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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(09)>> 1998-2004     doi: 10.3866/PKU.WHXB201307031         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package
HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei
Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China
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We fabricated activated carbon (AC)-based supercapacitors encased in flexible packaging using a novel organic electrolyte, triethylmethylammonium tetrafluoroborate/acetonitrile+propylene carbonate (MeEt3NBF4/(AN+PC)), and two conventional organic electrolytes, tetraethylammonium tetrafluoroborate/acetonitrile (Et4NBF4/AN) and tetraethylammonium tetrafluoroborate/propylene carbonate (Et4NBF4/PC). Cyclic voltammetry and electrochemical impedance spectroscopy measurements in various voltage windows were conducted. In addition, a comprehensive comparison of these three electrolytes was conducted via data obtained from cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge-discharge, leakage current, self-discharge, cyclic life, and coulombic efficiency within the 0-3 V voltage window. The results indicate that MeEt3NBF4/(AN+PC) combining the advantages of AN and PC exhibits excellent performance.



Keywords: Supercapacitor   Organic electrolyte   Activated carbon  
Received: 2013-04-08 Accepted: 2013-07-03 Publication Date (Web): 2013-07-03
Corresponding Authors: MA Yan-Wei Email: ywma@mail.iee.ac.cn

Fund: The project was supported by the Knowledge Innovation Programof the Chinese Academy of Sciences (KJCX2-YW-W26), Science and Technology Project of Beijing, China (Z111100056011007), and National Natural Science Foundation of China (21001103, 51025726).

Cite this article: HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei. Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29 (09): 1998-2004.    doi: 10.3866/PKU.WHXB201307031

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