ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(09)>> 2047-2055     doi: 10.3866/PKU.WHXB201306211         中文摘要
Effect of Surface Promoters-Modifying on Catalytic Performance of Cu/ZnO/Al2O3 Methanol Synthesis Catalyst
HAO Ai-Xiang, YU Yang, CHEN Hai-Bo, MAO Chun-Peng, WEI Shi-Xin, YIN Yu-Sheng
Research Institute of Nanjing Chemical Industry Group, Nanjing 210048, P. R. China
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Surface promoters-modified Cu/ZnO/Al2O3 (CZA) catalysts were prepared by a coprecipitationpost impregnation method and evaluated in methanol synthesis fromsyngas. The effects of Zr, Ba, and Mn as promoters, the reaction temperature and run time over CZA and Zr-promoted CZA catalysts on catalytic performance were investigated, respectively. The catalysts were characterized by X-ray diffraction (XRD), N2-sorption, reactive N2O sorption, X-ray photoelectron spectroscopy (XPS), temperature-programmed desorption of H2 (H2-TPD), scanning electron microscopy (SEM), and high-resolution transmittance electron microscopy (HR-TEM). The results showed that the space-time yield (STY) of methanol can be increased noticeably over the Zr-or Ba-promoted CZA catalyst before and after the heating treatment of the catalysts. The introduction of Mn as a promoter onto the CZA catalyst led to a decrease in the STY of methanol before heating treatment. The introduction of Zr as a promoter onto the CZA catalyst can decrease the temperature at which the STY of methanol reached the highest value and also improve the catalytic stability. A hydrogen molecule can be adsorbed and then activated over Cu0 and ZnO. The strong interaction between Cu0 and ZnO is favorable for improving the catalytic performance of the CZA catalyst. The decrease in catalytic performance after heating treatment of the CZA catalysts is attributed to a growth of Cu0 crystallites. Based on the results of catalytic performance and characterization, a possible "bidirectional but synchronous catalytic reaction course" in methanol synthesis from syngas over a CZA catalyst is proposed.

Keywords: Promoter   Zirconium   Barium   Cu/ZnO/Al2O3 catalyst   Methanol synthesis   Reaction course  
Received: 2013-04-08 Accepted: 2013-06-18 Publication Date (Web): 2013-06-21
Corresponding Authors: HAO Ai-Xiang Email:

Fund: The project was supported by the China Petroleum& Chemical Corporation on the Manufacture of Catalyst for Methanol Synthesis from Coal-derived Syngas (HX-KA12F001202).

Cite this article: HAO Ai-Xiang, YU Yang, CHEN Hai-Bo, MAO Chun-Peng, WEI Shi-Xin, YIN Yu-Sheng. Effect of Surface Promoters-Modifying on Catalytic Performance of Cu/ZnO/Al2O3 Methanol Synthesis Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29 (09): 2047-2055.    doi: 10.3866/PKU.WHXB201306211

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54. WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai.Preparation and Luminescent Characteristics of the NaBaPOM4:Tb3+ Green Phosphor[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3317-3321
55. SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao.Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3023-3029
56. SONG Hua, DONG Peng-Fei, ZHANG Xu.Effect of Al Content on the n-Pentane Isomerization of the Solid Superacid Pt-SO2-4 /ZrO2-Al2O3[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2229-2234
