ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(02)>> 371-376     doi: 10.3866/PKU.WHXB201211146         中文摘要
Determination of the Adsorption of Xanthate on Mesoporous CuAl2O4 Using a Continuous Online In situ ATR-FTIR Technology
GE Dong-Lai, FAN Ying-Ju, YIN Long, SUN Zhong-Xi
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China
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In this study, mesoporous nano CuAl2O4 was synthesized through a coprecipitation method using simple mixed templates consisting of butylamine and dodecanol. The sample was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorptiondesorption techniques. The absorption of butyl and octyl xanthate from aqueous solution onto the synthesized mesoporous CuAl2O4 solid surfaces was studied by a continuous, online, in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) technique. The CuAl2O4 membrane used in the adsorption experiments was prepared on a germanium internal reflection element using the chemical bath deposition method. During the adsorption process, the characteristic peak height of xanthate at 1200 and 1040 cm-1 emerged and gradually increased. By monitoring changes in the peak height at 1200 cm-1, which was assigned to the stretching vibration caused by C-O-C of the adsorbed xanthate molecules, the adsorption kinetics were studied. The adsorption results show that mesoporous CuAl2O4 has a high chemisorption capacity for xanthate, which reaches 236 and 300 mg·g-1 for butyl and octyl xanthate, respectively, within 100 min. The adsorption kinetics can be described by a pseudo-second-order reaction model.

Keywords: In situ adsorption   Attenuated total reflection Fourier transform infrared spectroscopy   Online   Mesopore   CuAl2O4   Xanthate  
Received: 2012-09-26 Accepted: 2012-11-13 Publication Date (Web): 2012-11-14
Corresponding Authors: Email:

Fund: The project was supported by the National Natural Science Foundation of China (51274104, 50874052) and National Key Basic Research Program of China (973) (2011CB933700).

Cite this article: GE Dong-Lai, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Determination of the Adsorption of Xanthate on Mesoporous CuAl2O4 Using a Continuous Online In situ ATR-FTIR Technology[J]. Acta Phys. -Chim. Sin., 2013,29 (02): 371-376.    doi: 10.3866/PKU.WHXB201211146

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69. PEI Su-Peng; ZHANG Bin; JIAO Kun; BAO Ren-Lie; YUE Bin; HE He-Yong.Nanostructured CoMoO4 Supported on Mesoporous SBA-15 for Catalytic Oxidative Dehydrogenation of Propane to Propene[J]. Acta Phys. -Chim. Sin., 2008,24(04): 561-564
70. WANG Jian-Hua; LI Bin; WU Hai-Yan; GUO Yu-Zhong.Synthesis of Mesoporous SnO2 and Its Application in Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2008,24(04): 681-685
71. LI Jian-Quan; SHEN Cheng-Yin; WANG Hong-Mei; HAN Hai-Yan; ZHENG Pei-Chao; XU Guo-Hua JIANG Hai-He; CHU Yan-Nan.Dynamic Measurements of Henry’s LawConstant of Aromatic Compounds Using Proton Transfer Reaction Mass Spectrometry[J]. Acta Phys. -Chim. Sin., 2008,24(04): 705-708
72. LIU Xiao-Lei; HE Jian-Ping; DANG Wang-Juan; JI Ya-Jun; ZHAO Gui-Wang; ZHANG Chuan-Xiang.Structural Characteristics and Humidity Sensing of Mesoporous SnO2[J]. Acta Phys. -Chim. Sin., 2008,24(03): 475-480
