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Acta Phys. -Chim. Sin.  2013, Vol. 29 Issue (06): 1266-1272    DOI: 10.3866/PKU.WHXB201304091
CATALYSIS AND SURFACE SCIENCE     
Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption
FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
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Abstract  

Mesocellular silica foam (MCF) was prepared using P123 (EO20-PO70-EO20) as template and then functionalized with pentaethylenehexamine (PEHA) for CO2 adsorption. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorptiondesorption isotherms, Fourier transform infrared (FTIR) spectroscopy and thermal gravimetric analysis (TGA). These results indicated that after modification with PEHA, the structure of the support itself was undamaged. The highest CO2 adsorption capacity of MCF-PEHA was obtained at 75℃. With increasing PEHA loading, the CO2 adsorption capacity increases and approached the highest adsorption capacity (3.55 mmol·g-1) with a 70% (w) PEHA loading. Moisture improved the CO2 adsorption performance of the adsorbents. Repeated adsorption-desorption cycling indicated that the sorbents maintained stable CO2 adsorption capacity after 4 cycles, indicating potential for regeneration of the adsorbents.



Key wordsMesostructure cellar foam      Pentaethylenehexamine      Adsorption      CO2     
Received: 27 December 2012      Published: 09 April 2013
MSC2000:  O647  
Fund:  

The project was supported by the National Natural Science Foundation of China (21203167).

Cite this article:

FENG Xing-Xing, XIE Jing, HU Geng-Shen, JIA Ai-Ping, XIE Guan-Qun, LUO Meng-Fei. Preparation of Pentaethylenehexamine-Functionalized Mesocellular Silica Foams and Their Application for CO2 Adsorption. Acta Phys. -Chim. Sin., 2013, 29(06): 1266-1272.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201304091     OR     http://www.whxb.pku.edu.cn/Y2013/V29/I06/1266

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