ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(02)>> 351-357     doi: 10.3866/PKU.WHXB201211214         中文摘要
Dynamic Surface Adsorption Properties of Sodium Dodecyl Sulfate Aqueous Solution
FAN Hai-Ming, ZHANG Yi-Nuo, ZHANG Jin, WANG Dong-Ying, GAO Jian-Bo, KANG Wan-Li, MENG Xiang-Can, ZHAO Jian, XU Hai
College of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong Province, P. R. China
Full text: PDF (761KB) HTML Export: BibTeX | EndNote (RIS)

The dynamic surface adsorption properties of aqueous sodium dodecyl sulfate (SDS) solutions were investigated at different concentrations of NaCl using bubble pressure tensiometry MPTC. In the case of ionic surfactants, the existence of a diffuse electric double layer on the surface adsorption layer and around the micelle produces a surface charge. Here, we discuss the influence of the surface charge on the dynamic surface diffusion processes and the micelle properties. It was found that the SDS adsorption process occurred in the presence of a 5.5 kJ·mol-1 adsorption barrier (Ea) that was generated by the surface charge; this barrier significantly decreased the effective diffusion coefficient (Deff) of the dodecyl sulfate ions (DS-). The ratio of the effective diffusion coefficient to the monomer self-diffusion coefficient (D) (Deff/D) was only 0.013. This indicated that at the beginning, the adsorption of SDS followed the mixed kinetic-diffusion controlled model; this is different from the behavior observed for nonionic surfactants. The adsorption barrier was reduced when NaCl was added. Ea was less than 0.3 kJ·mol-1 after the addition of 80 mmol·L-1 of NaCl. This resulted in values of between 0.8 and 1.2 for Deff/D, which was consistent with the diffusion-controlled model that describes the behavior of nonionic surfactants. The characteristic constants for the micelle dissociation rate (k2) were determined from the dynamic surface tension of the SDS micelle solutions. The calculated k values decreased as the NaCl concentration was increased, which demonstrated the existence of surface charge on the SDS micelles; this surface charge increased the repulsive forces between the dodecyl sulfate ions, and promoted the dispersion of the micelles.

Keywords: Sodium dodecyl sulfate   Dynamic surface tension   Surface charge   Adsorption barrier   Micelle dissociation  
Received: 2012-09-25 Accepted: 2012-11-19 Publication Date (Web): 2012-11-21
Corresponding Authors: Email:

Fund: The project was supported by the Taishan Scholars Construction Engineering of Shandong Province (ts20070704), National Natural Science Foundation of China (51234007, 51104169), Natural Science Foundation of Shandong Province, China (ZR2010BQ003, ZR2010EZ006), and National Undergraduate Innovative and Entrepreneurship Training Program of China University of Petroleum (East China), China (201210425011).

Cite this article: FAN Hai-Ming, ZHANG Yi-Nuo, ZHANG Jin, WANG Dong-Ying, GAO Jian-Bo, KANG Wan-Li, MENG Xiang-Can, ZHAO Jian, XU Hai. Dynamic Surface Adsorption Properties of Sodium Dodecyl Sulfate Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2013,29 (02): 351-357.    doi: 10.3866/PKU.WHXB201211214

