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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(02)>> 293-297     doi: 10.3866/PKU.WHXB201211142         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries
DING Peng1,2,3, XU You-Long1,2, SUN Xiao-Fei1,2
1 Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi’an 710049, P. R. China;
2 International Center for Dielectric Research, Xi'an Jiaotong University, Xi’an 71004
9. P. R. China;
3 Department of Power, Wuhan Ordnance Non-Commissioned Officer Academy, Wuhan 430075, P. R. China
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Transition metal oxides, especially manganese monoxide (MnO), are being intensively studied as candidate anode materials for next generation lithium-ion batteries in high efficiency energy storage applications such as portable electronics, electric vehicles, and stationary electricity storage. In this paper, the MnC2O4·2H2O precursor, prepared fromKMnO4 and ascorbic acid, was heat-treated to synthesize nano MnO by a solid-state reaction approach. X-ray diffraction (XRD) showed that the so-obtained MnO had a rock-salt structure with good crystallinity, and scanning electron microscopy (SEM) indicated that the primary particle size was about 50-100 nm, while the secondary particle size was about 400-600 nm. As an active material for lithium-ion batteries, the nano MnO material delivered a reversible capacity of 679.7 mAh·g-1 with an initial columbic efficiency of 68.9% at a current density of 46.3 mA·g-1. The specific discharge capacity slightly decreased from 584.5 to 581.5 mAh·g-1 with a retention of 99.5% after 50 cycles at a current density of 141.1 mA·g-1. Moreover, the material was able to release a capacity of 290 mAh·g-1 at current densities as high as 494.7 mA·g-1 (corresponding to ~2C), which demonstrates reasonable rate performance and moderately fast charge/discharge capabilities. All of the above characteristics make nano MnO promising anode materials for developing high-capacity, long-life, low-cost, and environmentally-friendly lithium-ion batteries.



Keywords: Manganese monoxide   Nano material   Conversion reaction   Lithium-ion battery   Anode material  
Received: 2012-09-10 Accepted: 2012-11-13 Publication Date (Web): 2012-11-14
Corresponding Authors: Email: ylxu@mail.xjtu.edu.cn


Cite this article: DING Peng, XU You-Long, SUN Xiao-Fei. Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2013,29 (02): 293-297.    doi: 10.3866/PKU.WHXB201211142

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68. CHENG Feng, HUANG Ke-Long, LIU Su-Qin, FANG Xue-Song, ZHANG Xin.Surfactant Carbonization to Synthesize a Fe3O4/C Composite and Its Electrochemical Performance[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1439-1445
69. SUN Du, YIN Peng-Gang, GUO Lin.Synthesis and Raman Property of Porous Jujube-Like Cu2O Hierarchy Structure[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1543-1550
70. Lü Rong-Guan, YANG Jun, WANG Jiu-Lin, NULI Yan-Na.Electrodeposition and Electrochemical Property of Porous Li-Si Film Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(04): 759-763
71. TANG Yan, ZHONG Ben-He, GUO Xiao-Dong, LIU Heng, ZHONG Yan-Jun, NIE Xiang, TANG Hong.Effects of Mixed Solvents on the High-Rate Performance of Li3V2(PO4)3/C Prepared by Sol-Gel Method[J]. Acta Phys. -Chim. Sin., 2011,27(04): 869-874
72. SU Chang, LU Guo-Qiang, XU Li-Huan, ZHANG Cheng, MA Chun-An.Synthesis and Properties of Spindle-Shaped LiFePO4 for the Cathode Material of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2011,27(03): 609-614
73. ZHANG Qiu-Mei, SHI Zhi-Cong, LI Yi-Xiao, GAO Dan, CHEN Guo-Hua, YANG Yong.Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(02): 267-274
