ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2013,Vol.29>> Issue(12)>> 2498-2504     doi: 10.3866/PKU.WHXB201310212         中文摘要
Preparation and Characterization of Superthermite Al/Fe2O3 and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine
ZHAO Ning-Ning1, HE Cui-Cui1, LIU Jian-Bing1, MA Hai-Xia1, AN Ting2, ZHAO Feng-Qi2, HU Rong-Zu2
1 School of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2 Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
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Hollow Fe2O3 nanorods were prepared using a hydrothermal method, and were then combined with Al nanoparticles to form superthermite Al/Fe2O3 by ultrasonic mixing. Fe2O3 and Al/Fe2O3 were characterized using X-ray powder diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS). The effects of Al/Fe2O3, Al, and nano-Fe2O3 powders on the thermal decomposition of cyclotrimethylene trinitramine (RDX) were investigated using differential scanning calorimetry (DSC). The results show that the superthermite Al/Fe2O3 affects the thermal decomposition of RDX and greatly enhances its secondary gas-phase reaction. The shapes of the main RDX decomposition peaks changed with increasing superthermite content. The main influences of superthermite Al/Fe2O3, Al nanopowders, and Fe2O3 nanorods on the thermal decomposition of RDX are that the secondary decomposition peaks become distinct and the peak temperature decreases.

Keywords: Nano-Fe2O3   Superthermite Al/Fe2O3   Cyclotrimethylene trinitramine   Hydrothermal method   Ultrasonically dispersed method   Thermal decomposition  
Received: 2013-06-12 Accepted: 2013-10-18 Publication Date (Web): 2013-10-21
Corresponding Authors: MA Hai-Xia Email:

Fund: The project was supported by the National Natural Science Foundation of China (21073141, 21373161), Program for New Century Excellent Talents in University of Ministry of Education of China (12-1047), Research Fund for the Doctoral Program of Higher Education of China (20126101110009), Science and Technology Foundation of Science and Technology on Combustion and Explosion Laboratory, China (9140C3501041001).

Cite this article: ZHAO Ning-Ning, HE Cui-Cui, LIU Jian-Bing, MA Hai-Xia, AN Ting, ZHAO Feng-Qi, HU Rong-Zu. Preparation and Characterization of Superthermite Al/Fe2O3 and Its Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Acta Phys. -Chim. Sin., 2013,29 (12): 2498-2504.    doi: 10.3866/PKU.WHXB201310212

(1) Valliappan, S.; Swiatkiewicz, J.; Puszynski, J. A. Powder Technol. 2005, 156, 164. doi: 10.1016/j.powtec.2005.04.027
(2) Dreizin, E. L. Prog. Energ. Combust. 2009, 35, 141. doi: 10.1016/j.pecs.2008.09.001
(3) An, T.; Zhao, F. Q.; Xiao, L. B. Chin. J. Expls. Propell. 2010, 33 (3), 55. [安亭, 赵凤起, 肖立柏. 火炸药学报, 2010, 33 (3),55.]
(4) Siegert, B.; Comet, M.; Muller, O.; Pourroy, G.; Spitzer, D. J. Phys. Chem. C 2010, 114, 19562. doi: 10.1021/jp1014737
(5) Pamela, J.; Kaste, B. The Amptiac Newsletter 2004, 8 (4), 85.
(6) Miziolek, A.W. Oxford: Oxford University Press, 2003; pp 1-5.
(7) Miziolek, A.W. The Amptica Newsletter 2002, 6 (1), 43.
(8) Zhou, L.; Piekiel, N.; Chowdhury, S.; Zachariah, M. R. J. Phys. Chem. C 2010, 114 (33), 14269. doi: 10.1021/jp101146a
(9) Park, C. D.; Mileham, M.; van de Burgt, L. J.; Muller, E. A.;Stiegman, A. E. J. Phys. Chem. C 2010, 114 (6), 2814. doi: 10.1021/jp910274w
(10) Wang, Y.; Li, F. S.; Jiang,W.; Zhang, X. F.; Guo, X. D.Initiators & Pyrotechnics 2008, 4, 11. [王毅, 李凤生, 姜炜, 张先锋, 郭效德. 火工品, 2008, 4, 11.]
