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Acta Phys. -Chim. Sin.  2013, Vol. 29 Issue (03): 460-466    DOI: 10.3866/PKU.WHXB201301071
Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin
SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan
Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China
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Increased water solubility of molybdenum trioxide (MoO3) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO3 precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO42- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d5/2 and 3d3/2 binding energies of the product compared with those of MoO3; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo=O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO42- ions. An interaction between β-CD and MoO42- has been revealed and hints at the possibility of exploiting it for improving MoO3 physical properties

Key wordsβ-Cyclodextrin      Molybdenum trioxide      Molecule-ion interaction      Water solubility     
Received: 02 November 2012      Published: 07 January 2013
MSC2000:  O641  

The project was supported by the National Natural Science Foundation of China (21071139) and National Synchrotron Radiation Laboratory at University of Science and Technology of China.

Cite this article:

SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin. Acta Phys. -Chim. Sin., 2013, 29(03): 460-466.

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