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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(02)>> 397-402     doi: 10.3866/PKU.WHXB201211161         中文摘要
CATALYSIS AND SURFACE SCIENCE
Photocatalytic Reduction of CO2 into CH4 Using SrB2O4 Catalyst
GUO Li-Mei1,2, KUANG Yuan-Jiang3, YANG Xiao-Dan1,2, YU Yan-Long1,2, YAO Jiang-Hong1,2, CAO Ya-An1,2
1 College of Physics, Nankai University, Tianjin 300071, P. R. China;
2 Teda Applied Physics School, Key Laboratory of Weak Light Nonlinear Photonics, Ministry of Education, Nankai University, Tianjin 300457, P. R. China;
3 Maintenance Training Center, Zhenjiang Watercraft College, Zhenjiang 212000, Jiangsu Province, P. R. China
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The reduction of carbon dioxide to methane in the presence of water was used to evaluate the photocatalytic activity of a prepared strontium metaborate catalyst. The strontium metaborate (SrB2O4) was prepared by a simple sol-gel method, and was shown to exhibit better photocatalytic performance than TiO2 (P25) under UV-light irradiation. The structure, morphology, and energy levels of the photocatalysts were studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), photoluminescence (PL) spectroscopy, and UV-Vis diffuse reflectance absorption spectroscopy. It was revealed that the SrB2O4 valence band (VB) was located at 2.07 V (vs normal hydrogen electrode, NHE), which is more positive than Eredoxo (H2O/H+) (0.82 V (vs NHE)); the conduction band was estimated to be -1.47 V (vs NHE)), which is more negative than Eredoxo (CO2/CH4) (-0.24 V (vs NHE)). Therefore, it is clear that strontium metaborate is capable of transforming CO2 into CH4. Moreover, the potential at the bottom of the conduction band for SrB2O4 is more negative than that for TiO2(P25), leading to a higher deoxidization capacity, which also favors CH4 formation. Thus, SrB2O4 exhibits a higher photocatalytic activity than TiO2(P25).



Keywords: Strontium metaborate   Photocatalytic reduction of CO2   CH4   Redox potential   Photocatalytic activity  
Received: 2012-09-28 Accepted: 2012-11-15 Publication Date (Web): 2012-11-21
Corresponding Authors: Email: caoyaan@yahoo.com

Fund: The project was supported by the National Natural Science Foundation of China (51072082, 21173121).

Cite this article: GUO Li-Mei, KUANG Yuan-Jiang, YANG Xiao-Dan, YU Yan-Long, YAO Jiang-Hong, CAO Ya-An. Photocatalytic Reduction of CO2 into CH4 Using SrB2O4 Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29 (02): 397-402.    doi: 10.3866/PKU.WHXB201211161