(11) An, T.; Zhao, F. Q.; Pei, Q.; Xiao, L. B.; Xu, S. Y.; Gao, H. X.;Xing, X. L. Chin. J. Inorg. Chem. 2011, 27 (2), 231. [安亭,赵凤起, 裴庆, 肖立柏, 徐司雨, 高红旭, 邢晓玲. 无机化学学报, 2011, 27 (2), 231.]
(12) Alexandre, M.; Dubois, P. Mater. Sci. Eng. 2000, 28 (1), 1.
(13) Cheng, J. L.; Hng, H. H.; Ng, H. Y.; Soon, P. C.; Lee, Y.W.J. Phys. Chem. Solids 2010, 71 (2), 90. doi: 10.1016/j.jpcs.2009.08.017
(14) Tillotson, T. M.; Gash, A. E.; Simpson, R. L.; Hrubesh, L.W.;Satcher, J. H.; Poco, J. F. J. Non-Cryst. Solids 2001, 285 (1-3),338. doi: 10.1016/S0022-3093(01)00477-X
(15) Stiegman, A. E.; Park, C. D.; Mileham, M.; van de Burgt, L. J.;Kramer, M. P. Propell. Explos. Pyrot. 2009, 34 (4), 293. doi: 10.1002/prep.v34:4
(16) Wang, R. H.; Zhang, J. L.;Wang, J. Y.; Pan, J. J.; Zhang, J.Energy Mater. 2011, 19 (6), 739. [王瑞浩, 张景林, 王金英,潘军杰, 张俊.含能材料, 2011, 19 (6), 739.]
(17) Liu, Z. R.; Liu, Y.; Fan, X. P.; Zhao, F. Q.; Yin, C. P. Chin. J. Expls. Propell. 2004, 27 (2), 63. [刘子如, 刘艳, 范夕萍,赵凤起, 阴翠梅. 火炸药学报, 2004, 27 (2), 63.]
(18) Jin, L. N.; Liu, Q.; Sun,W. Y. CrystEngComm 2012, 14 (22),7721.
(19) Vargeese, A. A.; Muralidharan, K. Mater. Chem. Phys. 2013,139 (2-3), 537. doi: 10.1016/j.matchemphys.2013.01.054
(20) Spitzer, D.; Comet, M.; Baras, C.; Pichot, V.; Piazzon, N.J. Phys. Chem. Solids 2010, 71 (2), 100. doi: 10.1016/j.jpcs.2009.09.010
(21) Hong,W. L.; Liu, J. H.; Chen, P.; Tian, D. Y.; Zhao, F. Q. J. Propul. Techn. 2001, 22 (3), 254. [洪伟良, 刘剑洪, 陈沛,田德余, 赵凤起. 推进技术, 2001, 22 (3), 254.]
(22) Apte, S. K.; Naik, S. D.; Sonawane, R. S.; Kalew, B. B. J. Am. Ceram. Soc. 2007, 90 (2), 412. doi: 10.1111/jace.2007.90.issue-2
(23) Jing, Z. H.;Wang, Y.;Wu, S. H. Chin. J. Inorg. Chem. 2005, 21 (1), 145. [景志红, 王燕, 吴世华. 无机化学学报, 2005, 21 (1), 145.]
(24) Wei, Z. X.;Wei, L.; Gong, L.;Wang, Y.; Hu, C.W. J. Hazard. Mater. 2010, 177 (1-3), 554. doi: 10.1016/j.jhazmat.2009.12.068
(25) Long, G. T.; Vyazovkin, S.; Brems, B. A.;Wight, C. A. J. Phys. Chem. B 2000, 104 (11), 2570. doi: 10.1021/jp993334n
(26) An, T.; Cao, H. Q.; Zhao, F. Q.; Ren, X. N.; Tian, D. Y.; Xu, S.Y.; Gao, H. X.; Tan, Y.; Xiao, L. B. Acta Phys. -Chim. Sin. 2012,28 (9), 2202. [安亭, 曹慧群, 赵凤起, 任晓宁, 田德余, 徐司雨, 高红旭, 谭艺, 肖立柏. 物理化学学报, 2012, 28 (9),2202.] doi: 10.3866/PKU.WHXB201206292
(27) Zhu, Y. L.; Huang, H.; Ren, H.; Jiao, Q. J. J. Energ. Mater.2013, 31 (3), 178. doi: 10.1080/07370652.2012.688788
(28) Yang, Y.; Xu, J. H.; Luo, F. S.; Han, A. J.; Li, F. S. Chin. J. Expls. Propell. 2002, 25 (1), 29. [杨毅, 徐建华, 罗付生, 韩爱军, 李凤生. 火炸药学报, 2002, 25 (1), 29.]
