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Acta Phys. Chim. Sin.  2013, Vol. 29 Issue (11): 2295-2299    DOI: 10.3866/PKU.WHXB201309241
COMMUNICATION     
PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries
CHEN Qiang1,2, NULI Yan-Na1,2, GUOWei3, YANG Jun1,2, WANG Jiu-Lin1,2, GUO Yu-Guo3
1 School of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
3 Key Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
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Abstract  

We report the synthesis of a poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA)/graphene nanocomposite in which graphene is used as a support for improving electronic conductivity. The structure and morphology of the nanocomposite were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). These results reveal that a graphene surface is decorated by nanoparticles of PTMAwith an average size of 10 nm. The electrochemical performance of the PTMA/graphene composite as a cathode material in rechargeable magnesium batteries was investigated using cyclic voltammetry and galvanostatic charge/discharge techniques. In a "first generation" electrolyte Mg(AlCl2BuEt)2/tetrahydrofuran (THF) (0.25 mol·L-1), the material exhibits an initial discharge capacity of 81.2 mAh·g-1 at 22.8 mA·g-1. Further studies will focus on improving the capacity using electrolytes with a wider electrochemical window.



Key wordsEnergy storage and conversion      Rechargeable magnesium battery      Nanocomposite      Organic cathode material      Graphene     
Received: 26 June 2013      Published: 24 September 2013
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (21273147) and Shanghai Municipal Science and Technology Commission, China (11JC1405700).

Corresponding Authors: NULI Yan-Na, GUO Yu-Guo     E-mail: nlyn@sjtu.edu.cn;ygguo@iccas.ac.cn
Cite this article:

CHEN Qiang, NULI Yan-Na, GUOWei, YANG Jun, WANG Jiu-Lin, GUO Yu-Guo. PTMA/Graphene as a Novel Cathode Material for Rechargeable Magnesium Batteries. Acta Phys. Chim. Sin., 2013, 29(11): 2295-2299.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201309241     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2013/V29/I11/2295

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