(1) Lo, C. C.; Hung, C. H.; Yuan, C. S.;Wu, J. F. Sol. Energy Mater. Sol. Cells 2007, 91, 1765. doi: 10.1016/j.solmat.2007.06.003
(2) Dimitrijevic, N. M.; Vijayan, B. K.; Poluektov, O. G.; Rajh, T.;Gray, K. A.; He, H; Zapol, P. J. Am. Chem. Soc. 2011, 133,3964. doi: 10.1021/ja108791u
(3) Tseng, I. H.; Chang,W. C.;Wu, J. Appl. Catal. B: Environ.2002, 37, 37. doi: 10.1016/S0926-3373(01)00322-8
(4) Xia, X. H.; Jia, Z. J.; Yu, Y.; Liang, Y.;Wang, Z.; Ma, L. L.Carbon 2007, 45, 717. doi: 10.1016/j.carbon.2006.11.028
(5) Varghese, O. K.; Paulose, M.; LaTempa, T. J.; Grimes, C. A.Nano Lett. 2009, 9, 731. doi: 10.1021/nl803258p
(6) Ikeue, K.; Yamashita, H.; Anpo, M. J. Phys. Chem. B 2001, 105,8350. doi: 10.1021/jp010885g
(7) Li, D.; Haneda, H.; Hishita, S.; Ohashi, N. Chem. Mater. 2005,17, 2596. doi: 10.1021/cm049099p
(8) Tan, S. S.; Zou, L. D.; Hu, E. Catal. Today 2006, 115, 269. doi: 10.1016/j.cattod.2006.02.057
(9) Tan, S. S.; Zou, L. D.; Hu, E. Catal. Today 2008, 131, 125. doi: 10.1016/j.cattod.2007.10.011
(10) Wang, C.; Thompson, R. L.; Baltrus, J.; Matranga, C. J. Phys. Chem. Lett. 2010, 1, 48. doi: 10.1021/jz9000032
(11) Pan, P.W.; Chen, Y.W. Catal. Commun. 2007, 8, 1546. doi: 10.1016/j.catcom.2007.01.006
(12) Liu, Q.; Zhou, Y.; Kou, J. H.; Chen, X. Y.; Tian, Z. P.; Gao, J.;Yan, S. C.; Zou, Z. G. J. Am. Chem. Soc. 2010, 132, 14385. doi: 10.1021/ja1068596
(13) Yan, S. C.; Ouyang, S. X.; Gao, J.; Yang, M.; Feng, J. Y.; Fan,X. X.;Wan, L. J.; Li, Z. S.; Ye, J. H.; Zhou, Y.; Zou, Z. G.Angew. Chem. 2010, 122, 6544. doi: 10.1002/ange.201003270
(14) Fu, Y. H.; Sun, D. R.; Chen, Y. J.; Huang, R. K.; Ding, Z. X.;Fu, X. Z.; Li, Z. H. Angew. Chem. Int. Edit. 2012, 124, 3420.
(15) Fujimoto, Y.; Yanagida, T.; Yokota, Y.; Kawaguchi, N.; Fukuda,K.; Totsuka, D.;Watanab, K.; Yamazaki, A.; Yoshikawa, A. Opt. Mater. 2011, 34, 444. doi: 10.1016/j.optmat.2011.04.016
(16) Li, R.; Bao, L. H.; Li, X. D. CrystEngComm 2011, 13, 5858.doi: 10.1039/c1ce05537b
(17) Yang, H. G.; Liu, G.; Qiao, S. Z.; Sun, C. H.; Jin, Y. G.; Smith,S. C.; Zou, J.; Cheng, H. M.; Lu, G. Q. J. Am. Chem. Soc. 2009,131, 12868. doi: 10.1021/ja903463q
(18) Xu, J. H.; Dai,W. L.; Li, J. X.; Cao, Y.; Li, H. X.; He, H. Y.;Fan, K. N. Catal. Commun. 2008, 9, 146. doi: 10.1016/j.catcom.2007.05.043
(19) Li, R.; Tao, X. Y.; Li, X. D. J. Mater. Chem. 2009, 19, 983. doi: 10.1039/b816518a
(20) Cao, Y. Q.; He, T.; Chen, Y. M.; Cao, Y. A. J. Phys. Chem. C2010, 114, 3627. doi: 10.1021/jp100786x
(21) Li, D.; Haneda, H.; Hishita, S.; Ohashi, N. Chem. Mater. 2005,17, 2596. doi: 10.1021/cm049099p
(22) Serpone, N.; Lawless, D. Khairutdinov, R. J. Phys. Chem. 1995,99, 16655. doi: 10.1021/j100045a027
(23) Yu, J. C.; Ho,W.; Yu, J.; Hark, S. K.; Lu, K. Langmuir 2003, 19,3889. doi: 10.1021/la025775v
(24) Saraf, L. V.; Patil, S. I.; Ogale, S. B. Int. J. Mod. Phys. B 1998,12, 2635. doi: 10.1142/S0217979298001538
(25) Yuan, J. X.;Wu, Q.; Zhang, P.; Yao, J. H.; He, T.; Cao, Y. A.Environ. Sci. Technol. 2012, 46, 2330. doi: 10.1021/es203333k
(26) Li, D.; Haneda, H.; Hishita, S.; Ohashi, N. Chem. Mater. 2005,17, 2588. doi: 10.1021/cm049100k
(27) Varghese, O. K.; Paulose, M.; LaTempa, T. J.; Grimes, C. A.Nano Lett. 2009, 9, 731. doi: 10.1021/nl803258p
(28) Izumi, Y. Coord. Chem. Rev. 2012, 10, 1016.
(29) Dimitrijevic, N. M.; Vijayan, B. K.; Poluektov, O. G.; Rajh, T.;Gray, K. A.; He, H. Y.; Zapol, P. J. Am. Chem. Soc. 2011, 133,3964. doi: 10.1021/ja108791u

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