74. WANG Xiao-Ya, CHENG Qian, HUANG Tao, YU Ai-Shui.Effect of Calcination Atmosphere on Li/Ni Disorder and Electrochemical Performance of Layered LiNi0.5Mn0.5O2[J]. Acta Phys. -Chim. Sin., 2011,27(02): 437-442
75. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia, ZHANG Jin-Qiu.Cathodic and Thermal Stabilities of the P(VdF-HFP)-Based Ionic Liquid Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(01): 78-84
76. CHEN Shi-Yu, WANG Zhao-Xiang, FANG Xiang-Peng, ZHAO Hai-Lei, LIU Xiao-Jiang, CHEN Li-Quan.Characterization of TiS2 as an Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(01): 97-102
77. ZHOU Xiao-Ling, HUANG Rui-An, WU Zhao-Cong, YANG Bin, DAI Yong-Nian.Synthesis and Electrochemical Properties of High-Rate Spinel Li4Ti5Ol2/TiN Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3187-3192
78. CHANG Zhao-Rong, DAI Dong-Mei, LI Bao, TANG Hong-Wei.Effect of Hydrazine on the Performance of LiNi0.5Mn1.5O4Cathode Materials[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2633-2637
79. LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong.Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2387-2391
80. DAI Ke-Hua, MAO Jing, ZHAI Yu-Chun.High Rate Capability of 5 V LiNi0.5Mn1.5O4 Cathode Materials Synthesized via a Gel-Combustion Method[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2130-2134
81. QIU Xiang-Yun, ZHUANG Quan-Chao, WANG Hong-Ming, CUI Yong-Li, FANG Liang, SUN Shi-Gang.Influence of Electrolyte Composition on the Intercalation-Deintercalation Process of Lithium Ion in Spinel LiMn2O4[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1499-1506
82. QU Xiao-Hua, LIU Jie, WANG Zhao-Xiang, CAO Dian-Liang, FANG Xiang-Peng, ZHANG Ling, DUAN Jing-Lai, YAO Hui-Jun, CHEN Yan-Feng, SUN You-Mei, HOU Ming-Dong.Preparation of Microporous Membranes by Swift Heavy Ion Irradiation and Impedance Characterization[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1722-1726
83. ZHANG Xiao-Yu, JIANG Wei-Jun, ZHU Xiao-Pei, QI Lu.Characterization of LiNi1/3Mn1/3Co1/3O2 Synthesized by Wet-Chemical Method[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1507-1514
84. ZHANG Hui-Juan, SONG Huai-He, ZHOU Ji-Sheng, ZHANG Hong-Kun, CHEN Xiao-Hong.Preparation and Electrochemical Properties of SnO2/Onion-Like Hollow Carbon Nanoparticle Composites as Anode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1259-1263
85. ZHAO Chuan-Xi, WU Ping, ZHANG Dan-Li, CHEN Rong, CHI Ling-Fei, XIAO Tan.Synthesis and Photoluminescence of Zn2SnO4 Nanomaterials[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1343-1348
86. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia.Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO4 Cathode[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1233-1238
87. CHANG Yu-Qing, HUANG Ling, SUN Shi-Gang.Electrodeposition and Electrochemical Properties of Ternary Sn-Co-Zn Alloy Electrodes as Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 561-566
88. XIONG Li-Zhi, HE Ze-Qiang.A New Rheological Phase Route to Synthesize Nano-LiVOPO4 Cathode Material for LithiumIon Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 573-577
89. CHANG Zhao-Rong, YU Xu, TANG Hong-Wei, WEI Wen-Qiang, DAI Dong-Mei.Influence of Al Doping Content on the Structure and Electrochemical Properties of LiNi1/3Co2/3-xAlxO2[J]. Acta Phys. -Chim. Sin., 2010,26(03): 567-572
90. LU Hua-Quan, WU Feng, SU Yue-Feng, LI Ning, CHEN Shi, BAO Li-Ying.Electrochemical Performance of LiNi0.5Mn0.5O2 as Cathode Material for Lithium-Ion Batteries Prepared by Oxalate Co-Precipitation Method[J]. Acta Phys. -Chim. Sin., 2010,26(01): 51-56
