ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(01)>> 205-211     doi: 10.3866/PKU.WHXB201210264         中文摘要
Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis
TAO Jing-Liang, XIONG Yuan-Quan
Key Laboratory for Energy of Heat Conversion and its Process of Measurement and Control, School of Energy and Environment, SouthEast University, Nanjing, 210096, P. R. China
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High-energy electrons play the most important role in the decomposition of ethanol aqueous solutions under glow discharge plasma electrolysis (GDE). The non-Faradaic currents greatly improve, resulting in the actual gas production yield exceeding the theoretical yield. In this paper, we investigated a novel process of hydrogen generation from ethanol decomposition by GDE. The main gaseous products were H2 and CO; in addition to small amounts of C2H4, CH4, O2, and C2H6. The H2 volume fraction was above 59% and CO was 20%. We conclude that voltages of points C and D (VC and VD) do not change with the electrolyte concentration, but the 'Kellogg area' becomes narrower with increasing electrolyte conductivity and the glow discharge is easier to attain. In addition, with increasing ethanol volume fraction, the H2 volume fraction decreases. The maximum gas production rate occurred for ethanol volume fractions of 30% and 80%. Improving the discharge voltage and raising the electrolyte conductivity had the same effect on glow discharge plasma electrolysis as the voltage load at both ends of the plasma steam sheath increases. The H2 volume fraction remains the same upon varying the discharge voltage or electrolyte conductivity, but increasing the electrolyte conductivity is advantageous to reduce Joule heating effects caused by GDE.

Keywords: Glow discharge electrolysis   Gas generation rate   Electrolyte   Ethanol   Steam sheath   Hydrogen generation  
Received: 2012-09-05 Accepted: 2012-10-26 Publication Date (Web): 2012-10-26
Corresponding Authors: Email:

Fund: The project was supported by the National Key Basic Research Program of China (973) (2010CB227002-02) and National High Technology Research and Development Program of China (863) (2011AA05A201).

Cite this article: TAO Jing-Liang, XIONG Yuan-Quan. Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis[J]. Acta Phys. -Chim. Sin., 2013,29 (01): 205-211.    doi: 10.3866/PKU.WHXB201210264

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