反应性模板法合成硫化银中空球-银纳米粒子异质结构

doi:10.3866/PKU.WHXB201209031

Abstract

Abstract:

Silver sulfide hollow sphere-silver nanoparticle heterostructures were prepared by the simultaneous cation exchange and oxidation-reduction reactions of Cu₂S hollow spheres with Ag⁺ ions in aqueous solution. The obtained Ag₂S-Ag hybrid hollow spheres consisted of Ag₂S hollow spheres about 600 nm in diameter and 20-30 nm in thickness with a single Ag nanoparticle attached to the outer surface of each Ag₂S hollow sphere. The products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS). When CuS hollow spheres were used as the reactive template instead of Cu₂S hollow spheres, Ag₂S hollow spheres were the predominant product under similar reaction conditions, indicating that the Cu(I) in the Cu₂S hollow spheres served as a reductant for reducing Ag⁺ ions to metallic Ag, and hence played a key role in the formation of the Ag₂S-Ag hybrid hollow spheres. Furthermore, secondary deposition of Ag on the Ag₂S-Ag hybrid hollow spheres resulted in the formation of larger Ag₂S-Ag hybrid hollow spheres consisting of Ag₂S hollow spheres with around a half of the surface coated by a Ag film.

Key words: Silver sulfide, Hollow sphere, Silver nanoparticle, Heterostructure, Reactive template, Chemical transformation, Cuprous sulfide

MSC2000:

O648

GAO Ji-Ning, ZHAO Hua-Bo, QI Li-Min. Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2487-2492.

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Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates

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