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Acta Phys. Chim. Sin.
PHYSICAL CHEMISTRY OF MATERIALS     
Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies
LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei
Key Laboratory of Aerospace Materials and Performance,Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China
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Abstract  

Nickel nanoparticles-graphene (Ni-GNs) composites with two different morphologies were successfully synthesized by in situ chemical reduction, and the morphology-dependent electromagnetic absorption properties of the composites was investigated. By changing the sequence of the reactants are added during preparation, spherical and spinous spherical nickel nanoparticle-graphene composites were obtained. The structure, morphology, and microwave absorption properties of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vector network analysis (VNA). The results indicated that the spinous spherical nickel nanoparticle-graphene composites had better microwave absorption ability than the spherical nickel nanoparticle-graphene composites. This is due to the unique isotropic antenna morphology of the spinous spherical nickel nanoparticles in the composites, arising from the point discharge effect. This facile in situ chemical reduction method for the preparation of nickel nanoparticle-graphene composites to give different morphologies could be used for the preparation of other composites.



Key wordsGraphene      Nickel      Nanocomposite      Microwave absorption      In-situ chemical reduction method     
Received: 02 July 2012      Published: 29 August 2012
MSC2000:  O641  
  TB333  
Fund:  

The project was supported by the Aviation Science Foundation of China (20110251003).

Cite this article:

LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei. Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies. Acta Phys. Chim. Sin., 2012, 28(11): 2754-2760.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201208292     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2012/V28/I11/2754

(1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A.Science 2004, 306 (5696), 666. doi: 10.1126/science.1102896
(2) Chae, H. K.; Siberio-Perez, D. Y.; Kim, J.; Go, Y.; Eddaoudi,M.; Matzger, A. J.; Okeeffe, M.; Yaghi, O. M. Nature 2004, 427(6974), 523. doi: 10.1038/nature02311
(3) Sclladler, L. S.; Giammris, S. C.; Ajayan, P. M. Appl. Phys. Lett.1998, 73 (26), 3842.
(4) Zhang, Y. B.; Tan, J.W.; Stormer, H. L.; Kim, P. Nature 2005,438 (7065), 201. doi: 10.1038/nature04235
(5) Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.;Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008, 146 (9/10), 351.
(6) Balandin, A. A.; Ghosh, S.; Bao,W. Z.; Calizo, I.;Teweldebrhan, D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3),902. doi: 10.1021/nl0731872
(7) Reina, A.; Thiele, S.; Jia, X. T.; Bhaviripudi, S.; Dresselhaus, M.S.; Schaefer, J. A.; Kong, J. Nano Res. 2009, 2 (6), 509. doi: 10.1007/s12274-009-9059-y
(8) Berger, C.; Song, Z.; Li, X.;Wu, X. S.; Brown, N.; Naud, C.;Mayou, D.; Li, T.; Hass, J.; Marchhenkow, A. N.; Conrad, E. H.;First, P. N.; Heer,W. A. Science 2006, 312 (5777), 1191. doi: 10.1126/science.1125925
(9) Pei, S. F.; Zhao, J. P.; Du, J. H.; Ren,W.C.; Cheng, H. M.Carbon 2010, 48 (15), 4466. doi: 10.1016/j.carbon.2010.08.006
(10) Stankovich, S.; Piner, R. D.; Chen, X. Q.;Wu, N. Q.; Nguyen,S. T.; Ruoff, R. S. J. Mater. Chem. 2006, 16 (2), 155. doi: 10.1039/b512799h
(11) Stankovich, S.; Dikin, D. A.; Dommett, G. H.; Kohlhaas, K. M.;Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff,R. S. Nature 2006, 442 (7100), 282. doi: 10.1038/nature04969
(12) Niu, H. L.; Chen, Q.W.; Ning, M.; Jia, Y. S.;Wang, X, J.J. Phys. Chem. B 2004, 108 (13), 3996. doi: 10.1021/jp0361172
(13) An, Z. G.; Pan, S. L.; Zhang, J. J. J. Phys. Chem. C 2009, 113 (4), 1346. doi: 10.1021/jp809224j
(14) Zhao, H. T.; Han, X. J.; Zhang, L. F.;Wang, G. Y.;Wang, C.; Li,X. A.; Xu, P. Radiat. Phys. Chem. 2011, 80 (3), 390. doi: 10.1016/j.radphyschem.2010.11.007
(15) Ma, F.; Ma, J.; Huang, J. J.; Li, J. G. J. Magn. Magn. Mater.2012, 324 (2), 205. doi: 10.1016/j.jmmm.2011.08.013
(16) Wang, C.; Han, X. J.; Xu, P.;Wang, J. Y.; Du, Y. C.;Wang, X.H.; Qin,W.; Zhang, T. J. Phys. Chem. C 2010, 114 (7), 3196.doi: 10.1021/jp908839r
(17) Deng, Y. D.; Zhao, L.; Shen, B.; Liu, L.; Hu,W. B. J. Appl. Phys. 2006, 100 (1), 014304. doi: 10.1063/1.2210187
(18) Zhao, J. P.; Pei, S. F.; Ren,W. C.; Gao, L. B.; Cheng, H. M. ACS Nano 2010, 4 (9), 5245. doi: 10.1021/nn1015506
(19) Xu, C.;Wang, X. Small 2009, 5 (19), 2212. doi: 10.1002/smll.v5:19
(20) Yu, M.; Liu, P. R.; Sun, Y. J.; Liu, J. H.; An, J.W.; Li, S. M.J. Inorg. Mater. 2012, 27 (1), 89. [于美, 刘鹏瑞, 孙玉静, 刘建华, 安军伟, 李松梅. 无机材料学报, 2012, 27 (1), 89.]
(21) Xu, P.; Han, X. J.;Wang, C.; Zhao, H. T.;Wang, J. Y.;Wang, X.H.; Zhang, B. J. Phys. Chem. B 2008, 112 (10), 2775. doi: 10.1021/jp710259v
(22) Sue, K.; Suzuki, A.; Suzuki, M.; Arai, K.; Hakuta, Y.; Hayashi,H.; Hiaki, T. Ind. Eng. Chem. Res. 2006, 45 (2), 623. doi: 10.1021/ie0506062
(23) Sarkar, S.; Sinha, A. K.; Pradhan, M.; Basu, M.; Negish, Y.; Pal,T. J. Phys. Chem. C 2011, 115 (5), 1659. doi: 10.1021/jp109572c
(24) Li, S. M.; Chen, D. M.; Liu, J. H. Acta Phys. -Chim. Sin. 2004,20 (11), 1389. [李松梅, 陈冬梅, 刘建华. 物理化学学报,2004, 20 (11), 1389. ] doi: 10.3866/PKU.WHXB20041121
(25) Ferreira, M. G. S.; Duarte, R. G.; Montemor, M. F.; Simoes, A.M. P. Electrochim. Acta 2004, 49 (17-18), 2927. doi: 10.1016/j.electacta.2004.01.051
(26) Sigh, P.; Babbar, V. K.; Razdan, A.; Puri, R. K.; Goel, T. C.J. Appl. Phys. 2000, 87 (9), 4362.
(27) Zhuo, R. F.; Qiao, L.; Feng, H. T.; Chen, J. T.; Yan, D.;Wu, Z.G.; Yan, P. X. J. Appl. Phys. 2008, 104 (9), 094101. doi: 10.1063/1.2973198
(28) Zhou, Z.W.; Chu, L. S.; Hu, S. C. Mater. Sci. Eng. B 2006, 126 (1), 93. doi: 10.1016/j.mseb.2005.09.009

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