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Acta Phys. Chim. Sin.  2013, Vol. 29 Issue (03): 546-552    DOI: 10.3866/PKU.WHXB201301081
ELECTROCHEMISTRY AND NEW ENERGY     
Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material
XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang
College of Material Science & Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P.R. China
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Abstract  

Three-dimensional (3D) hierarchical CNTs/GO/S ternary composites were prepared by solution-based reaction-deposition, using graphene oxide (GO) and carbon nanotubes (CNTs) as precursors. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated a uniform S coating on CNTs/GO which arose because of the large GO specific surface area. CNTs interspersed between the GO layers to form a 3D porous structure. Constant current charge-discharge tests showed that CNTs/GO/S composites had a high discharge capacity and excellent cycling stability, and delivered a high initial discharge capacity of 904 mAh·g-1 at 1C rate. After 50 cycles at the same rate, the reversible capacity remained at 578 mAh·g-1.



Key wordsLithium-sulfur battery      Graphene oxide      Carbon nanotube      Composite      Cycling performance     
Received: 08 October 2012      Published: 08 January 2013
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (21173120), Natural Science Foundation of Jiangsu Province, China (BK2011030), and Funding of Graduate Innovation Center in Nanjing University of Aeronautics and Astronautics, China (kfjj120209).

Cite this article:

XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang. Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material. Acta Phys. Chim. Sin., 2013, 29(03): 546-552.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201301081     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2013/V29/I03/546

(1) Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J.M. Nat. Mater. 2012, 11 (1), 19. doi: 10.1038/nmat3191
(2) Yao, Z. D.;Wei,W.;Wang, J. L.; Yang, J.; Nuli, Y. N. ActaPhys. -Chim. Sin. 2011, 27 (5), 1005. [姚真东, 魏巍, 王久林, 杨军, 努丽燕娜. 物理化学学报, 2011, 27 (5), 1005.]doi: 10.3866/PKU.WHXB20110345
(3) Xiao, L. F.; Cao, Y. L.; Xiao, J.; Schwenzer, B.; Engelhard, M.H.; Saraf, L. V.; Nie, Z. M.; Exarhos, G. J.; Liu, J. Adv. Mater.2012, 24 (9), 1176. doi: 10.1002/adma.201103392
(4) Ai, X. P.; Cao, Y. L.; Yang, H. X. J. Electrochemistry 2012, 18 (3), 224. [艾新平, 曹余良, 杨汉西. 电化学, 2012, 18 (3),224.]
(5) Ji, X. L.; Nazar, L. F. J. Mater. Chem. 2010, 20 (44), 9821. doi: 10.1039/b925751a
(6) Aurbach, D.; Pollak, E.; Elazari, R.; Salitra, G.; Kelley, C. S.;Affinito, J. J. Electrochem. Soc. 2009, 156, A694. doi: 10.1149/1.3148721
(7) Mikhaylik, Y. V.; Akridge, J. R. J. Electrochem. Soc. 2004, 151 (11), A1969. doi: 10.1149/1.1806394
(8) Choi, N. S.; Chen, Z. H.; Freunberger, S. A.; Ji, X. L.; Sun, Y.K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G.Angew. Chem. Int. Edit. 2012, 51 (40), 9994. doi: 10.1002/anie.201201429
(9) Wang,W. K.;Wang, A. B.; Cao, G. P.; Yang, Y. S. ActaPhys. -Chim. Sin. 2004, 20 (12), 1440. [王维坤, 王安邦, 曹高萍, 杨裕生. 物理化学学报, 2004, 20 (12), 1440.] doi: 10.3866/PKU.WHXB20041208
(10) Wang, C.; Chen, J. J.; Shi, Y. N.; Zheng, M. S.; Dong, Q. F.Electrochim. Acta 2010, 55 (23), 7010. doi: 10.1016/j.electacta.2010.06.019
(11) Elazari, R.; Salitra, G.; Garsuch, A.; Panchenko, A.; Aurbach, D.Adv. Mater. 2011, 23 (47), 5641. doi: 10.1002/adma.v23.47
(12) Yin, L. C.;Wang, J. L.; Lin, F. J.; Yang, J.; Nuli, Y. N. EnergyEnviron. Sci. 2012, 5 (5), 6966. doi: 10.1039/c2ee03495f
(13) Rao, M. M.; Li,W. S.; Cairns, E. J. Electrochem. Commun.2012, 17, 1. doi: 10.1016/j.elecom.2011.12.022
(14) Ji, X. L.; Lee, K. T.; Nazar, L. F. Nat. Mater. 2009, 8 (6), 500.doi: 10.1038/nmat2460
(15) Wang, J. L.; Yang, J.; Xie, J. Y.; Xu, N. X.; Li, Y. Electrochem.Commun. 2002, 4 (6), 499.
(16) Ji, L.W.; Rao, M. M.; Aloni, S.;Wang, L.; Cairns, E. J.; Zhang,Y. G. Energy Environ. Sci. 2011, 4 (12), 5053. doi: 10.1039/clee02256c
(17) Wang, D.W.; Zhou, G. M.; Li, F.;Wu, K. H.; Lu, G. Q.; Cheng,H. M.; Gentle, I. R. Phys. Chem. Chem. Phys. 2012, 14 (24),8703. doi: 10.1039/c2cp40808b
(18) Ji, L.W.; Rao, M. M.; Zheng, H. M.; Zhang, L.; Li, Y. C.; Duan,W. H.; Guo, J. H.; Cairns, E. J.; Zhang, Y. G. J. Am. Chem. Soc.2011, 133 (46), 18522. doi: 10.1021/ja206955k
(19) Buglione, L.; Pumera, M. Electrochem. Commun. 2012, 17, 45.doi: 10.1016/j.elecom.2012.01.018
(20) Huang, Z. D.; Zhang, B.; Oh, S.W.; Zheng, Q. B.; Lin, X. Y.;Yousefi, N.; Kim, J. K. J. Mater. Chem. 2012, 22 (8), 3591.doi: 10.1039/c2jm15048d
(21) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
(22) Che, Q.; Zhang, F.; Zhang, X. G.; Lu, X. J.; Ding, B.; Zhu, J. J.Acta Phys. -Chim. Sin. 2012, 28 (4), 837. [车倩, 张方,张校刚, 卢向军, 丁兵, 朱佳佳. 物理化学学报, 2012, 28 (4),837.]doi: 10.3866/PKU.WHXB201202074
(23) Zhang, L.; Ji, L.W.; Glans, P. A.; Zhang, Y. G.; Zhu, J. F.; Guo,J. H. Phys. Chem. Chem. Phys. 2012, 14 (39), 13670. doi: 10.1039/c2cp42866k
(24) Cheon, S. E.; Choi, S. S.; Han, J. S.; Choi, Y. S.; Jung, B. H.;Lim, H. S. J. Electrochem. Soc. 2004, 151, A2067. doi: 10.1149/1.1815153
(25) Chen, J. J.; Zhang, Q.; Shi, Y. N.; Qin, L. L.; Cao, Y.; Zheng, M.S.; Dong, Q. F. Phys. Chem. Chem. Phys. 2012, 14 (16), 5376.doi: 10.1039/c2cp40141j
(26) Wang, Y. X.; Huang, L.; Sun, L. C.; Xie, S. Y.; Xu, G. L.; Chen,S. R.; Xu, Y. F.; Li, J. T.; Chou, S. L.; Dou, S. X.; Sun, S. G. J.Mater. Chem. 2012, 22 (11), 4744. doi: 10.1039/c2jm15041g

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