ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(09)>> 2062-2068     doi: 10.3866/PKU.WHXB201306213         中文摘要
Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn2GeO4 Nanoribbons
DU Shu-Qing, YUAN Yu-Feng, TU Wei-Xia
State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China
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Zn2GeO4 nanoribbons were synthesized via a microwave-hydrothermal method. The effects of reaction factors, such as reaction temperature, amount of reactants and template, were investigated and optimized for the formation of Zn2GeO4 nanoribbons. The products were characterized by various techniques including field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). Photocatalytic activities of the synthesized Zn2GeO4 nanostructures were evaluated for the degradation of aqueous methyl orange. Experimental results indicated that Zn2GeO4 nanoribbons can be synthesized from Zn(CH3COO)2 and GeO2 (molar ratio 2: 1) under microwave irradiation at 160℃ for 20 min. The nanoribbons have uniformsizes with widths of 100 nm and are tens of micrometers in length. Compared with conventional hydrothermal methods, Zn2GeO4 nanoribbons from microwave-hydrothermal synthesis have less native defects, lower PL spectra, 50.7% larger specific surface area, and 54.7% higher photocatalytic activity.

Keywords: Microwave-hydrothermal synthesis   Zn2GeO4   Nanoribbon   Photocatalyst   Degradation of organics  
Received: 2013-04-26 Accepted: 2013-06-18 Publication Date (Web): 2013-06-21
Corresponding Authors: TU Wei-Xia Email:

Fund: The project was supported by the National Natural Science Foundation of China (21106006).

Cite this article: DU Shu-Qing, YUAN Yu-Feng, TU Wei-Xia. Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn2GeO4 Nanoribbons[J]. Acta Phys. -Chim. Sin., 2013,29 (09): 2062-2068.    doi: 10.3866/PKU.WHXB201306213

