对氯硝基苯吸附在银纳米粒子上的偶联反应

doi:10.3866/PKU.WHXB201209052

Abstract

Abstract:

Surface-enhanced Raman spectroscopy (SERS) on silver nanoparticles is highly sensitive because of surface plasmon resonance. We have studied the structures and photoinduced chemical reactions of p-chloronitrobenzene (PCNB) molecules adsorbed on silver nanoparticles using a combination of SERS and density functional theory (DFT) calculations. When the PCNB molecules are adsorbed to the surface of silver nanoparticles in alkaline solution, the SERS spectra are very different from the normal Raman spectra of PCNB. Comparison of the DFT simulated Raman spectra of PCNB and p,p'-dichloroazobenzene (DCAB) indicates that the new peaks in the SERS spectrum of PCNB adsorbed on silver nanoparticles arise from the azo (C－N＝N－C) group of DCAB.

Key words: Surface-enhanced Raman spectroscopy, Density functional theory, p-Chloronitrobenzene, p,p'-Dichloroazobenzene, Silver nanoparticle

MSC2000:

O646

LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun. Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles[J].Acta Phys. -Chim. Sin., 2012, 28(12): 2767-2773.

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Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles

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