91. TAN Xiao-Lan, CHENG Xin-Qun, MA Yu-Lin, ZUO Peng-Jian, YIN Ge-Ping.Film Formation and Cycleability of LiBOB-Based Electrolyte[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1967-1971
92. ZHENG Jun-Chao, LI Xin-Hai, WANG Zhi-Xing, LI Jin-Hui, WU Ling, LI Ling-Jun, GUO Hua-Jun.A Coalescence Mechanism for the Composite Cathode Material xLiFePO4·yLi3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1916-1920
93. ZHONG Mei-E, ZHOU Zhi-Hui, ZHOU Zhen-Tao.Electrochemical Performance of High-Density LiFePO4/C Composites Synthesized by Solid State-Carbothermal Reduction Method[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1504-1510
94. JIANG Dong-Dong, FU Yan-Bao, MA Xiao-Hua.Fabrication and Characterization of Tin Nanorod Electrodes for Lithium Ion Rechargeable Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1481-1484
95. FENG Ji-Jun, LIU Xiang-Zhe, LIU Xiao-Zhen, JIANG Jian-Zhuang, ZHAO Jing.Hydrothermal Syntheses and Properties of LiV3-xMnxO8 as Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1490-1494
96. HU Guo-Rong, CAO Yan-Bing, PENG Zhong-Dong, DU Ke, JIANG Qing-Lai.Preparation of Li2FeSiO4 Cathode Material for Lithium-Ion Batteries by Microwave Synthesis[J]. Acta Phys. -Chim. Sin., 2009,25(05): 1004-1008
97. GAO Hong-Quan, LAI Yan-Qing, ZHANG Zhi-An, LIU Ye-Xiang.Electrochemical Behaviors of New Lithium Salt LiBC2O4F2 in EC+DMC Solvents[J]. Acta Phys. -Chim. Sin., 2009,25(05): 905-910
98. FAN Xiao-Yong, ZHUANG Quan-Chao, WEI Guo-Zhen, KE Fu-Sheng, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang.Fabrication and Performance of Cu6Sn5 Alloy Anode Using Porous Cu as Current Collector[J]. Acta Phys. -Chim. Sin., 2009,25(04): 611-616
99. WU Feng, WANG Meng, SU Yue-Feng, CHEN Shi.Surface Modification of LiCo1/3Ni1/3Mn1/3O2 by TiO2-Coating[J]. Acta Phys. -Chim. Sin., 2009,25(04): 629-634
100. ZHANG Guo-Qiang, MA Li, WU Zhong-Jie, ZHANG Hai-Yan, NI Pei.Electrochemical Behaviour of the Composite Polymer Electrolyte P(VDF-HFP)-PMMA/CaCO3(SiO2)[J]. Acta Phys. -Chim. Sin., 2009,25(03): 555-560
101. MA Ruo-Biao, FU Yan-Bao, MA Xiao-Hua.Preparation and Electrochemical Performance of Tin-Dioxide Filled Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 441-445
102. ZHUANG Quan-Tiao, WEI Guo-Zhen, DONG Quan-Feng, SUN Shi-Gang.Influence of Temperature on the Performance of a Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(03): 406-410
103. XU Jie; YAO Wan-Hao; YAO Yi-Wen; WANG Zhou-Cheng; YANG Yong.Effect of Fluoroethylene Carbonate Additive on the Performance of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2009,25(02): 201-206
104. LI Yang; XIE Hua-Qing; TU Jiang-Ping.SnS with Various Morphologies and Sizes as Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(02): 365-370
105. YANG Shun-Yi; WANG Xian-You; WEI Jian-Liang; LI Xiu-Qin; TANG An-Ping.Preparation and Electrochemical Performance of Na-Mn-O Cathode Materials[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1669-1674
106. HUANG Jun-Jie; JIANG Zhi-Yu.Electrochemical Performance of LiMn2O4 Thin Film Electrode Fabricated by Ink-Jet Printing Technique[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1563-1567
107. ZHANG Hua; ZHOU Yong-Ning; WU Xiao-Jing; FU Zheng-Wen.Electrochemical Properties of CuF2 Films Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1287-1291
108. LI Fan-Qun; LAI Yan-Qing; ZHANG Zhi-An; GAO Hong-Quan; YANG Juan.Electrochemical Behaviors of Et4NBF4+LiPF6/EC+PC+DMC Electrolyte on Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1302-1306
109. WANG Meng; WU Feng; SU Yue-Feng; CHEN Shi.Electrochemical Characteristics of Y2O3-Coated LiCo1/3Ni1/3Mn1/3O2[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1175-1179
110. WANG Jian-Hua; LI Bin; WU Hai-Yan; GUO Yu-Zhong.Synthesis of Mesoporous SnO2 and Its Application in Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2008,24(04): 681-685