(1) Tong, H.; Ouyang, S. X.; Bi, Y. P.; Umezawa, N.; Oshikiri, M.;Ye, J. Adv. Mater. 2012, 24 (2), 229. doi: 10.1002/adma.201102752
(2) Chen, C. C.; Ma, W. H.; Zhao, J. C. Chem. Soc. Rev. 2010, 39 (11), 4206. doi: 10.1039/b921692h
(3) Fujishima, A.; Zhang, X. T.; Tryk, D. A. Surf. Sci. Rep. 2008, 63 (12), 515. doi: 10.1016/j.surfrep.2008.10.001
(4) Yan, H. J.; Yang, J. H.; Ma, G. J.;Wu, G. P.; Zong, X.; Lei, Z.B.; Shi, J. Y. J. Catal. 2009, 266 (2), 165. doi: 10.1016/j.jcat.2009.06.024
(5) Ying, H.; Wang, Z. Y.; Guo, Z. D.; Shi, Z. J.; Yang, S. F. Acta Phys. -Chim. Sin. 2011, 27 (6), 1482. [应红, 王志永,郭政铎,施祖进, 杨上峰.物理化学学报, 2011, 27 (6), 1482.] doi: 10.3866/PKU.WHXB20110630
(6) Stevens, R.; Woodfield, B. F.; Boerio-Goates, J.; Crawford, M.K. J. Chem. Thermodyn. 2004, 36 (5), 349. doi: 10.1016/j.jct.2003.12.010
(7) Pei, L. Z.; Yang, Y.; Yang, L. J.; Fan, G. G.; Yuan, C. Z.; Zhang,Q. F. Solid State Commun. 2011, 151 (14-15), 1036. doi: 10.1016/j.ssc.2011.04.017
(8) Liu, Z. S.; Jing, X. P.; Wang, L. X. J. Electrochem. Soc. 2007,154 (6), H500. doi: 10.1149/1.2720769
(9) Takeshita, S.; Honda, J.; Isobe, T.; Sawayama, T.; Niikura, S. Cryst. Growth Des. 2010, 10 (10), 4494. doi: 10.1021/cg100753g
(10) Yoon, K. H.; Kim, J. H. Thin Solid Films 2010, 519 (5), 1583.doi: 10.1016/j.tsf.2010.08.157
(11) Yan, C. Y.; Singh, N. D.; Lee, P. S. Appl. Phys. Lett. 2010, 96 (5), 053108. doi: 10.1063/1.3297905
(12) Ma, B. J.; Wen, F. Y.; Jiang, H. F.; Yang, J. H.; Ying, P. L.; Li, C. Catal. Lett. 2010, 134 (1-2), 78. doi: 10.1007/s10562-009-0220-8
(13) Yan, S. C.; Wan, L. J.; Li, Z. S.; Zou, Z. G. Chem. Commun.2011, 47 (19), 5632. doi: 10.1039/c1cc10513b
(14) Huang, J. H.; Ding, K. N.; Hou, Y. D.; Wang, X. C.; Fu, X. C.ChemSusChem 2008, 1 (12), 1011. doi: 10.1002/cssc.200800166
(15) Chi, J. H.; Wang, J. Acta Phys. -Chim. Sin. 2010, 26 (8), 2306.[池俊红,王娟.物理化学学报, 2010, 26 (8), 2306.] doi: 10.3866/PKU.WHXB20100820
(16) Li, X. N.; Bai, S. L.; Yang, W. S. Acta Phys. -Chim. Sin. 2012, 28 (7), 1797. [李晓宁, 白守礼, 杨文胜.物理化学学报, 2012, 28 (7), 1797.] doi: 10.3866/PKU.WHXB201205081
(17) Yan, C. Y.; Lee, P. S. J. Phys. Chem. C 2009, 114 (1), 265. doi: 10.1021/jp909068v
(18) Yan, C. Y.; Lee, P. S. J. Phys. Chem. C 2009, 113 (32), 14135.doi: 10.1021/jp9050879
(19) Tsai, M. Y.; Yu, C. Y.; Wang, C. C.; Perng, T. Y. J. Cryst. Growth Des. 2008, 8 (7), 2264. doi: 10.1021/cg700924j
(20) Liu, Q.; Zhou, Y.; Kou, J. H.; Chen, X. Y.; Tian, Z. P.; Gao, J.;Yan, S. C.; Zou, Z. G. J. Am. Chem. Soc. 2010, 132 (41), 14385.doi: 10.1021/ja1068596
(21) Yu, L.; Zou, R. J.; Zhang, Z. Y.; Song, G. S.; Chen, Z. G.; Yang,J. M.; Hu, J. Q. Chem. Commun. 2011, 47 (38), 10719. doi: 10.1039/c1cc14159g
(22) Mao, X. L.; Xu, D. X.; Fu, M. I.; Yuan, B. L.; Shi, J. W.; Cui, H.J. J. Chem. Eng. 2013, 218, 73. doi: 10.1016/j.cej.2012.12.031
(23) Nüchter, M.; Ondruschka, B.; Bonrath, W.; Gum, A. Green Chem. 2004, 6 (3), 128. doi: 10.1039/b310502d
(24) Zhang, L.; Cao, X. F.; Ma, Y. L.; Chen, X. T.; Xue, Z. L.CrystEngComm 2010, 12 (10), 3201. doi: 10.1039/b927170h
(25) Du, J.; Li, X. L.; Wang, S. J.; Wu, Y. Z.; Hao, X. P.; Xu, C. W.;Zhao, X. J. Mater. Chem. 2012, 22 (22), 11390. doi: 10.1039/c2jm30882g
(26) Mou, Q. Y.; Li, X. J. Physics 2004, 33 (6), 438. [牟群英, 李贤军. 物理, 2004, 33 (6), 438.] doi: 0379-4148.0.2004.06.013
(27) Xiao, H. J.; Xu, Y. X.; Ning, Q. J. J. Shaanxi Univ. Sci. Tech. (Nat. Sci. Ed.) 2009, 27 (4), 164. [肖昊江,徐依玺,宁青菊.陕西科技大学学报(自然科学版), 2009, 27 (4), 164.]
(28) Zhang, L.; Cao, X. F.; Chen, X. T.; Xue, Z. L. CrystEngComm2011, 13, 2464. doi: 10.1039/c0ce00872a
(29) Boppana, V. B. R.; Hould, N. D.; Lobo, R. F. J. Solid State Chem. 2011, 184 (5), 1054. doi: 10.1016/j.jssc.2011.02.022
(30) Daharma, J.; Pisal, A. Simple Method of Measuring the BandGap Energy Value of TiO2 in the Powder Formusing a UV/Vis/NIR Spectrometer. (accessed Jun 18, 2013).
(31) Liu, Z. Q.; Zhou, Y. P.; Ge, C. C. Rare. Metal. Mat. Eng. 2006,35 (Suppl. 2), 104. [刘中清, 周艳平,葛昌纯. 稀有金属材料与工程, 2006, 35 (Suppl. 2), 104.] doi: 1002-185x.0.2006-S2-026

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19. SUN Da-Li, PENG Sheng-Lin, OUYANG Jun, OUYANG Fang-Ping.Electronic Transport Properties of Graphene Nanoribbons with Nanoholes[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1103-1107
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