57. WANG Jian-Qiang, SHEN Mei-Qing, WANG Jun, WANG Wu-Lin, JIA Li-Wei.Complete Oxidation of Ethanol and Thermal Stability of Ceria-BasedMaterials Modified by Doping Cu[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2249-2254
58. YUAN Peng, LIU Zhong-Yi, SUN Hai-Jie, LIU Shou-Chang.Influence of Calcination Temperature on the Performance of Cu-Al-Ba Catalyst for Hydrogenation of Esters to Alcohols[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2235-2241
59. WU Bao-Hu, ZHANG Shu-Cui, TANG Tao, XU Yao, LIU Yi, WU Zhong-Hua.Small-Angle X-Ray Scattering Studies of Carboxyl Functionalized[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2217-2223
60. YUAN Jin-Fang, LI Jian-Sheng, GU Juan, WANG Fang, SUN Xiu-Yun, HAN Wei-Qing, WANG Lian-Jun.Synthesis and Adsorption Properties of Amino-Functionalized H2N-Zr-Ce-SBA-15 Mesoporous Materials with Short Mesochannels[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1711-1716
61. LI Li, LU Dan, JI Yuan, ZHAO Yue-Hong.Preparation of Nanocomposite Ag/TiO2-ZrO2 and the Microwave Enhanced Photocatalytic Degradation of Methyl Orange[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1323-1329
62. ZHANG Shu-Cui, JIANG Dong, TANG Tao, LI Jun-Hua, XU Yao.Synthesis and Photocatalytic Activity of Highly Dispersed TiO2/SBA-15[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1330-1336
63. HE Gui-Ping, ZHANG Jiang, YAO Ruo-He.Preparation, Structure and Photoluminescence of Er3+ and Ce3+/Ce4+ Doped β-BaB2O4 Nanorods[J]. Acta Phys. -Chim. Sin., 2010,26(03): 685-690
64. WANG Jin-E, YANG Chun.Direct Syntheses and Characterizations of PW11/SBA-15 Mesoporous Hybrid Materials[J]. Acta Phys. -Chim. Sin., 2010,26(02): 515-520
65. AMEMIYA Takashi, WANG Jichang.Design of Photo-Controlled Chemical Oscillators[J]. Acta Phys. -Chim. Sin., 2010,26(01): 99-109
66. YUAN Na, CHENG Gang, WANG De-Kun, AN Yan-Qing, DU Zu-Liang, WU Si-Xin.Preparation of ZnS Nanobundles by SBA-15 Template and Their Photoelectric Properties[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2575-2580
67. LIU Jian, ZHAO Zhen, ZHANG Zhe, XU Chun-Ming, DUAN Ai-Jun, JIANG Gui-Yuan.Selective Oxidation of Ethane over SBA-15 Mesoporous Zeolite Supported Vanadium-Based Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2467-2474
68. GURTEN T., SERINDAG O..Synthesis of Immobilized Schiff Base Complexes as Ligand Exchange Matrix[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2218-2224
69. WANG Yue-Juan, JIN Wei-Yang, WANG Xue-Li, JIN Ling-Yun, LU Ji-Qing, LUO Meng-Fei.Synthesis of Spherical SBA-15 Particles under Mixed and Dilute Electrolyte Conditions[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1550-1554
70. LANG Bao, LI Xiu-Jin, JI Sheng-Fu, FABIEN Habimana, LI Cheng-Yue.Effect of La Promoter on the Structure and Performance of Ni/SBA-15 Catalyst in the Reforming of Simulated Biogas to Syngas[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1611-1617
71. ZENG Ying, MA Min-Rui.Predominance Diagram of Dissolved Species and Pourbaix Diagram of V-H2O Systemat High Vanadium Concentration[J]. Acta Phys. -Chim. Sin., 2009,25(05): 953-957
72. ZHAO Qing-Xun; GENG Bo; WANG Shu-Biao; BIAN Fang; GUAN Li; LIU Bao-Ting.Effect of Hydrogen on the Ferroelectric Properties of PbZr0.5Ti0.5O3 during Forming Gas Annealing[J]. Acta Phys. -Chim. Sin., 2009,25(01): 183-186
