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Acta Phys. -Chim. Sin.  2013, Vol. 29 Issue (10): 2101-2106    DOI: 10.3866/PKU.WHXB201307153
THERMALANALYSIS KINETICS ANDTHERMOKINETICS     
Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one
LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei
Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
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Abstract  

The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of ΔfHm0 (Li(NTO)·2H2O, aq, 298.15 K) and ΔfHm0 (Na(NTO)·2H2O, aq, 298.15 K) are obtained.



Key wordsMetal salts of 3-nitro-1,2,4-triazol-5-one      Formation reaction      Microcalorimeter      Thermokinetics     
Received: 03 June 2013      Published: 15 July 2013
MSC2000:  O643  
  O642  
Fund:  

The project was supported by the National Natural Science Foundation of China (21173163) and Technology Foundation of Laboratory of Propellant and Explosive Combustion in China (9140C350307110C3506).

Corresponding Authors: ZHAO Feng-Qi     E-mail: npecc@163.com
Cite this article:

LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one. Acta Phys. -Chim. Sin., 2013, 29(10): 2101-2106.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201307153     OR     http://www.whxb.pku.edu.cn/Y2013/V29/I10/2101

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