73. MA Xue-Hui; ZHAO Yan-Bao; XIAO Gao-Feng; WU Zhi-Shen.Synthesis of Mercaptopropyl Functionalized Nanosized Mesoporous Silica[J]. Acta Phys. -Chim. Sin., 2008,24(03): 492-496
74. SU Zhao-Hui; CHEN Qi-Yuan; LI Jie; LIU Shi-Jun.Preparation and Characterization of Mesoporous Silicon Dioxide Doped with Tungsten[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1760-1764
75. MA Na; JI Sheng-Fu; WU Ping-Yi; HU Lin-Hua; NIE Ping-Ying.Preparation, Characterization and Catalytic Performance for Hydrodesulfurization of WxC/SBA-16 Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1189-1194
76. DANG Wang-Juan; HE Jian-Ping; ZHOU Jian-Hua; JI Ya-Jun; LIU Xiao-Lei; MEI Tian-Qing; LI Hu-Lin.Dispersion and Electrocatalytic Performance of Platinum Nanoparticles Supported on Ordered Mesoporous Carbon[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1085-1089
77. ZHAO Hai-Jun; HOU Hai-Tao; CAO Jie-Ming ZHENG Ming-Bo; LIU Jing-Song; ZHANG Fang.Solvothermal Synthesis of Mesoporous SnO2 with Spongy Structure[J]. Acta Phys. -Chim. Sin., 2007,23(06): 959-963
78. KE Xing-Fei; CAO Jie-Ming; ZHENG Ming-Bo; CHEN Yong-Ping; LIU Jin-Song.Synthesis of Hierarchically Meso-Macroporous Structured Carbon Sieve by Dual-template Method[J]. Acta Phys. -Chim. Sin., 2007,23(05): 757-760
79. LIU Yong; MENG Ming; YAO Jin-Song; ZHA Yu-Qing.Preparation and Characterization of the Multi-component Mesoporous Mixed Oxide La-Mn-Ce-O Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(05): 641-646
80. HAO Zhi-Xian;LIU Hui;GUO Bin;LI Hong;ZHANG Jia-Wei;GAN Li-Hua;XU Zi-Jie;CHEN Long-Wu.Sol-Gel Synthesis of Alumina Using Inorganic Salt Precursor[J]. Acta Phys. -Chim. Sin., 2007,23(03): 289-294
81. LI Cui-Ping;ZHAO Rui-Hong;GUO Fen;CHEN Jian-Feng.Preparation and Characterization of Ni Catalysts Supported on Organized Mesoporous Alumina[J]. Acta Phys. -Chim. Sin., 2007,23(02): 157-161
82. ZHAO Chun-Xia;CHEN Wen;LIU Qi;TIAN Gao.Influence of HCl on the Mesostructure and Morphology of the Ordered Mesoporous Silica[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1201-1205
83. HU Jun;WANG Jian-Jun;ZHOU Li-Hui;XIE Song-Hai;LIU Hong-Lai.The Mechanism of Mesoporous Phase Transition of Titanic-Silica Mesoporous Materials[J]. Acta Phys. -Chim. Sin., 2006,22(06): 679-683
84. ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun.Synthesis and Application of Ce-doped Mesoporous TiO2[J]. Acta Phys. -Chim. Sin., 2006,22(05): 532-537
85. LIU Li-cheng; LI Hui-quan; CAI Wei-quan; ZHANG Yi.Synthesis, Characterization and Catalytic Activity of Mesoporous Cr-MSU-1[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1311-1314
86. HU Jun; ZHOU Li-hui; LI Hong-ning; LI Wan-xin; LIU Hong-lai; HU Ying.The Influences of the Spacer of Gemini Surfactants on the Structure of Silicic Mesoporous Materials[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1217-1222
87. JIN Sheng-ming; QIU Guan-zhou; YANG Hua-ming; DENG Zhen-xia.Preparation of HMS and AlSBA Mesoporous Materials from Sepiolite[J]. Acta Phys. -Chim. Sin., 2005,21(07): 796-799
88. ZHENG Jun-Lin; ZHAI Shang-Ru; YANG Dong-Jiang; ZHANG Ye; WU Dong; SUN Yu-Han.Comparison on the Catalytic Cracking and Alkylation Activities between MSU-SMFI and MCM-41 Aluminosilicates[J]. Acta Phys. -Chim. Sin., 2005,21(03): 324-327