(29) Yao, L. N.; Feng, X. S.; Zhao, S. X.;Wang, C. L.;Wang, S. P.Chin. J. Expls. Propell. 2012, 35 (4), 15. [姚李娜, 封雪松, 赵省向, 王彩玲, 王淑萍. 火炸药学报, 2012, 35 (4), 15.]
(30) Zhao,W. Z.; Zheng, H. Y.; Lin, B. L. Chin. J. Expls. Propell.2008, 31 (5), 69. [赵文忠, 郑邯勇, 林碧亮. 火炸药学报,2008, 31 (5), 69.]

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61. WANG Run-Han, JIANG Ji-Sen, HU Ming.Controlled Syntheses of FeNi3 Alloy Nanostructures via Reverse Microemulsion-Directed Hydrothermal Motheds[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2167-2172
62. DONG Xiang, TAO Jie, LI Ying-Ying, WANG Tao, ZHU Hong.Photoelectrochemical Properties of Three-Dimensional Network TiO2 Nanowire Film Prepared by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1874-1882
63. SUN Zhi-Quan, LU Hai-Yan, REN Xiu-Bin, HUANG Wei-Min, DONG Yan-Jie, LIN Hai-Bo.Performances of Ti/SnO2-Sb2O5 Anodes Prepared by Brush Coating Thermal Decomposition Method[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1385-1390
64. LV Yong, LU Wen-Cong, ZHANG Liang-Miao, YUE Bao-Hua, SHANG Xing-Fu, NI Ji-Peng.Synthesis, Characterization and Growth Mechanism of Core/Shell AlOOH Microspheres[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1391-1396
65. ZHANG Qiang, QIAO Xiao-Jing, ZHANG Jian-Guo, ZUO Xiao-Li.Flash Pyrolysis of Trinitrophloroglucinol Metallic (Li, Na, K, Mg) Compounds[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1081-1087
66. DONG Lin-Mao, LI Xiao-Dong, YANG Rong-Jie.Thermal Decomposition of Hexanitrohexaazaisowurtzitane and Its Residues[J]. Acta Phys. -Chim. Sin., 2009,25(05): 981-986
67. CHEN Qi-Feng, JIANG Dong, XU Yao, WU Dong, SUN Yu-Han.Visible Region Photocatalysis of Ce-Si/TiO2 Synthesized Using Sol-Gel-Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(04): 617-623
68. ZHAO Rui-Hua, DONG Mei, QIN Zhang-Feng, DING Jian-Fei, GUO Xing-Cui, WANG Jian-Guo.Synthesis and Characterization of CoAPO-5 with different Cobalt Contents and Their Catalytic Performance for Cyclohexane Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2304-2308
69. ZHANG Heng, ZHAO Feng-Qi, YI Jian-Hua, ZHANG Xiao-Hong, HU Rong-Zu, XU Si-Yu, REN Xiao-Ning.Preparation, Thermal Behavior and Non-isothermal Decomposition Reaction Kinetics of Zr(3-NO2-PHT)2·2H2O[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2263-2267
70. XU Peng, SONG Le-Xin.Thermal Decomposition Kinetics of Survived β-Cyclodextrin from an Inclusion Complex of β-Cyclodextrin with Clove Oil[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2214-2220
71. LI Hai-Long; LUO Wu-Lin; CHEN Tao; TIAN Wen-Yu; SUN Mao; LI Chun; ZHU Di; LIU Ran-Ran; ZHAO Yu-Liang; LIU Chun-Li.Preparation and Photocatalytic Performance of Titania Nanotubes Loaded with Ag Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1383-1386
72. WANG Bai-Qi; XIA Chun-Hui; FU Qiang; WANG Peng-Wei; SHAN Xu-Dong; YU Da-Peng.Hydrothermal Preparation and Photoluminescence Property of Co-Doped ZnO Nanorods[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1165-1168