73. ZHANG Nuo-Wei, HUANG Chuan-Jing, KUANG Fei-Ping, GAO Xiao-Xiao, WENG Wei-Zheng, WAN Hui-Lin.Effect of a Mg Promoter on the Structure and Catalytic Performance of a Co/Mg/HZSM-5 Catalyst for the Partial Oxidation of Methane to Syngas[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2165-2171
74. HUANG Xiao-Fan; JI Sheng-Fu; WU Ping-Yi; LIU Qian-Qian; LIU Hui; ZHU Ji-Qin; LI Cheng-Yue.Structure and Hydrodesulfurization Performances of Ni2P/SBA-15 Catalysts[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1773-1779
75. LEI Xue-Ling; ZHU Heng-Jiang; WANG Xian-Ming; LUO You-Hua.Study on Structures and Properties of ZrnB(n=1-13) Clusters Using DFT[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1655-1661
76. ZHANG Lei, ZHENG Ling-Min, GUO Jia-Xiu, WU Dong-Dong, GONG Mao-Chu, WANG Jian-Li, CHEN Yao-Qiang.Structure Evolution Process of Ce0.65Zr0.25Y0.1O1.95 Prepared by Oxidation-Coprecipitation Method[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1342-1346
77. LIN Tao; ZHANG Qiu-Lin; LI Wei; GONG Mao-Chu; XING Yi-Xun; CHEN Yao-Qiang.Monolith Manganese-Based Catalyst Supported on ZrO2-TiO2 for NH3-SCR Reaction at Low Temperature[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1127-1131
78. LI Chun-Hong; QIU Wei-Hua; KANG Xiao-Li; CHOU Kuo-Chih; LU Xiong-Gang; LI Fu-Shen.Kinetics of Synthesis of Ba1.0Co0.7Fe0.2Nb0.1O3-δ through Solid-Solid Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(05): 767-771
79. LIN Ming-Gui; FANG Ke-Gong; LI De-Bao; SUN Yu-Han.Effect of Zn and Mn Promoters on Copper-Iron Based Catalysts for Higher Alcohol Synthesis[J]. Acta Phys. -Chim. Sin., 2008,24(05): 833-838
80. PEI Su-Peng; ZHANG Bin; JIAO Kun; BAO Ren-Lie; YUE Bin; HE He-Yong.Nanostructured CoMoO4 Supported on Mesoporous SBA-15 for Catalytic Oxidative Dehydrogenation of Propane to Propene[J]. Acta Phys. -Chim. Sin., 2008,24(04): 561-564
81. AKGEMCI Emine G.; BINGOL Haluk; OZCELIK Mehmet; ERSOZ Mustafa.Investigation of the Lipophilicity of 2-Benzoylpyridine-Thiosemicarbazone Based on the Ion Transfer across the Liquid/Liquid Interface[J]. Acta Phys. -Chim. Sin., 2008,24(04): 619-624
82. XIAO Xue-Zhang; CHEN Li-Xin; FAN Xiu-Lin; GE Hong-Wei; LI Shou-Quan; YING Tiao; WANG Xin-Hua; CHEN Chang-Pin
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83. LIN Tao; LI Wei; GONG Mao-Chu; YU Yao; DU Bo; CHEN Yao-Qiang.Prepareration of ZrO2-TiO2-CeO2 and Its Application in the Selective Catalytic Reduction of NO with NH3[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1851-1856
84. XU Wei-Xing.Polarizabilities of Nanoparticles of SiO2 and ZrO2[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1808-1810
85. MA Na; JI Sheng-Fu; WU Ping-Yi; HU Lin-Hua; NIE Ping-Ying.Preparation, Characterization and Catalytic Performance for Hydrodesulfurization of WxC/SBA-16 Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1189-1194
86. DANG Wang-Juan; HE Jian-Ping; ZHOU Jian-Hua; JI Ya-Jun; LIU Xiao-Lei; MEI Tian-Qing; LI Hu-Lin.Dispersion and Electrocatalytic Performance of Platinum Nanoparticles Supported on Ordered Mesoporous Carbon[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1085-1089
87. GE Li; HUI Xi-Dong; CHEN Guo-Liang; LIU Zi-Kui.Prediction of the Glass-Forming Ability of Cu-Zr Binary Alloys[J]. Acta Phys. -Chim. Sin., 2007,23(06): 895-899