89. Dai Zhi-Hui;Ju Huang-Xian.Direct Electron Transfer of Protein Immobilized on Mesoporous Molecular Sieves Matrix[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1262-1266
90. Zhu Jian-Hua;Xu Yang;Wang Ying;Zhou Shi-Lu;Zhou Chun-Fang.Adsorption and Catalytic Degradation of Nitrosamines by Zeolites and Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 946-952
91. Shi Xi-E;Zhai Shang-Ru;Dai Li-Yi;Shan Yong-Kui;He Ming-Yuan;Wei Wei;Wu Dong;Sun Yu-Han.Synthesis of Mesoporous Aluminosilicate Nanoparticles and Its Performance in Catalytic Cracking[J]. Acta Phys. -Chim. Sin., 2004,20(03): 265-270
92. Nie Chun-Fa;Suo Ji-Shuan.Synthesis,Characterization and Catalytic Applications of Asymmetric Hydrogenation Catalyst Immobilized on Hybrid MCM-41[J]. Acta Phys. -Chim. Sin., 2004,20(02): 149-153
93. Liu Lei;Zhang Gao-Yong;Dong Jin-Xiang.Effects of Different Templating Agent on the Structure of Silica MCM-41 Mesoporous Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2004,20(01): 65-69
94. Zheng Jun-Lin;Zhang Ye;Wei Wei; Wu Dong;Sun Yu-Han;Deng Feng;Luo Qing;Yue Yong.Hydrothermally Stable Mesoporous Aluminosilicates with Strongly Acidic Sites[J]. Acta Phys. -Chim. Sin., 2003,19(10): 907-912
95. Ni Qi-Liang;Zhang Jian-Cheng;Liu Jian-Min;Shen Yue.Fe/SAB-3 Composite Mesoporous Materials and Magnetic Properties[J]. Acta Phys. -Chim. Sin., 2003,19(10): 944-947
96. Wang Jin-Zhong;Zhao Yan;Zhang Cai-Bei.Synthesis of Ordered Mesoporous TiO2 on a Composite Surfactant Template[J]. Acta Phys. -Chim. Sin., 2003,19(03): 251-255
97. Li Wei-Hua;Lü Guo-Wei;Huang Lan;Gao Hong;Du Wei-Min.Aspirin Synthesis On-line Measurement by Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2003,19(02): 105-108
98. Song Chun-Min;Yan Zi-Feng;Max Lu.Synthesis and Characterization of Supersurface MCM-41 Zeolites[J]. Acta Phys. -Chim. Sin., 2002,18(03): 279-283
99. Yao Yun-Feng;Zhang Mai-Sheng;Yang Yan-Sheng.Synthesis of Nano-sized MCM-41 Mesoporous Molecular Sieve by[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1117-1121
100. Wang Shu-Guo;Wu Dong;Sun Yu-Han;Zhong Bing;Deng Feng;Yue Yong;Luo Qin.Synthesis of MCM-48 under High Pressure[J]. Acta Phys. -Chim. Sin., 2001,17(07): 659-661
101. Wang Tong-Wen;Dai Le-Rong.Synthesis of Hexagonal Mesostructured Titaniumcontaining Silica by Mixed Supramolecular Templating[J]. Acta Phys. -Chim. Sin., 2001,17(01): 10-14
102. Gong Yan-Jun;Li Zhi-Hong;Wu Dong;Sun Yu-Han.Interface Characteristics of Organo-MSU-x Silica[J]. Acta Phys. -Chim. Sin., 2001,17(01): 1-4
103. Wang Tong-Wen, Chen Jing-Lei, Dai Le-Rong.Synthesis of Cubic Mesoporous Titanium-containing Silica by Mixed Surfactant Templating[J]. Acta Phys. -Chim. Sin., 2000,16(05): 385-388
104. TANY Yan-Ping, YUAN Sha, GUO Yu-Zhong, HUANG Rui-An, WANG Jian-Hua, YANGBin, DAI Yong-Nian.Magnesiothermic Reduction Preparation and Electrochemical Properties of Highly Ordered Mesoporous Si/C Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
105. LI Chun-Yang, GENG Long-Long, YANG Xu-Wei, WU Shu-Jie, ZHANG Wen-Xiang, LIU Gang.Influence of Surface Properties of Mesoporous Carbon on the Adsorption Removal of Ammonia with Low Concentration[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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