73. DONG Lin-Mao; LI Xiao-Dong; YANG Rong-Jie.Thermal Decomposition Kinetics of Hexanitrohexaazaisowurtzitane by Mass Spectrometry[J]. Acta Phys. -Chim. Sin., 2008,24(06): 997-1001
74. MA Wei; WANG Su; CUI Ji-Ping; ZHANG Sheng-Tao; FAN Bing-Cheng; HE Yu-Zhong.Thermal Decomposition Kinetic Model of Phenolic Resin[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1090-1094
75. ZHANG Jin; ZHANG Tong-Lai; YANG Li; ZHANG Jian-Guo; CUI Yan.Preparation, Crystal Structure and Thermal Decomposition Character of [Ni(CHZ)3]SO4·3H2O[J]. Acta Phys. -Chim. Sin., 2008,24(05): 760-766
76. HU Xiao-Chun; ZHANG Tong-Lai; QIAO Xiao-Jing; YANG Li; ZHANG Jian-Guo; CUI Yan; ZHANG Jin.Crystal Structure and Thermal Decomposition of 5-Aminotetrazole Trinitrophloroglucinolate[J]. Acta Phys. -Chim. Sin., 2008,24(04): 576-580
77. XU Peng; SONG Le-Xin.Analysis of Thermal Decomposition Behavior Diversity of Host in a Supermolecule——Thermal Decomposition of Survived Cyclodextrin[J]. Acta Phys. -Chim. Sin., 2008,24(04): 729-736
78. CAO Ji-Lin; XING Dong-Qiang; LIU Xiu-Wu; TAN Zhao-Yang.Synthesis of Magnetic 4A Zeolite at Ultrasonic Condition[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1893-1898
79. ZHANG Bao-Li; XING Yong-Heng; GE Mao-Fa; SUN Zheng; LI Zhang-Peng; HAN Jing; NIU Shu-Yun.Synthesis, Structure and Non-thermal Decomposition Kinetics of Scorpionates Oxovanadium Complexes with Carboxyl Acid Ligand[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1701-1706
80. LI Ai-Ling; XIONG Jin-Ping; ZUO Yu. WANG Cheng-Zhong.Thermal Decomposition Kinetics of Polyurethane Adhesive[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1622-1626
81. WANG Shao-Xu; ZHAO Zhe; TAN Zhi-Cheng; LI Yan-Sheng; TONG Bo; SHI Quan; LI Ying.Thermal Stability and Kinetics of Thermal Decomposition for Protionamide[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1459-1462
82. ZHANG Yu-Dong; LI Bin-Jie; XU Xiang-Min; LI De-Liang.Thermal Decomposition Kinetics of ZnSn(OH)6[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1095-1098
83. TANG Yan-Jun; LI You-Ming; SONG Jing; PAN Zhi-Dong.Structural Characterization and Thermal Decomposition Behavior of Microsized and Nanosized CaCO3[J]. Acta Phys. -Chim. Sin., 2007,23(05): 717-722
84. TANG Wan-Jun; CHEN Dong-Hua.Thermal Decomposition Kinetics of Ferrous Oxalate Dihydrate[J]. Acta Phys. -Chim. Sin., 2007,23(04): 605-608
85. YIN Li-Song;CHEN Min-Tao;LI Ting;ZHOU Ke-Sheng;GAO Song-Hua.Preparation of Rhombic MgO Nanoflakes from Dolomites[J]. Acta Phys. -Chim. Sin., 2007,23(03): 433-437
86. SONG Xu-Chun;ZHENG Yi-Fan;LIN Shen;WANG Yun.A Simple Method to Synthesize α-MnO2 and β-MnO2 Single-crystalline Nanorods[J]. Acta Phys. -Chim. Sin., 2007,23(02): 258-261
87. FANG Li-Mei;LI Zhi-Jie;LIU Chun-Ming;ZU Xiao-Tao.Synthesis of Fe3+-modified SnO2 Nanoparticles by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1212-1216
88. GUO Jin-Yu;ZHANG Jian-Guo;ZHANG Tong-Lai;WU Rui-Feng;YU Wei.Thermal Decomposition Mechanisms of a Three-dimensional Framework Coordination Polymer [Cu(HCOO)2(H2O)2][J]. Acta Phys. -Chim. Sin., 2006,22(10): 1206-1211