111. GUO Ying-Jun; LI Qi-Qi-Ge; NING Ying-Kun; QI Lu; TANG Hong-Wu.Performance of Liquid Electrolyte for Lithium-ion Battery at Elevated-temperature[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 1-4
112. WANG Ya-Dan; WANG Jian; MU Qi-Yong; LI Yong-Wei; QI Lu.Electrochemical Performances of LiMn2O4-based Electrode with Water-soluble Binder[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 14-17
113. QI Lu; SONG Zhao-Shuang; XU Hua; MAO Yong-Zhi; WU Ning-Ning; LIU Zheng-Yao.Electrochemical Performance of LithiumIon Battery Power Syetemfor Electric Vehicles[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 21-25
114. ZHANG Chun-Ling; JIANG Wei-Jun; ZHANG Jing; QI Lu.Performance of LiMn1.5Ni0.5-xCuxO4 as 5V Cathode Material for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 31-35
115. TANG Ding-Guo.Application of Polymer LithiumIon Batteries Based on IPN[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 18-20
116. HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan.Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 40-45
117. FAN Mao-Song; LEI Xiang-Li; WU Ning-Ning; QI Lu.Electrochemical Performance of LiMn2O4 Power Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 36-39
118. WANG Hai-Yan; LIU Xin-Hou; WU Da-Yong.Electrospinning and Electrospun Membranes[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 67-74
119. AN Hong-Li; WU Ning-Ning; LEI Xiang-Li; XU Jin-Long; QI Lu.Electrochemical Performance of LithiumIon Battery for Plug-in Hybrid Electric Vehicle Applications[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 60-66
120. GUO Ying-Jun; CHEN Hui; QI Lu.Progress in Electrolyte Solutions for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 80-89
121. LEE Meng-Lung; LEE Yi-Da; CHANG Chie-Tai; GAO Tong-Han; LEE Torng-Jinn.Application and Technology of Aluminum Bag Lithium-Ion Polymer Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 100-106
122. FENG Hua-Jun; CHEN Yuan;DAI Ke-Hua; SONG Zhao-Shuang; MA Jian-Wei; QI Lu.Preparation and Characterization of a Novel Kind of Polymer Electrolyte Composite Membrane for Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1922-1926
123. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Preferred Orientation of Crystals and the Intensity Ratios of XRD Peaks of Cathode Material LiCoO2[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1948-1953
124. HOU Chun-Ping; YUE Min.A Novel Cathode Material Lithium Vanadium Phosphate Synthesized by Liquid-phase Sphericizing Granulation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1954-1957
125. XU Can; ZHANG Xiao-Fang; CHEN Liang; ZHU Li-Fang; ZHANG Rong-Jun.Theoretical Study on the Even-Odd Oscillation of the Vibration Modes of the Silica Nanowire[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1733-1737
126. TANG Hong-Wei; ZHU Zhi-Hong; CHANG Zhao-Rong; CHEN Zhong-Jun.Drawing and Application of Phase Diagram Related to Eutectic Mixed Lithium Salts[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1265-1268
127. WEI Ying-Jin; LI Xu; WANG Chun-Zhong; ZHAN Shi-Ying; CHEN Gang.Preparation and Electrochemical Properties of Cu Doped V2O5[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1090-1094
128. ZHANG Hong-Fang; FU Ping-Ping; SONG Ying-Jie; DU Chen-Shu; YANG Hua-Bin; ZHOU Zuo-Xiang; WU Meng-Tao; HUANG Lai-He.Preparation and Properties of Sandwich-type Si/Fe/Si Film Anode for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1065-1070
129. SHE Shi-Xiong; SU Bi-Tao; YANG Yan; MIN Shi-Xiong; LEI Zi-Qiang.Preparation of Functional Polymer Nanomaterial and Its Catalytic Property[J]. Acta Phys. -Chim. Sin., 2007,23(06): 900-904