(1) Rosen, M. J. Surfactant and Interfacial Phenomena; JohnWileyand Sons: New York, 1989.
(2) Aveyard, R.; Haydon, D. A. An Introduction to the Principles of Surface Chemistry; Cambridge Univ. Press: London, 1973.
(3) Myers, D. In Surfactant Science Series; Reiger, M. M., Rhein,L. D. Eds.; Marcal Dekker: New York, 1997; Vol. 68, pp 29-82.
(4) Zhao, F. L. Principles of Enhanced Oil Recovery; ChinaUniversity of Petroleum Press: Dongying, 2006; pp 1-2.[赵福麟. EOR原理. 东营: 石油大学出版社, 2006:1-2.]
(5) McClements, D. J. Food Emulsions: Principles, Practice and Technology; CRC Press: Boca Raton, Florida, 2005.
(6) Fan, H. M.; Han, F.; Liu, Z.; Qin, L.; Li, Z. C.; Liang, D. H.;Ke, F. Y.; Huang, J. B.; Fu, H. L. J. Colloid Interface Sci. 2008,321, 227.
(7) Han, X.; Cheng, X. H.;Wang, J.; Huang, J. B. Acta Phys. -Chim. Sin. 2012, 28, 146. [韩霞, 程新皓, 王江,黄建滨. 物理化学学报, 2012, 28, 146.] doi: 10.3866/PKU.WHXB201228146
(8) Valentini, J. E.; Thomas,W. R.; Sevenhuysen, P.; Jiang, T. S.;Lee, H. O.; Yi, L.; Yen, S. C. Ind. Eng. Chem. Res. 1991, 30,453. doi: 10.1021/ie00051a004
(9) Knoche, M.; Tamura, H.; Bukovac, M. J. J. Agric. Food Chem.1991, 39, 202. doi: 10.1021/jf00001a041
(10) Tang, X. L.; Dong, J. F.; Li, X. F. J. Colloid Interface Sci. 2008,325, 223. doi: 10.1016/j.jcis.2008.05.055
(11) Zhang, L.; Luo, L.; Zhao, S.; Xu, Z. C.; An, J. Y.; Yu, J. Y.J. Petro. Sci. Eng. 2004, 41, 189. doi: 10.1016/S0920-4105(03)00153-0
(12) Zhao, Z. K.; Li, Z. S.; Zhao, S.; Qiao,W. H.; Cheng, L. B.Colloids Surf. A: Physicochem. Eng. Aspects 2005, 259, 71.doi: 10.1016/j.colsurfa.2005.02.012
(13) Marinova, K. G.; Basheva, E. S.; Nenova, B.; Temelska, M.;Mirarefi, A.Y. Food Hydrocolloids 2009, 23, 1864. doi: 10.1016/j.foodhyd.2009.03.003
(14) Chang, C. H.; Franses, E. I. Colloids Surf. A: Physicochem. Eng. Aspects 1995, 100, 1. doi: 10.1016/0927-7757(94)03061-4
(15) Eastoe, J.; Dalton, J. S.; Rogueda, P. G. A.; Crooks, E. R.; Pitt,A. R.; Simister, E. A. J. Colloid Interface Sci. 1997, 188, 423.doi: 10.1006/jcis.1997.4778
(16) Ferrari, M.; Liggerieri, L.; Ravera, F. J. Phys. Chem. B 1998,102, 10521. doi: 10.1021/jp9827429
(17) Liggieri, L.; Ferrari, M.; Massa, A.; Francesca, F.; Ravera, F.Colloids Surf. A: Physicochem. Eng. Aspects 1999, 156, 455.doi: 10.1016/S0927-7757(99)00103-X
(18) Eastoe, J.; Dalton, J. S. Adv. Colloid Interface Sci. 2000, 85,103. doi: 10.1016/S0001-8686(99)00017-2
(19) Chatterjee, A.; Moulik, S. P.; Sanyal, S. K.; Mishra, B. K.; Puri,P. M. J. Phys. Chem. B 2001, 105, 12823. doi: 10.1021/jp0123029
(20) Ward, A. F. H.; Tordai, L. J. J. Chem. Phys. 1946, 14, 453. doi: 10.1063/1.1724167
(21) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; Chinalight Industry Press: Beijing, 2003, pp 119-122. [赵国玺,朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社,2003: 119-122.]
(22) Kamenka, N.; Lindman, B.; Brun, B. Colloid Polym. Sci. 1974,252, 144. doi: 10.1007/BF01555539
(23) Ravera, F.; Liggieri, L.; Steinchen, A. J. Colloid Interface Sci.1993, 156, 109 doi: 10.1006/jcis.1993.1088
(24) Liggieri, L.; Ravera, F.; Passerone, A. Colloids Surf. A: Physicochem. Eng. Aspects 1996, 114, 351. doi: 10.1016/0927-7757(96)03650-3
(25) Noskov, B.A. Adv. Colloid Interface Sci. 2002, 95, 237. doi: 10.1016/S0001-8686(00)00085-3
(26) Joos, P.; Rillaerts, E. J. Phys. Chem. 1982, 86, 3471. doi: 10.1021/j100214a040
(27) Makievski, A. V.; Fainerman, V. B.; Joos, P. J. Colloid Interface Sci. 1994, 166, 6. doi: 10.1006/jcis.1994.1264
(28) Aniannson, E.;Wall, S. N.; Almgren, M.; Hoffmann, H.;Kielmann, I.; Ulbricht,W.; Zana, R.; Lang, J.; Tondre, C.J. Phys. Chem. 1976, 80, 905. doi: 10.1021/j100550a001
(29) Tondre, C.; Zana, R. J. Colloid Interface Sci. 1978, 66, 544. doi: 10.1016/0021-9797(78)90074-7
(30) Ulbricht,W.; Zana, R. Colloids Surf. A: Physicochem. Eng. Aspects 2001, 183 -185, 487.