89. WU Xin-Min;LIU Jian-Hua;LI Wei;QI Chuan-Song .Thermal Decomposition Kinetics of Complexes of Rare Earths (RE = Nd, Sm) with Amino Acid RE(Val)Cl3•6H2O[J]. Acta Phys. -Chim. Sin., 2006,22(08): 942-946
90. HU Ji-Ming;HOU Yan-Yuan;WANG Xiao-Mei;ZHANG Jian-Qing;CAO Chun-Nan .Effect of Calcination Procedure on the Electrocatalytic Activities of Ti/IrO2 Electrodes in Acidic Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1010-1014
91. SUN Yuan-Hua;ZHANG Tong-Lai;ZHANG Jian-Guo;YANG Li;QIAO Xiao-Jing.Kinetics of Flash Pyrolysis of [Co(CHZ3](ClO42 and [Ni(CHZ)3](ClO4)2[J]. Acta Phys. -Chim. Sin., 2006,22(06): 649-652
92. HAO Yan-Zhong; HAN Wen-Tao.Preparation and Photoelectrochemical Properties of Titanate Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(02): 221-225
93. SONG Xu-chun; ZHENG Yi-fan; YIN Hao-yong; CAO Guang-sheng.Synthesis and Characterization of Transition Element Substituted Titanate Nanotubes[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1076-1080
94. YUE Lin-hai; JIN Da-lai; LU De-yi; XU Zhu-de.The Non-isothermal Kinetic Analysis of Thermal Decomposition of Mg(OH)2[J]. Acta Phys. -Chim. Sin., 2005,21(07): 752-757
95. QIAN Xin-Ming;LIU Li;FENG Chang-Gen.Calculating Apparent Activation Energy of Adiabatic Decomposition Process Using Pressure Data[J]. Acta Phys. -Chim. Sin., 2005,21(02): 134-138
96. LIU Chang-Jian;ZHANG Yi.Thermal Decomposition of NaNH4CrO4•2H2O[J]. Acta Phys. -Chim. Sin., 2005,21(02): 218-220
97. Cai Wei-Quan;Li Hui-Quan;Zhang Yi.Hydrothrmal Crystal Growth of Very Light Boehmite products[J]. Acta Phys. -Chim. Sin., 2004,20(07): 717-721
98. Yu Xue-Chun;Peng Hai-Lin;Zhang Ran;Zhang Ying-Ying;Liu Zhong-Fan.Influence of Decomposition Temperature on the Threshold Voltage for a Series of Charge Transfer Complexes[J]. Acta Phys. -Chim. Sin., 2004,20(06): 565-568
99. Guo Min;Diao Peng;Ren Yan-Jie;Wang Bin;Cai Sheng-Min.Preparation and Characterization of Highly Oriented ZnO Single Crystal Submicrorod Arrays[J]. Acta Phys. -Chim. Sin., 2003,19(05): 478-480
100. Cheng Hu-Min;Ma Yu-Rong;Liao Fu-Hui;Ma Ji-Ming;Qi Li-Min.Synthesis of Mesoporous Zirconia with Hydrothermal Homogeneous Precipitation Method[J]. Acta Phys. -Chim. Sin., 2003,19(04): 326-328
101. He Shui-Yang;Cao Wen-Kai;Hu Ting;Zhao Jian-She;Zhang Wei-Ping;Xue Gang-Lin;Hu Rong-Zu.Synthesis, Characterization and Thermochemical Properties of La(III) with Salicylaldehyde-1H- benzotriazol-1-aceylhydrazone[J]. Acta Phys. -Chim. Sin., 2002,18(10): 865-870
102. Zhai Shang-Ru;Pu Min;Gong Yan-Jun;Zhang Ye;Wu Dong;Sun Yu-Han.The Synthesis of Mesoporous Molecular Sieve MCM-48 Using Two Surfactants as Co-template[J]. Acta Phys. -Chim. Sin., 2002,18(10): 911-915
103. Liu Bei-Ping;Tan Zhi-Cheng;Nan Zhao-Dong;Liu Ping;Sun Li-Xian;Xu Fen.Calorimetric Study and Thermal Analysis of [Ho2(Ala)4(H2O)8]Cl6 and >;[ErY(Ala)4(H2O)8](ClO4)6[J]. Acta Phys. -Chim. Sin., 2002,18(06): 481-485
104. Gao Gai-Ling;Fang Yu;Wang Ming-Zhen;Hu Dao-Dao.Properties of Y2O3:Eu Nanocrystals Prepared by Thermodecomposition of Benzoic Acid[J]. Acta Phys. -Chim. Sin., 2002,18(05): 399-413
