Please wait a minute...
Acta Phys. Chim. Sin.  2013, Vol. 29 Issue (02): 371-376    DOI: 10.3866/PKU.WHXB201211146
CATALYSIS AND SURFACE SCIENCE     
Determination of the Adsorption of Xanthate on Mesoporous CuAl2O4 Using a Continuous Online In situ ATR-FTIR Technology
GE Dong-Lai, FAN Ying-Ju, YIN Long, SUN Zhong-Xi
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China
Download:   PDF(726KB) Export: BibTeX | EndNote (RIS)      

Abstract  

In this study, mesoporous nano CuAl2O4 was synthesized through a coprecipitation method using simple mixed templates consisting of butylamine and dodecanol. The sample was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorptiondesorption techniques. The absorption of butyl and octyl xanthate from aqueous solution onto the synthesized mesoporous CuAl2O4 solid surfaces was studied by a continuous, online, in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) technique. The CuAl2O4 membrane used in the adsorption experiments was prepared on a germanium internal reflection element using the chemical bath deposition method. During the adsorption process, the characteristic peak height of xanthate at 1200 and 1040 cm-1 emerged and gradually increased. By monitoring changes in the peak height at 1200 cm-1, which was assigned to the stretching vibration caused by C-O-C of the adsorbed xanthate molecules, the adsorption kinetics were studied. The adsorption results show that mesoporous CuAl2O4 has a high chemisorption capacity for xanthate, which reaches 236 and 300 mg·g-1 for butyl and octyl xanthate, respectively, within 100 min. The adsorption kinetics can be described by a pseudo-second-order reaction model.



Key wordsIn situ adsorption      Attenuated total reflection Fourier transform infrared spectroscopy      Online      Mesopore      CuAl2O4      Xanthate     
Received: 26 September 2012      Published: 14 November 2012
MSC2000:  O647  
Fund:  

The project was supported by the National Natural Science Foundation of China (51274104, 50874052) and National Key Basic Research Program of China (973) (2011CB933700).

Cite this article:

GE Dong-Lai, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Determination of the Adsorption of Xanthate on Mesoporous CuAl2O4 Using a Continuous Online In situ ATR-FTIR Technology. Acta Phys. Chim. Sin., 2013, 29(02): 371-376.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201211146     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2013/V29/I02/371