88. ZHAO Hui-Ling; HU Jun; WANG Jian-Jun; ZHOU Li-Hui; LIU Hong-Lai.CO2 Capture by the Amine-modified Mesoporous Materials[J]. Acta Phys. -Chim. Sin., 2007,23(06): 801-806
89. LIAKATHALIKHAN Faize; SIVAGURUNATHAN Periyasamy.Dielectric Relaxation ofMethyl Methacrylate and Ethyl Methacrylate on Complexation with Phenols[J]. Acta Phys. -Chim. Sin., 2007,23(04): 513-516
90. ZHOU Li-Hui; ZHANG Li-Zhong; HU Jun; ZHAO Xiu-Ge; LIU Hong-Lai.Direct Synthesis ofMesoporous SBA-15 Functionalized with Quaternary AmmoniumOrganic Group[J]. Acta Phys. -Chim. Sin., 2007,23(04): 620-624
91. MA Liang; MA Jie; LIU Hui.Composite Electrodeposition of CoNiP-BaFe12O19Magnetic Thin Film[J]. Acta Phys. -Chim. Sin., 2007,23(04): 590-594
92. BINGOL Haluk;ATALAY Tevfik.Study of Kinetics of Complexation Reaction of Co2+ with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone and Kinetic-spectrophotometric Determination of Cobalt[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1484-1488
93. HAN Cheng-Hui;LIU Bing-Hua;ZHANG Hui-Liang;SHEN Jian-Yi .Characterization of TiO2–ZrO2and Isopropanol Catalysis Conversion[J]. Acta Phys. -Chim. Sin., 2006,22(08): 993-998
94. CHEN Zhe;YAN You-Wei .Combustion Synthesis and Luminescent Properties of blue-emitting Nanocrystalline Phosphor for PDP Application[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1030-1033
95. XIAO Jian-Hua;LI Xue-Hui;DENG Sha;XU Jian-Chang;WANG Le-Fu.The NOx Oxidation-Storage and Tolerance of SO2 Poison of Mn/Ba/Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(07): 815-819
96. YE Qing; WANG Rui-pu; XU Bo-qing.Structure and Oxygen Mobility of Ce1-xZrxO2 Prepared by Citric Acid Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2006,22(01): 33-37
97. GUAN Hong-bo; LIANG Jian; ZHU Yue-xiang; ZHAO Bi-ying; XIE You-chang.Structure Characterization and Monolayer Dispersion Phenomenon of MgO-ZrO2 Prepared by Co-precipitation[J]. Acta Phys. -Chim. Sin., 2005,21(09): 1011-1016
98. ZHU Ling; WANG Xue-zhong; YU Jun-jie; HAO Zheng-ping.Catalytic Performance of K-Ce0.5Zr0.5O2 Catalysts for Soot Combustion[J]. Acta Phys. -Chim. Sin., 2005,21(08): 840-845
99. SHEN Bin; LU Zhong-hua; CHI Xue-bin; LÜ Hai-feng; REN Tian-rui.Research on Pseudoreceptor Models for the Inhibitors at GABA Receptors via Flexible Atom Receptor Model[J]. Acta Phys. -Chim. Sin., 2005,21(07): 800-803
100. JIA Yu-Xiang; GUO Xiang-Yun.Monte Carlo Simulation of Adsorption Process of CO and H2 in Supercritical Fluids[J]. Acta Phys. -Chim. Sin., 2005,21(03): 306-309
101. TANG Zhi-Yuan;ZHANG Na;LU Xing-He;HUANG Qing-Hua.Characterizations of Spinel LiMn2-xZrxO4 Cathode for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2005,21(01): 89-92
102. Su Wen-Yue;Zhang Yong;Wang Xu-Xu;Fu Xian-Zhi.Reaction Pathway of Photocatalytic Degradation of Methyl-tert-butyl Ether in Water[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1211-1215
103. Shipra Baluja;Pranav Inamdar;Mayur Soni.Acoustical Studies of Schiff Bases in 1,4-dioxane and Dimethylformamide at 308.15 K[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1104-1107
104. Li Chun-Lin;Fu Yi-Lu.Effect on the Carbon Deposit in CO2 Reforming of CH4 over Ni/Ce-Zr-Al-Ox Catalyst by Adding Steam[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 906-910
105. Lu Ai-Jun;Liu Bing;Liu Hai-Bo;Zhou Jia-Ju.3D-QSAR Study of Benzodiazepines at Five Recombinant GABAA/Benzodiazepine Receptor Subtypes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 488-493
