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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(03)>> 460-466     doi: 10.3866/PKU.WHXB201301071         中文摘要
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY
Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin
SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan
Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China
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Increased water solubility of molybdenum trioxide (MoO3) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO3 precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO42- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d5/2 and 3d3/2 binding energies of the product compared with those of MoO3; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo=O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO42- ions. An interaction between β-CD and MoO42- has been revealed and hints at the possibility of exploiting it for improving MoO3 physical properties



Keywords: β-Cyclodextrin   Molybdenum trioxide   Molecule-ion interaction   Water solubility  
Received: 2012-11-02 Accepted: 2013-01-07 Publication Date (Web): 2013-01-07
Corresponding Authors: Email: solexin@ustc.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21071139) and National Synchrotron Radiation Laboratory at University of Science and Technology of China.

Cite this article: SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin[J]. Acta Phys. -Chim. Sin., 2013,29 (03): 460-466.    doi: 10.3866/PKU.WHXB201301071

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