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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(09)>> 2035-2040     doi: 10.3866/PKU.WHXB201306183         中文摘要
CATALYSIS AND SURFACE SCIENCE
Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO2/Al2O3 Molar Ratios
WANG Wu-Gang, ZHANG Shao-Long, ZHANG Lan-Lan, WANG Yan, LIU Xiao-Ling, GONG Yan-Jun, DOU Tao
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry Engineering, University of Petroleum-Beijing, Beijing 102249, P. R. China
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Nanosheet ZSM-5 zeolites with different SiO2/Al2O3 molar ratios have been hydrothermally synthesized by an organic surfactant with a diquaternary ammoniumgroup. The samples were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, X-ray fluorescence spectroscopy (XRF), scanning electron microscopy (SEM) and 27Al magic angle spinning nuclear magnetic resonance (27Al MAS-NMR) techniques. The synthesis conditions of the nanosheets ZSM-5 were studied, including the synthesis factors such as crystallization temperature and time, the amount of structure-directing agent (SDA) and alkalinity. The results showed that shorter crystallization times were required when synthesis was conducted at higher crystallization temperatures, higher SiO2/Al2O3 ratios, larger amounts of structure-directing agent were used, and higher SiO2/Al2O3 ratios. The morphology, BET and mesopore volume changed with increasing SiO2/Al2O3.



Keywords: Nanosheet   ZSM-5 zeolite   Synthetic chemistry   SiO2/Al2O3 ratio  
Received: 2013-04-25 Accepted: 2013-06-14 Publication Date (Web): 2013-06-18
Corresponding Authors: GONG Yan-Jun Email: gongyj@cup.edu.cn

Fund: The project was supported by the State Key Development Program for Basic Research of China (973) (2012CB215002), National Natural Science Foundation of China (21276278, 21176255), and China National PetroleumCorporation (CNPC) Program, China (2011A-2101).

Cite this article: WANG Wu-Gang, ZHANG Shao-Long, ZHANG Lan-Lan, WANG Yan, LIU Xiao-Ling, GONG Yan-Jun, DOU Tao. Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO2/Al2O3 Molar Ratios[J]. Acta Phys. -Chim. Sin., 2013,29 (09): 2035-2040.    doi: 10.3866/PKU.WHXB201306183

(1) Srivastava, R.; Choi, M.; Ryoo, R. Chem. Commun. 2006, 4489.
(2) Tian, Y.; Li, Y. D. Journal of Chemical Industry and Engineering 2013, 64 (2), 393. [田野,李永丹.化工学报,2013, 64 (2), 393.]
(3) Zhang, C.; Liu, Q.; Xu, Z.; Wan, K. Microporous Mesoporous Mat. 2003, 62, 157. doi: 10.1016/S1387-1811(03)00427-X
(4) Bernasconi, S.; van Bokhoven, J. A.; Krumeich, F.; Pirngruber,G. D.; Prins, R. Microporous Mesoporous Mat. 2003, 66,21. doi: 10.1016/j.micromeso.2003.08.022
(5) Triantafillidis, C. S.; Vlessidis, A. G.; Nalbandian, L.;Evmiridis, N. P. Microporous Mesoporous Mat. 2001, 47,369. doi: 10.1016/S1387-1811(01)00399-7
(6) Ogura, M.; Shinomiya, S. Y.; Tateno, J.; Nara, Y.; Nomura, M.;Kikuchi, E.; Matsukata, M. Appl. Catal. 2001, 219, 33. doi: 10.1016/S0926-860X(01)00645-7
(7) Wang, J.; Chen, D. M.; Gu, H. W.; Teng, H.; Ren, X. Q. Nanjing Technol. Univ. (Nat. Sci.) 2010, 32 (4), 100. [王军,陈德民,顾海威,滕晖,任晓乾.南京工业大学学报, 2010, 32 (4),100.]
(8) Jacobsen, C. J. H.; Madsen, C.; Houzvicka, J.; Schmidt, I.;Carlsson, A. J. Am. Chem. Soc. 2000, 122, 7116. doi: 10.1021/ja000744c
(9) Schmidt, I.; Krogh, A.;Wienberg, K.; Carlsson, A.; Brorson,M.; Jacobsen, C. J. H. Chem. Commun. 2000, 2157.
(10) Yang, Z. X.; Xia, Y. D.; Mokaya, R. Adv. Mater. 2004, 16, 727.
(11) Xiao, F. S.; Wang, L.; Yin, C.; Lin, K.; Di, Y.; Li, J.; Xu, R.; Su,D. S.; Schlögl, R.; Yokoi, T.; Tatsumi, T. Angew. Chem. 2006,118, 3162.
(12) Na, K.; Kim, J.; Ryoo, R. Science 2011, 333, 328. doi: 10.1126/science.1204452
(13) Choi, M.; Na, K.; Kim, J.; Sakamoto, Y.; Terasaki, O.; Ryoo, R.Nature 2009, 461, 246. doi: 10.1038/nature08288
(14) Na, K.; Choi, M.; Park, W.; Sakamoto, Y.; Terasaki, O.; Ryoo,R. J. Am. Chem. Soc. 2010, 132, 4169. doi: 10.1021/ja908382n
(15) Na, K.; Park, W.; Seo, Y.; Ryoo, R. Chem. Mater. 2011, 23,1273. doi: 10.1021/cm103245m
(16) Ma, H.; Zhao, Z. L.; Tang, S. J.; Hu, J.; Liu, H. L. Acta Phys. -Chim. Sin. 2011, 27 (3), 689. [马辉,赵志玲,唐圣杰, 胡军, 刘洪来. 物理化学学报, 2011, 27 (3), 389.] doi: 10.3866/PKU.WHXB20110335
(17) Kim, J.; Choi, M.; Ryoo, R. J. Catal. 2010, 269, 219. doi: 10.1016/j.jcat.2009.11.009
(18) Seo, Y.; Cho, K.; Jung, Y.; Ryoo, R. ACS Catal. 2013, 3,713. doi: 10.1021/cs300824e
(19) Hu, S.; Shan, J.; Zhang, Q.; Wang, Y.; Liu, Y. S.; Gong, Y. J.;Wu, Z. J.; Dou, T. Appl. Catal. A 2012, 445-446, 215.

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17. Jiang Hua;Zhao Bi-Ying;Xie You-Chang.Influence of Water on Adsorption Properties of Lithium Exchanged Low Silica X Zeolite[J]. Acta Phys. -Chim. Sin., 2002,18(07): 577-580
18. Zhao Qi, Han Xiu-Wen, Liu Xiu-Mei, Liu Xian-Chun, Zhai Run-Sheng, Bao Xin-He, Lin Li-Wu, Guo Xin-Wen, Zhang Fa-Zhi, Wang Xiang-Sheng.Structure of Highly Siliceous ZSM-5 Zeolites and Ti-ZSM-5 Zeolites Obtained by Indirect Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 320-326
19. Wang Bi-Xun,Fu Yi-Lu,Fang Shu-Nong.A Study of [Cu-O-Cu]2+ Species on Cu-ZSM-5 Zeolite by in situ Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 1995,11(11): 974-978
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