1. SUN Zhi-Guo, GAO Xiong-Hou, MA Jian-Tai, ZHANG Li, LIU Hong-Hai, WANG Bao-Jie.Effect of Lauryl Sodium Sulfate on the In situ Crystallization of Small-Grain NaY[J]. Acta Phys. -Chim. Sin., 2015,31(10): 2011-2015
2. GE Song, CHEN Min.Effects of Surface Charge and Electric Field on the Interfacial Thermal Resistance at Liquid/Solid Interfaces[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2939-2943
3. HUANG Zhen-Jian, TAN Chun-Hua, HUANG Xu-Guang.Determination of Surfactant cmc Based on the Fiber Refractive Index Sensor Principle[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1271-1276
4. YANG Hui, HU Min, CHEN Hui-Bo, YANG Shi-Wei, WANG Jin-Ben.Molecular Aggregation Behavior in the Mixture of Amphiphilic Poly(amidoamine)-Based Dendrimer and Sodium Dodecyl Sulfate[J]. Acta Phys. -Chim. Sin., 2010,26(03): 626-630
5. RUAN Xiao-Yun; FANG Yun; FAN Ye.Preparation of Ultrafine Nickel Powders in SDS-PVP Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1513-1518
6. WANG Chun-Rong; FANG Yun; LI Bo.Self-Assembly of Multipod-like Gold Nanoparticles in the Soft Template of SDS-PVP Clusters[J]. Acta Phys. -Chim. Sin., 2008,24(01): 183-186
7. LEI Sheng; ZHANG Jing; HUANG Jian-Bin.Promotion of the Surface Activity and Aggregation Ability of Sodium Dodecylsulfate in Aqueous Solution by Ionic Liquid 1-butyl-3-methyl-imidazolium Tetrafluoroborate[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1657-1661
8. XU Hu-Jun;WANG Zhong-Cai;LIU Xiao-Ya;LÜ Chun-Xu.The Interaction of Esterquat Gemini Surfactant with SDS[J]. Acta Phys. -Chim. Sin., 2006,22(04): 414-418
9. LIU Yan;GUO Xia;GUO Rong.Interaction between N, N-diethylaniline and SDS/n-C5H11OH/H2O Microemulsion[J]. Acta Phys. -Chim. Sin., 2005,21(01): 38-41
10. Bi Zhi-Chu;Liao Wen-Sheng;Qi Li-Yun.Characteristics of Ethanediyl-α,β-bis(cetyldimethylammonium bromide) Dilute Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1015-1019
11. Xu Jian-Xin;Liu Tian-Qing;Guo Rong.Determination of the Diffusion Coefficients of SDS Molecules in SDS/n-C5H11OH/H2O Lyotropic Liquid Crystal[J]. Acta Phys. -Chim. Sin., 2003,19(04): 364-367
12. Yu Ming;Zhang Yu-Ting.Covering of Y(OH)CO3 on AgI and Preparation of Hollow Particles of Y(OH)CO3[J]. Acta Phys. -Chim. Sin., 2002,18(11): 1005-1008
13. Guo Xia;Xu Hui;Guo Rong.The Fluorescence Quenching of Anthracene by Phenothiazine in Sodium Dodecyl Sulfate / Benzyl Alcohol / Water Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(06): 500-503
14. Zhang Zhi-Qing;Xu Gui-Ying;Ye Fan;Zheng Li-Qiang;Luan Yu-Xia.Surface Activity of Mixed System of Dodecyl Betaine and Sodium Dodecyl Sulphate[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1122-1125
15. Fang Yun;Liu Xue-Feng;Xia Yong-Mei;Yang Yang;Cai Kun;Suh Jung-Mok;Cho Heon-Young.Determination of Critical Micellar Aggregation Numbers by Steadystate Fluorescence Probe Method[J]. Acta Phys. -Chim. Sin., 2001,17(09): 828-831
16. Hai Ming-Tan;Han Bu-Xing;Yan Hai-Ke.Investigation on the Interaction of Sodium Dodecyl Sulfate with Poly(Ethylene Oxide) by Electron Spin Resonance and UV Spectrum[J]. Acta Phys. -Chim. Sin., 2001,17(04): 338-342
17. Zhang Xiao-Hong, Fan Yu, Wu Shi-Kang.Effect of Sodium Dodecyl Sulfate on the Behavior of PEO-PPO-PEO Triblock Copolymer in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1999,15(05): 390-397
18. Hai Ming-Tan, Gao Jie, Han Bu-Xing, Yan Hai-Ke, Liu Yun, Han Qi-Yong.Vapour Pressure and Surface Tension of Aqueous Solution SDS-PEO[J]. Acta Phys. -Chim. Sin., 1998,14(08): 747-751
19. Bi Zhi-Chu, Neuman A W.Interaction between BSA and SDBS at Water-air Interface by ADSA Method[J]. Acta Phys. -Chim. Sin., 1998,14(07): 649-653
20. Zhang Yuan-Qin, Zeng Xian-Cheng, Yu Xiao-Qi, Tian An-Min.Effect of SDS Micelles and Premicelles on the Alkaline fading of Malachite Green[J]. Acta Phys. -Chim. Sin., 1998,14(02): 147-153
21. Wu Jiong-Ru; Tian Yong-Chi; Liang Ying-Qiu.Phase Transition of Sodium Dodecyl Sulfate-Water System: Probing by Pyrene Fluorescence[J]. Acta Phys. -Chim. Sin., 1991,7(03): 329-332
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top