(1) Lotter, N. O.; Bradshaw, D. J. Minerals Engineering 2010, 23 (11-13), 945. doi: 10.1016/j.mineng.2010.03.011
(2) Bag, B.; Das, B.; Mishra, B. K. Minerals Engineering 2011, 24 (8), 760. doi: 10.1016/j.mineng.2011.01.006
(3) Hao, Y.;Wu, X. L.; Mo, C. H.; Li, Y.W.; Huang, X. P.; Qu, X.L.; Xiang, L.; Liang, J. H. Journal of Central South University (Science and Technology) 2011, 42 (10), 3213. [郝艳, 吴小莲, 莫测辉, 李彦文, 黄献培, 屈相龙, 向垒, 梁嘉华. 中南大学学报(自然科学版), 2011, 42 (10), 3213.]
(4) Chen, S. H.; Gong,W. Q.; Mei, G. J.; Chen, X. D.; Yan, H. Z.Journal of Central South University (Science and Technology)2011, 42 (2), 546. [陈绍华, 龚文琪, 梅光军, 陈晓东, 鄢恒珍.中南大学学报(自然科学版), 2011, 42 (2), 546.]
(5) Ballarini, N.; Cavani, F.; Passeri, S.; Pesaresi, L.; Lee, A. F.;Wilson, K. Appl. Catal. A 2009, 366 (1), 184. doi: 10.1016/j.apcata.2009.07.003
(6) Fortunato, G.; Oswald, H. R.; Reller, A. J. Mater. Chem. 2001,11, 905. doi: 10.1039/b007306g
(7) Li,W. C.; Comotti, M.; Lu, A. H.; Schüth, F. Chem. Commun.2006, 1772. doi: 10.1039/B601109H
(8) Jiang, Y. Y.; Li, J. G.; Sui, X. T.; Ning, G. L.;Wang, C. Y.; Gu,X. M. J. Sol-Gel Sci. Technol. 2007, 42, 41. doi: 10.1007/s10971-006-1525-3
(9) Ding, D.W.; Long, M. C.; Cai,W. M.;Wu, Y. H.;Wu, D. Y.;Chen, C. Chem. Commun. 2009, 3588. doi: 10.1039/B903865E
(10) Lv,W. Z.; Liu, B.; Qiu, Q.;Wang, F.; Luo, Z. K.; Zhang, P. X.;Wei, S. H. J. Alloys. Compd. 2009, 479 (1-2), 480. doi: 10.1016/j.jallcom.2008.12.111
(11) Tabor, R. F.; Rastoe, J.; Dowding, P. Langmuir 2009, 25 (17),9785. doi: 10.1021/la901138h
(12) Roonasi, P.; Holmgren, A. J. Colloid Interface Sci. 2009, 333,27. doi: 10.1016/j.jcis.2008.12.080
(13) Potapova, E.; Grahn, M.; Holmgren, A.; Hedlund, J. J. Colloid Interface Sci. 2010, 345, 96. doi: 10.1016/j.jcis.2010.01.056
(14) Yang, X. F.; Roonasia, P.; Jolsterå, R.; Holmgrena, A. Colloid Surface A: Physicochem. Eng. Aspects 2009, 343, 24. doi: 10.1016/j.colsurfa.2009.01.041
(15) Liu, H.; Liu, P.; You, K.; Luo, H. Catal. Commun. 2010, 11,887. doi: 10.1016/j.catcom.2010.04.001
(16) Mitchell,W.; Goldberg, S.; Al-Abadleh, H. A. J. Colloid Interface Sci. 2011, 358, 534. doi: 10.1016/j.jcis.2011.02.040
(17) Zheng, T. T.; Sun, Z. X.; Yang, X. F.; Holmgren, A. Chem. Cent. J. 2012, 6 (26), 1. doi: 10.1186/1752-153X-6-26
(18) Potapova, E.; Yang, X.;Westerstrand, M.; Grahn, M.; Holmgren,A.; Hedlund, J. Miner. Eng. 2012, 36-38, 87. http://dx.doi.org/10.1016/j.mineng. 2012.03.030
(19) Fredriksson, A.; Larsson, M. L.; Holmgren, A. J. Colloid Interface Sci. 2005, 286, 1. doi: 10.1016/j.jcis.2005.01.022
(20) Masoud, S. N.; Fatemeh, D.; Masoud, F. J. Sol-Gel Sci. Technol.2009, 51, 48. doi: 10.1007/s10971-009-1940-3
(21) Mielczarski, J.; Leppinen, J. Surf. Sci. 1987, 187 (2-3), 526.doi: 10.1016/S0039-6028(87)80073-0
(22) Colthup, N. B.; Porter Powel, L. Spectrochim Acta 1987, 43A (3), 317. doi: org/10.1016/0584-8539(87)80111-3
(23) Larsson, M. L.; Holmgren, A.; Forsling,W. Langmuir 2000, 16 (21), 8129. doi: 10.1021/la000454+
(24) Fredriksson, A.; Hellström, P.; Öberg, S.; Holmgren, A.J. Phys. Chem. C 2007, 111 (26), 9299. doi: 10.1021/jp071444l
(25) Chernyshova, I. V. J. Phys. Chem. B 2001, 105 (34), 8185. doi: 10.1021/jp011026v
(26) Hellström, P.; Holmgren, A.; Öberg, S. J. Phys. Chem. C 2007,111 (45), 16920. doi: 10.1021/jp074254j