106. Li Ling-Xia;Wu Xia-Wan;Wang Hong-Ru;Zhang Zhi-Ping;Yu Hao-Ming.Analysis on Quantitative Relationship between Dielectric Properties and Phase Structure of High Frequency Dielectric System[J]. Acta Phys. -Chim. Sin., 2004,20(04): 396-399
107. Wang Yin-Jie;Qi-Lu.The Influencing Factor for CO2 Absorption of Li2ZrO3 at High Temperature[J]. Acta Phys. -Chim. Sin., 2004,20(04): 364-367
108. Guo Hui-Fen;Zhang Xing-Tang;Liu Bing;Li Yun-Cai;Huang Ya-Bin;Du Zu-Liang.Preparation of Nanometer-sized BaTiO3 Crystallites by Sol-gel Method and Size Effects on Structure[J]. Acta Phys. -Chim. Sin., 2004,20(02): 164-168
109. Chen Qi-Bin;Dong Ya-Ming;Liu Hong-Lai;Hu Ying.Observation of the Domain Morphology of Gemini Surfactant at an Air/Liquid Interface Using BAM[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1069-1072
110. Yang Peng-Cheng;Cai Xiao-Hai;Xie You-Chang.Studies on the Dispersion Structure of Co-precipitated CuO-ZrO2 Mixed Oxides[J]. Acta Phys. -Chim. Sin., 2003,19(08): 714-717
111. Wang Li;Yin Mu-Sheng;Zhu Yong-Fa.A Study of Interface Diffusion and Reaction of Ti/ZrN2/Si Film[J]. Acta Phys. -Chim. Sin., 2003,19(07): 641-646
112. Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yang Le-Fu;Yi Xiao-Dong.Role of Ce on Selective Oxidation of Propane to Acrolein over Ce-Ag-Mo-P-O Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(06): 492-497
113. Xu Run;Ma Zhong-Yi;Yang Cheng;Wei Wei;Sun Yu-Han.Effect of Manganese Promoter on the CuFeZrO2 Catalyst for Higher Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(05): 423-427
114. Jing Xi-Ping;Anthony R. West.AC Impedance Characterization for Microwave Dielectric Material BaEu2Ti4O12[J]. Acta Phys. -Chim. Sin., 2003,19(02): 109-114
115. Liang Jian;Huang Hui-Zhong;Xie You-Chang.The Phases of ZrO2-Al2O3 Composites with High Specific Surface Prepared by Co-precipitation[J]. Acta Phys. -Chim. Sin., 2003,19(01): 30-34
116. Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei.Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(01): 65-69
117. Wang Jun-Wei;Xu Jin-Guang;Tian Zhi-Jian;Xu Yun-Peng;Xu Zhu-Sheng;Lin Li-Wu.Effect of Introduction of Ba, Mn on Thermal Stability and Catalytic Activity to Methane Combustion of Al2O3[J]. Acta Phys. -Chim. Sin., 2002,18(11): 1018-1022
118. Jing Xi-Ping;Anthony R.West.AC Impedance and Gas Concentration Cell Measurements for Ba12Y4.67Ti8O35[J]. Acta Phys. -Chim. Sin., 2002,18(07): 617-623
119. Song Xiang-Zhi;Liu Guang;Zhang Shi-Wei.Synthesis and Crystal Structures of Cancer Cell Inducers of Differentiation PMDH[J]. Acta Phys. -Chim. Sin., 2002,18(06): 545-549
120. Zhang Jun-Ling;Ren Jie;Chen Jian-Gang;Sun Yu-Han.Effect of Manganese Promoter on the Performance of Co/Al2O3 Catalysts for FischerTropsch Synthesis[J]. Acta Phys. -Chim. Sin., 2002,18(03): 260-263
121. Li Xin-Gang;Meng Ming;Lin Pei-Yan;Huang Zhi-Jian;Fu Yi-Lu;Xie Ya-Ning;Hu Tian-Dou.The Study of XAFS for the NOx Storage Catalyst Pt/BaAl2O4-Al2O3[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1072-1076
122. Luo De-Li;Jiang Gang;Zhu Zheng-He;Meng Da-Qiao;Xue Wei-Dong.Ab initio of the Thermodynamic Function for the Hydrogenating of Zirconium-Cobalt Alloy[J]. Acta Phys. -Chim. Sin., 2001,17(10): 913-917
