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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(10)>> 2101-2106     doi: 10.3866/PKU.WHXB201307153         中文摘要
THERMALANALYSIS KINETICS ANDTHERMOKINETICS
Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one
LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei
Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
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The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of ΔfHm0 (Li(NTO)·2H2O, aq, 298.15 K) and ΔfHm0 (Na(NTO)·2H2O, aq, 298.15 K) are obtained.



Keywords: Metal salts of 3-nitro-1,2,4-triazol-5-one   Formation reaction   Microcalorimeter   Thermokinetics  
Received: 2013-06-03 Accepted: 2013-07-15 Publication Date (Web): 2013-07-15
Corresponding Authors: ZHAO Feng-Qi Email: npecc@163.com

Fund: The project was supported by the National Natural Science Foundation of China (21173163) and Technology Foundation of Laboratory of Propellant and Explosive Combustion in China (9140C350307110C3506).

Cite this article: LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J]. Acta Phys. -Chim. Sin., 2013,29 (10): 2101-2106.    doi: 10.3866/PKU.WHXB201307153

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