130. LIU Su-Qin; LI Shi-Cai; HUANG Ke-Long; CHEN Zhao-Hui.Effect of Doping Ti4+ on the Structure and Performances of Li3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2007,23(04): 537-542
131. HUANG Ke-Long;YANG Sai;LIU Su-Qin;WANG Hai-Bo.Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution[J]. Acta Phys. -Chim. Sin., 2007,23(01): 129-133
132. QIN Hai-Ying;XIE Jian;MI Jian-Li;TU Jian;ZHAO Xin-Bing.Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb2 Nanorods[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1555-1559
133. CHAI Yong-Cun;CHEN Xiao;SUI Zhen-Ming;ZHUANG Wen-Chang.Electrochemical Deposition of Bunchy Nanostructured Platinum from Lyotropic Liquid Crystal Template[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1506-1510
134. HUANG Ling;JIANG Hong-Hong;KE Fu-Sheng;FAN Xiao-Yong;ZHUANG Quan-Chao;YANG Fang-Zu;SUN Shi-Gang.Structure and Properties of Three-dimensional Reticular Sn-Co Alloy Electrodes as Anode Material for Lithium Batteries[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1537-1541
135. XU Yu-Hong;ZHANG Bao-Hong;GONG GUI-Ying;MA Ping .Electrochemical Properties Study of Sb2O3 doped Li4Ti5O12[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1336-1341
136. XIE Jian;ZHAO Xin-Bing;YU Hong-Ming;QI Hao;CAO Gao-Shao;TU Jiang-Ping .Preparation, Characterization and Electrochemical Li-absorption/extraction Behaviors of Nanosized Co-Sn Intermetallic Compounds[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1409-1412
137. ZHUANG Da-Gao;ZHAO Xin-Bing;XIE Jian;TU Jian;ZHU Tie-Jun;CAO Gao-Shao.One-step Solid-state Synthesis and Electrochemical Performance of Nb-doped LiFePO4/C[J]. Acta Phys. -Chim. Sin., 2006,22(07): 840-844
138. WANG Zhong;TIAN Wen-Huai;LI Xing-Guo.Synthesis and Electrochemical Properties of Sn-Sb Alloy Prepared by Hydrogen Plasma-metal Reaction[J]. Acta Phys. -Chim. Sin., 2006,22(06): 752-755
139. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
140. XUE Ming-Zhe; CHENG Sun-Chao; YAO Jia; FU Zheng-Wen.Electrochemical Properties of SnSe Thin Film Electrode Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2006,22(03): 383-387
141. YANG Xiao; NI Jiang-feng; HUANG You-yuan; CHEN Ji-tao; ZHOU Heng-hui; ZHANG Xinxiang.Effect of Ti-Doping on Different Morphologic LiCoO2[J]. Acta Phys. -Chim. Sin., 2006,22(02): 183-188
142. ZHUANG Quan-chao; FAN Xiao-yong; XU Jin-mei; CHEN Zuo-feng; DONG Quan-feng; JIANG Yan-xia; HUANG Ling; SUN Shi-gang.Electrochemical Impedance Spectroscopic Study of the First Delithiation of Spinel Lithium Manganese Oxide[J]. Acta Phys. -Chim. Sin., 2006,22(02): 234-238
143. WANG Ying; LIU Wen-yuan; FU Zheng-wen.Electrochemistry of Mn4N with Lithium[J]. Acta Phys. -Chim. Sin., 2006,22(01): 65-70
144. WANG Guo-guang WANG Jian-ming MAO Wen-qu LIU Li-qing ZHANG Jian-qing CAO Chu-nan.Structure and Electrochemical Performance of LiNiyCo0.1-yMn1.9O4 Cathode Materials Prepared by a Precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1285-1290
145. TANG Xin-cun; HUANG Bo-yun; HE Yue-hui.Dependence of Li+ Diffusion Coefficients in LiMn2O4 on Charge/Discharge Cycles[J]. Acta Phys. -Chim. Sin., 2005,21(09): 957-960
146. TANG Zhi-yuan; LU Xing-he; ZHANG Na.The Anion-cation Multiple Doping Effect of Spinel Cathode Materials on Electrochemical Speciality[J]. Acta Phys. -Chim. Sin., 2005,21(08): 934-938
147. HUANG You-yuan; ZHOU Heng-hui; CHEN Ji-tao; GAO De-shu; SU Guang-yao.The Effect of Ti4+, Mg2+ Co-doping on Performance of LiNi0.4Co0.2Mn0.4O2[J]. Acta Phys. -Chim. Sin., 2005,21(07): 725-729
148. XUE Ming-zhe; FU Zheng-wen.Electrochemical Properties of LiFePO4 Cathode Thin Film Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2005,21(07): 707-710