[1] NIU Hui-Chang, JI Dan, LIU Nai-An. Method for Optimizing the Kinetic Parameters for the Thermal Degradation of Forest Fuels Based on a Hybrid Genetic Algorithm[J]. Acta Phys. Chim. Sin., 2016, 32(9): 2223-2231.
[2] SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao. Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Phys. Chim. Sin., 2015, 31(7): 1430-1436.
[3] HU Si, ZHANG Qing, YIN Qi, ZHANG Ya-Fei, GONG Yan-Jun, ZHANG Ying, WU Zhi-Jie, DOU Tao. Catalytic Conversion of Methanol to Propylene over HZSM-5 Modified by NaOH and (NH4)2SiF6[J]. Acta Phys. Chim. Sin., 2015, 31(7): 1374-1382.
[4] CHEN Jun, WANG Shuang-Qing, YANG Guo-Qiang. Nonlinear Optical Limiting Properties of Organic Metal Phthalocyanine Compounds[J]. Acta Phys. Chim. Sin., 2015, 31(4): 595-611.
[5] ZHU Chang-Li, WANG Wen-Yong, TIAN Dong-Mei, WANG Jiao, QIU Yong-Qing. Second-Order Nonlinear Optical Properties of Bis-Cyclometalated Iridium(Ⅲ) Isocyanide Complexes[J]. Acta Phys. Chim. Sin., 2015, 31(2): 245-252.
[6] ZHANG Lan-Lan, SONG Yu, LI Guo-Dong, ZHANG Shao-Long, SHANG Yun-Shan, GONG Yan-Jun. ZSM-5 Zeolite with Micro-Mesoporous Structures Synthesized Using Different Templates for Methanol to Propylene Reaction[J]. Acta Phys. Chim. Sin., 2015, 31(11): 2139-2150.
[7] HOU Na, LI Ying, WU Di, LI Zhi-Ru. Structures and Nonlinear Optical Properties of Alkali Metal-Doped t-Bu-calix[4]arene Molecules[J]. Acta Phys. Chim. Sin., 2014, 30(7): 1223-1229.
[8] WANG Liu-Heng, PENG Rong-Zong, ZHAO Yu-Xia, WU Fei-Peng. Synthesis and Optical Limiting Behaviors of Malononitrile Derivatives[J]. Acta Phys. Chim. Sin., 2014, 30(5): 980-986.
[9] SHEN Qi, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces[J]. Acta Phys. Chim. Sin., 2014, 30(2): 359-364.
[10] LIU Huan, ZANG Na, ZHAO Fang-Yao, LIU Kun, LI Yue, RUAN Wen-Juan. Synthesis and Nonlinear Optical Properties of Porphyrin-Salen Type Homo- and Hetero-Binuclear Metal Complexes[J]. Acta Phys. Chim. Sin., 2014, 30(10): 1801-1809.
[11] HONG Xiao-Ting, WU Xiao-Hui, MO Ming-Yue, LUO Zhi-Ping, HUI Kwan San, CHEN Hong-Yu, LI Lai-sheng, HUI Kwun Nam, ZHANG Qiu-Yun. Synthesis and Electrochemical Capacitive Performances of Novel Hierarchically Micro-Meso-Structured Porous Carbons Fabricated Using Microporous Rod-Like Hydroxyapatites as a Template[J]. Acta Phys. Chim. Sin., 2013, 29(02): 298-304.
[12] SONG Hong-Juan, ZHANG Meng-Ying, SUN Xiu-Xin, SUN Shi-Ling QIU Yong-Qing. Nonlinear Optical Properties of a Series of 6,12-Diethynylindeno[1,2-b]fluorene Derivatives[J]. Acta Phys. Chim. Sin., 2012, 28(12): 2839-2844.
[13] LING Xing, DING Chuan-Fan. Online Electrochemistry/Electrospray Mass Spectrometry with a Coaxial Probe for Investigation of Electrochemical Derivatization of Anthracene with Dodecylamine[J]. Acta Phys. Chim. Sin., 2012, 28(11): 2616-2624.
[14] CHEN Jing-Wei, REN Quan, WANG Xin-Qiang, YANG Xu-Dong, LI Ting-Bin, YANG Hong-Liang, ZHU Lu-Yi, ZHANG Jing-Nan, LI Guo-Chao. Third-Order Nonlinear Optical Properties of 1,3-Dithiole-2-thione- 4,5-dithiolate Compounds at Different Wavelengths[J]. Acta Phys. Chim. Sin., 2012, 28(04): 942-948.
[15] FAN Li-Tao, LI Ying, WU Di, LI Zhi-Ru, SUN Chia-Chung. Structures and Nonlinear Optical Properties of the Alkalides M+aza222M′- (M, M′=Li, Na, K)[J]. Acta Phys. Chim. Sin., 2012, 28(03): 555-560.