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Acta Phys. -Chim. Sin.  2013, Vol. 29 Issue (01): 151-156    DOI: 10.3866/PKU.WHXB201210093
CATALYSIS AND SURFACE SCIENCE     
Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn2S4 under Visible Light
YUAN Wen-Hui1, LIU Xiao-Chen1, LI Li2
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China;
2 College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China
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Abstract  

A series of Co-doped ZnIn2S4 photocatalysts were prepared via a solvothermal synthesis method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-visible (UV-Vis) diffuse reflectance spectroscopy. The results indicated that the Co was successfully incorporated into the ZnIn2S4 lattice as confirmed by XRD and XPS. With increasing Co concentration, the absorption edge of the samples shifted to longer wavelength, while the morphology of ZnIn2S4 was gradually destroyed. Photocatalytic results demonstrated that Co2+ doping could greatly enhance the photocatalytic activity of ZnIn2S4. The optimal amount of Co doping for the ZnIn2S4 photocatalyst was 0.3%(w), which displayed the highest photocatalytic activity. The possible photocatalytic mechanism was discussed.



Key wordsPhotocatalyst      Doping      Visible light      Hydrogen generation      Water splitting     
Received: 09 August 2012      Published: 09 October 2012
MSC2000:  O643  
Fund:  

The project was supported by the National Natural Science Foundation of China (20976057).

Cite this article:

YUAN Wen-Hui, LIU Xiao-Chen, LI Li. Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn2S4 under Visible Light. Acta Phys. -Chim. Sin., 2013, 29(01): 151-156.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201210093     OR     http://www.whxb.pku.edu.cn/Y2013/V29/I01/151

(1) Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125 (10), 3082. doi: 10.1021/ja027751g
(2) Kim, H. G.; Hwang, D.W.; Bae, S.W.; Jung, J. H.; Lee, J. S.Catal. Lett. 2003, 91 (3-4), 193.
(3) Chen,W.; Dong, X. F.; Chen, Z. S.; Chen, S. Z.; Lin,W. M.Acta Phys. -Chim. Sin. 2009, 25 (6), 1107. [陈威, 董新法,陈之善, 陈胜洲, 林维明. 物理化学学报, 2009, 25 (6), 1107.]doi: 10.3866/PKU.WHXB20090624
(4) Huang, L. H.; Chan, Q. Z.; Zhang, B.;Wu, X. J.; Gao, P.; Jiao,Z. B.; Liu, Y. L. Chin. J. Catal. 2011, 32 (11-12), 1822. doi: 10.1016/S1872-2067(10)60286-0
(5) Zou, Z.; Ye, J.; Arakawa, H.; Sayama, K. Nature 2001, 414 (6864), 625. doi: 10.1038/414625a
(6) Kim, H. G.; Hwang, D.W.; Lee, J. S. J. Am. Chem. Soc. 2004,126 (29), 8912. doi: 10.1021/ja049676a
(7) Maeda, K.; Teramura, K.; Lu, D. L.; Takata, T.; Saito, N.; Inoue,Y.; Domen, K. Nature 2006, 440 (7082), 295. doi: 10.1038/440295a
(8) Ritterskamp, P.; Kuklya, A.;Wustkamp, M. A.; Kerpen, K.;Weidenthaler, C.; Demuth, M. Angew. Chem. Int. Edit. 2007, 46 (41), 7770.
(9) Chaudhari, N. S.; Bhirud, A. P.; Sonawane, R. S.; Nikam, L. K.;Warule, S. S.; Rane, V. H.; Kale, B. B. Green Chem. 2011, 13 (9), 2500. doi: 10.1039/c1gc15515f
(10) Tsuji, I.; Kato, H.; Kobayashi, H.; Kudo, A. J. Phys. Chem. B2005, 109 (15), 7323. doi: 10.1021/jp044722e
(11) Tsuji, I.; Kato, H.; Kobayashi, H.; Kudo, A. J. Am. Chem. Soc.2004, 126 (41), 13406. doi: 10.1021/ja048296m
(12) Tsuji, I.; Kato, H.; Kudo, A. Chem. Mater. 2006, 18 (7), 1969.doi: 10.1021/cm0527017
(13) Romeo, N.; Dallaturca, A.; Braglia, R.; Sberveglieri, G. Appl. Phys. Lett. 1973, 22 (1), 21. doi: 10.1063/1.1654457
(14) Castro, S. L.; Bailey, S. G.; Raffaelle, R. P.; Banger, K. K.;Hepp, A. F. Chem. Mater. 2003, 15 (16), 3142. doi: 10.1021/cm034161o
(15) Seo,W. S.; Otsuka, R.; Okuno, H.; Ohta, M.; Koumoto, K.J. Mater. Res. 1999, 14 (11), 4176. doi: 10.1557/JMR.1999.0565
(16) Lei, Z.; You,W.; Liu, M.; Zhou, G.; Takata, T.; Hara, M.;Domen, K.; Li, C. Chem. Commun. 2003, 2142.
(17) Shen, S. H.; Zhao, L.; Guo, L. J. J. Phys. Chem. Solids 2008, 69 (10), 2426. doi: 10.1016/j.jpcs.2008.04.035
(18) Shen, S. H.; Zhao, L.; Guo, L. J. Int. J. Hydrog. Energy 2008,33 (17), 4501. doi: 10.1016/j.ijhydene.2008.05.043
(19) Shen, S. H.; Zhao, L.; Guo, L. J. Mater. Res. Bull. 2009, 44 (1),100. doi: 10.1016/j.materresbull.2008.03.027
(20) Lu, Y. C.; Lin, Y. H.;Wang, D. J.;Wang, L. L.; Xie, T. F.; Jiang,T. F. Nano Res. 2011, 4 (11), 1144. doi: 10.1007/s12274-011-0163-4
(21) Bai, X. F.; Li, J. S. Mater. Res. Bull. 2011, 46 (7), 1028. doi: 10.1016/j.materresbull.2011.03.012
(22) Peng, S. J.; Zhu, P. N.; Thavasi, V.; Mhaisalkar, S. G.;Ramakrishna, S. Nanoscale 2011, 3, 2602. doi: 10.1039/c0nr00955e
(23) Cai,W.; Zhao, Y. S.; Hu, J.; Zhong, J. S.; Xiang,W. D. J. Mater. Sci. Technol. 2011, 27 (6), 559. doi: 10.1016/S1005-0302(11)60108-4
(24) Dubey, N.; Labhsetwar, K.; Devotta, S.; Rayalu, S. Catal. Today2007, 129 (3-4), 428. doi: 10.1016/j.cattod.2006.09.041
(25) Jing, D.W.; Liu, M. C.; Guo, L. J. Catal. Lett. 2010, 140 (3-4),167. doi: 10.1007/s10562-010-0442-9
(26) Shen, S. H.; Zhao, L.; Guo, L. J. J. Phys. Chem. C 2008, 112 (41), 16148. doi: 10.1021/jp804525q
(27) Zhang, X.; Jing, D.; Liu, M.; Guo, L. J. Catal. Commun. 2008, 9 (8), 1720. doi: 10.1016/j.catcom.2008.01.032
(28) Wang, B. Q.; Xia, C. H.; Iqbal, J.; Tang, N. J.; Sun, Z. R.; Lv, Y.;Wu, L. Solid State Sci. 2009, 11 (8), 1419. doi: 10.1016/j.solidstatesciences.2009.04.024
(29) Jing, D.W.; Zhang, Y.; Guo, L. J. Chem. Phys. Lett. 2005, 415 (1-3), 74. doi: 10.1016/j.cplett.2005.08.080

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