149. CAO Jie-ming; WANG Jun; FANG Bao-qing; ZHENG Ming-bo; LU Hong-xia; CHANG Xin; WANG Hai-yan.Synthesis and Characterization of ZnO Nanomaterials with Different Morphologies in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(06): 668-672
150. TANG Zhi-Yuan;ZHANG Na;LU Xing-He;HUANG Qing-Hua.Characterizations of Spinel LiMn2-xZrxO4 Cathode for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2005,21(01): 89-92
151. Chen Feng; Zhu Yi-Ping; Ma Hong-Liao; Bo Zi-Long; Zhang Jin-Long.Preparation and Characterization of TiO2--CdS-MCM-41 Nano-composite[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1292-1296
152. Chang Xiao-Yan;Wang Zhi-Xing;Li Xin-Hai;Kuang Qiong;Peng Wen-Jie;Guo Hua-Jun;Zhang Yun-He.Synthesis and Performance of LiMnPO4 Used as Cathode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1249-1252
153. Li Di;Li Jing-Hong.Electrochemistry of Monolayer Protected Nanoclusters[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 982-988
154. Sun Shi-Gang.Enhanced IR Absorption and Abnormal IR Effects of Low-dimensional Nanomaterials[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 1017-1023
155. Wang Zhi-Xing;Xing Zhi-Jun;Li Xin-Hai;Guo Hua-Jun;Peng Wen-Jie.Study on Al2O3-modified LiMn2O4 Prepared by Heterogeneous Nucleation[J]. Acta Phys. -Chim. Sin., 2004,20(08): 790-794
156. Du Jun;Wu Ling;Tao Chang-Yuan;Sun Cai-Xin.Preparation and Characterization of Fe3O4/PVDF Magnetic Composite Membrane[J]. Acta Phys. -Chim. Sin., 2004,20(06): 598-601
157. Liu En-Hui;Li Xin-Hai;Hou Zhao-Hui;He Ze-Qiang;Deng Ling-Feng.Chemical Diffusion Behaviors of Lithium-ion in the LiV3O8 Prepared by Wet Method Reaction[J]. Acta Phys. -Chim. Sin., 2004,20(04): 377-381
158. Wang Hui;Zhang Xiu-Juan;Zhang Xiao-Hong;Wu Shi-Kang.The Preparation of Nano-sized Silica Gel Suspension and the Recognition of Transition Metal Cations[J]. Acta Phys. -Chim. Sin., 2004,20(03): 313-317
159. Qiu Jie-Shan;An Yu-Liang;Li Qi-Xiu;Zhou Ying;Yang Qing.Preparation of Carbon Encapsulated Metal (Mn,Co) Nanomaterials with Apoferrintin as the Constrained Nano-sized Reactor[J]. Acta Phys. -Chim. Sin., 2004,20(03): 260-264
160. Wang Zhan-Liang;Tang Zhi-Yuan.Research on the Interfacial Properties of Polymer Electrolyte by A.C.Impedance[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1097-1101
161. Dong Xiang-Ting;He Ying;Yan Jing-Hui;Xue Bo-Fei;Feng Xiu-Li;Hong Guang-Yan.Preparation and Characterization of Nanosized AgBr/PMMA Photochromic Hybrid Material[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1159-1162
162. Li Jian-Gang;Wan Chun-Rong;Yang Dong-Ping;Yang Zhang-Ping.Effect of Cell Temperature on the Electrochemical Reaction of LiNi3/8Co2/8Mn3/8O2[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1030-1034
163. Xu Jin-Xia;Huang Xin-Min;Qian Li-Hua.Structure and Properties of Ni-Al2O3 Nanochannel Array System by Direct Current Electro-deposition[J]. Acta Phys. -Chim. Sin., 2003,19(03): 265-267
164. Chen Ji-Tao;Zhou Heng-Hui;Chang Wen-Bao;Ci Yun-Xiang.Effect of Particle Size on Lithium Intercalation Performance of Graphite Anode[J]. Acta Phys. -Chim. Sin., 2003,19(03): 278-282
165. Tang Xin-Cun;He Li-Ping;Chen Zong-Zhang;Xia Xi.Determination of the Li+ Diffusion Coefficient in Graphite By the Method of the Ratio of Potentio-charge Capacity to Galvano-charge Capacity[J]. Acta Phys. -Chim. Sin., 2002,18(08): 705-709
166. Wang Zhan-Liang;Tang Zhi-Yuan;Geng Xin;Xue Jian-Jun.Research on Novel PMMAbased Gel Electrolyte for Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2002,18(03): 272-275
167. Zhao Li-Li;Wang Rong-Shu;Niu Wen-Tai;Li Xiang.Synthesis of γ-MnO2 Nano Powder Used for SieveMembrane Reactor[J]. Acta Phys. -Chim. Sin., 2002,18(03): 197-200
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