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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2012,Vol.28>> Issue(10)>> 2336-2342     doi: 10.3866/PKU.WHXB201209104         中文摘要
CATALYSIS AND SURFACE SCIENCE
Modification of Carbon Nitride Photocatalysts by Copolymerization with Diaminomaleonitrile
ZHENG Hua-Rong, ZHANG Jin-Shui, WANG Xin-Chen, FU Xian-Zhi
Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, P. R. China
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g-C3N4photocatalysts were synthesized by copolymerization of diaminomaleonitrile (DMNA) with dicyanodiamide (DCDA) at high temperatures. The effect of copolymerization on the crystal structure, chemical structure, band structure, texture, optical property and photocatalytic performance of g-C3N4 was studied by such characterization techniques as X-ray diffraction patterns (XRD), Fourier transformed infrared (FT-IR), transmission electron microscopy (TEM), nitrogen-sorption (N2-sorption),electron paramagnetic resonance (EPR), UV-Vis diffuse reflectance spectra (UV-Vis DSR) and photoluminescence (PL) analyses. Results demonstrated that the graphitic-like layer packing structure of g-C3N4 remained unchanged after the modification; however the copolymerization with DMNA can efficiently extend the delocalizationof π-electrons and induce the formation of surface junctions, greatly enhancing the light-harvesting abilityof g-C3N4 in visible light region and promoting the separation of photogenerated charge carriers, respectively. Photocatalytic performance showed that all DMNA-modified samples presented an enhanced H2 evolution activity under visible light irradiation. The optimized weight-in amount of DMNA is found to be 0.01g, by which the modified sample shows the highest hydrogen evolution rate of 45.0 μmol·h-1. This value is 4.5 times as high as that of the unmodified carbon nitride sample.



Keywords: Photocatalyst   Solar energy utilization   Hydrogen fuel   Copolymerization   Carbon nitride  
Received: 2012-08-09 Accepted: 2012-09-10 Publication Date (Web): 2012-09-10
Corresponding Authors: Email: xcwang@fzu.edu.cn

Fund: The project was supported by the National Basic Research Program of China (973 Program,2013CB632405) and National Natural Science Foundation of China(21033003,21173043).

Cite this article: ZHENG Hua-Rong, ZHANG Jin-Shui, WANG Xin-Chen, FU Xian-Zhi. Modification of Carbon Nitride Photocatalysts by Copolymerization with Diaminomaleonitrile[J]. Acta Phys. -Chim. Sin., 2012,28 (10): 2336-2342.    doi: 10.3866/PKU.WHXB201209104

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