123. Luo De-Li;Zhu Zheng-He;Jiang Gang;Meng Da-Qiao;Xue Wei-Dong.Quantum Mechanical Calculation of the Adsorption of Hydrogen Isotopes on Metallic Zirconium[J]. Acta Phys. -Chim. Sin., 2001,17(07): 626-630
124. Li Han-Sheng;Zhong Shun-He;Wang Jian-Wei;Xiao Xiu-Fen.Effect of K2O on Properties of Cu-Ni/V2O5-SiO2 Catalyst for the Synthesis of Dimethyl Carbonate[J]. Acta Phys. -Chim. Sin., 2001,17(06): 552-554
125. Xu Bo-Qing;Cheng Shi-Biao.Dispersion and Interaction State of Boria on Zirconia Surface[J]. Acta Phys. -Chim. Sin., 2001,17(05): 443-447
126. Chen Jian-Gang;Xiang Hong-Wei;Dong Qing-Nian;Wang Xiu-Zhi;Sun Yu-Han.H2 or CO Chemsorption on Co-based Catalysts for F-T Synthesis[J]. Acta Phys. -Chim. Sin., 2001,17(02): 161-164
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128. Zhao Liang-Zhong, Wang Rui-Lan, Xu Hong-Yu, Li Hong-Cheng, Liu Shi-Hong.XPS Studies of Superconducting Gd-Ba-Cu-O Films[J]. Acta Phys. -Chim. Sin., 1999,15(05): 398-402
129. Jin Rong-Chao, Chen Yan-Xin, Li Wen-Zhao, Ji Ya-Ying, Qin Yong-Sheng, Jiang Yi.Ni/α-Al2O3 Catalyst for the Partial Oxidation of Methane to Syngas[J]. Acta Phys. -Chim. Sin., 1998,14(08): 737-741
130. Chen Hong-Bo, Yu La-Jia, Liao Dai-Wei, Lin Guo-Dong, Zhang Hong-Bin, Cai Qi-Rui.The Effect of Cr2O3 over Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(06): 534-539
131. Wang Gui-Chang, Sun Yu-Han, Zhong Bing.Simulation to the Structure Sensitive of Cu Based catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 337-342
132. Li Ji-Tao,Gao Li-Zhen,Zhang Wei-De.CO Adsorption and Hydrogenation on Crystalline YBa2Cu3Ox Thin Films[J]. Acta Phys. -Chim. Sin., 1997,13(08): 700-705
133. Wang Yuan-Yang,Wu Dong,Fan Yan-Zhen,Sun Yu-Han,Chen Song-Ying.Mechanistic Study on the Effects of Preparation Parameters on the Structure Property of ZrO2 Aerogels[J]. Acta Phys. -Chim. Sin., 1997,13(07): 580-585
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136. Chen Kai-Dong,Yan Qi-Jie.Influence of Ceria on the Structure and Catalytic Property of F-T Synthesis Fe/ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 1996,12(11): 990-994
137. Yuan Xun-Dao,Zeng Guang-Fu,Xi Shi-Quan.Study on the Films Forming Process of Nanosized SnO2 Colloid Particles at the Gas-Liquid Interface[J]. Acta Phys. -Chim. Sin., 1996,12(10): 916-920
138. Lei Yu,Cheng Zhao-Nian,Tang Ding-Yuan.A Study of Structure in β-BAB2O4 Melt by Molecular Dynamics Simulation[J]. Acta Phys. -Chim. Sin., 1996,12(06): 481-484
139. Chen Xiao-Hua.Peng Jing-Cui.Chen Zong-Zhang.Lnduced Optical Absorption of Light Alkali-Doped C60[J]. Acta Phys. -Chim. Sin., 1996,12(06): 564-567
140. Chu Yan-Lai,Li Shu-Ben,Gong Hua,Chen Zheng-Shi.Active Phase and Reaction Mechanism of Methane Partial Oxidation on Ni-Cu-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 1996,12(05): 429-435
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142. Xia Shi-Wen,Li Shu-Ben,Wei Chi-Li,Shen Run-Nan.Stereoselective Epoxidation of Alkenes Catalyzed by Mycobacterium E3 Resting Cell[J]. Acta Phys. -Chim. Sin., 1996,12(03): 218-223
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144. ZHOU Ren-Xian, WEI Jian-Gen, ZHENG Xiao-Ming, WU Hong-Li, LV Guang-Lie.Study on Phase Structure, Pore Structure and catalytic Property of Out-layer ZrO2 on Alumina Base[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1097-1100
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