukin, D.; Fedutik, Y.; Petrov, A. I.;Sukhorukov, G. B.; Mohwald, H. Colloids and Surfaces A: Physicochem. Eng. Aspects 2003, 224, 175. doi: 10.1016/S0927-7757(03)00195-X
(14) Gao, L.; Fei, J. B.; Zhao, J.; Cui,W.; Cui, Y.; Li, J. B. Chem. Eur. J. 2012, 18, 3185. doi: 10.1002/chem.v18.11
(15) Cui, J.W.; Zhang, R. J.; Lin, Z. G.; Li, L.; Jin,W. R. Dalton Trans. 2008, 7, 895.
(16) Lakowicz, J. R. Principles of Fluorescence Spectroscopy, 3rded.; Springer: Berlin, 2006; pp 101-103.
(17) Nogami, M.; Abe, Y. J. Non-Cryst. Solids 1996, 197, 73. doi: 10.1016/0022-3093(95)00621-4
(18) Capobianco, J. A.; Proulx, P. P.; Bettinelli, M.; Negrisolo, F.Phys. Rev. B 1990, 42, 5936. doi: 10.1103/PhysRevB.42.5936
(19) Kamphuis, M. M. J.; Johnston, A. P. R.; Such, G. K.; Dam, H.H.; Evans, R. A.; Scott, A. M.; Nice, E. C.; Heath, J. K.; Caruso,F. J. Am. Chem. Soc. 2010, 132, 15881. doi: 10.1021/ja106405c

[1]	Sheng-Jun ZHAO,Wei ZHANG,Hui-Ning DENG,Wei LIU. Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation [J]. Acta Phys. -Chim. Sin., 2016, 32(3): 723-727.
[2]	Chen Zhi-Chun;Xu Shan-Hao;Lin Han-Feng;Yang Shao-Ming;Lin Xian-Fu. Glucose Oxidase Modified Electrode Fabricated by Layer-by-layer Molecular Deposition [J]. Acta Phys. -Chim. Sin., 2004, 20(10): 1267-1270.

Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 2

Metrics

Comments

Recommended 10