ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(06)>> 1319-1326     doi: 10.3866/PKU.WHXB201304012         中文摘要
Effect of Designed Zr/Ti Molar Ratio on the Photocatalytic Activity of Sr-Zr-Ti Mixed Oxide Catalysts under Visible Light
HUANG Hai-Feng1, JIA Jian-Ming1, LU Han-Feng2, ZHANG Hong-Hua1, PAN Lie-Qun3
1 College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
2 Research Institute of Catalytic Reaction Engineering, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
3 Environmental Monitoring Station of Fuyang City, Fuyang 311400, Zhejiang Province, P. R. China
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A series of Sr-Zr-Ti (SZT) mixed oxide catalysts were prepared by a fractional-precipitation method. These photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and ultraviolet visible (UV-Vis) diffuse reflectance absorption spectra. Photocatalytic degradation of methylene blue was investigated to determine the photoactivity of the catalyst. It was shown that with a Zr/Ti ratio<1, the SZT mixed oxide catalysts showed improved photocatalytic activity. This was attributed to lattice defects creating active photocatalytic sites because of Zr4+ doping. For Zr/Ti ratios ≥1, the catalysts showed markedly improved photocatalytic activity because of new crystalline phases of SrZrO3 and TinO2n-1 (n=4, 9)that facilitated splitting and conduction for electron/hole. Typical SZT samples (Zr/Ti=4) showed the highest photocatalytic activity, with first-order reaction rate constant 13.5 times that of a SrTiO3 sample.

Keywords: Visible light   Sr-Zr-Ti mixed oxide   Zr/Ti molar ratio   Photocatalytic degradation   Methylene blue  
Received: 2012-11-20 Accepted: 2013-04-01 Publication Date (Web): 2013-04-01
Corresponding Authors: Email:

Fund: The project was supported by the National Natural Science Foundation of China (21107096).

Cite this article: HUANG Hai-Feng, JIA Jian-Ming, LU Han-Feng, ZHANG Hong-Hua, PAN Lie-Qun. Effect of Designed Zr/Ti Molar Ratio on the Photocatalytic Activity of Sr-Zr-Ti Mixed Oxide Catalysts under Visible Light[J]. Acta Phys. -Chim. Sin., 2013,29 (06): 1319-1326.    doi: 10.3866/PKU.WHXB201304012

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