105. Gao En-Qin;Zhang Li;Yang Mai-Zhi;Cai Sheng-Min.Preparation of TiO2 Nanoparticles by Hydrothermal Method and its Application for Photoelectrochemical Cell[J]. Acta Phys. -Chim. Sin., 2001,17(02): 177-180
106. Qian xin-Ming;Wang Yun;Feng Chang-Gen;Zheng Rao.Investigation of Thermal Decomposition of KClO3/CuO/S/Mg-Al/C6Cl6 System by Accelerating Rate Calorimeter[J]. Acta Phys. -Chim. Sin., 2001,17(01): 70-73
107. Zhang Jian-Guo, Zhang Tong-Lai.Synthesis,Structural Characterization and Thermal Decomposition Mechanism of {[Ag(ATO)2]ClO4}n[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1110-1114
108. Liu Shi-Jun, Chen Qi-Yuan, Zhang Ping-Min.Thermal Decomposition of Monoclinic Ammonium Paratungstate[J]. Acta Phys. -Chim. Sin., 2000,16(11): 1048-1052
109. Lv Chun-Hua, Zhang Tong-Lai, Qiao Xiao-Jing, Cai Rui-Jiao, Yu Kai-Bei.Structure and Thermal Decomposition Mecharism of [Pb2(TNR)2(CHZ)2(H2O)2]4H2O[J]. Acta Phys. -Chim. Sin., 2000,16(05): 441-446
110. Jiang De-En, Zhao Bi-Ying, Xie You-Chang.Thermal Decomposition Behavior of Mg(NO3)2 on γ-Al2O3 and Basicity of MgO/γ-Al2O3[J]. Acta Phys. -Chim. Sin., 2000,16(02): 105-110
111. Chen Jie-Hao, Wang Yan, Feng Wen-Lin.Mechanism of Pyrolysis of Pyruvic Acid and Benzoylformic Acid and Calculations of Thermal Rate Constants[J]. Acta Phys. -Chim. Sin., 1999,15(05): 431-435
112. Hong San-Guo, Peng Yi-Yuan, Zhu Shi-Lai, Wang Shen.Theoretical Study on the Thermolyses of ο-acetylcyclopentanone and ο-acetylcyclohexanone[J]. Acta Phys. -Chim. Sin., 1999,15(02): 186-189
113. Liu Shi-Jun, Chen Qi-Yuan, Zhang Ping-Min, Liu Min-Na.Study on Thermal Decomposition of Sodium Paratungstate Na10H2W12O42·27H2O[J]. Acta Phys. -Chim. Sin., 1998,14(09): 821-825
114. Xu Wen-Yuan, Liu Gou-Sheng, Peng Yi-Yuan, Hong San-Guo.AM1 Method Study of Thermolyses of Formacyl and Benzoyl Azides[J]. Acta Phys. -Chim. Sin., 1998,14(07): 669-672
115. Luo Jin, Su Lian-Yong, Xie Lei, Zhou Jing, Zu Yan-Bing, Lin Zhong-Hua.Studies on Photoelectrochemical Behaviors of Nanocrystalline TiO2 Films[J]. Acta Phys. -Chim. Sin., 1998,14(04): 315-319
116. Tian Sheng-Jun,Cheng Qing-Tang,Xi Guo-Xi,Lou Xiang-Dong,Li Jing-Hua.Preparation of Inclusion Complex of Benzyl Acetate with β-Cyclodextrin and Studies on its Thermal Dissociation[J]. Acta Phys. -Chim. Sin., 1997,13(05): 459-465
117. Wang Ya-Juan,Qi Xue-Yong,Li Xiao-Yan.Studies on the Non-isothermal Kinetics of Thermal Decomposition of Benzimidazolyl-bontaining Dicopper(I) Complexes[J]. Acta Phys. -Chim. Sin., 1996,12(07): 668-672
118. Yin Zhou-Lan.Study on the Kinetics of the Thermal Decomposition of Ammonium Molybdates[J]. Acta Phys. -Chim. Sin., 1996,12(02): 181-184
119. Deng Hong-Mei,Sun Yao-Jun,Wang Li-Ping,Wu Tai-Liu,Ma Li-Dun,Fei Lun.Silicon Clusters Synthesized by the Thermal Decomposition of Silicane[J]. Acta Phys. -Chim. Sin., 1995,11(05): 468-469
120. Hong San-Guo.Quantum Chemical Study of the Thermolysis of Chroman[J]. Acta Phys. -Chim. Sin., 1995,11(04): 297-301
121. Pang Xian-Jie, Zhong Bang-Ke.Studies on XRD and Thermal Decomposition of Tris [Tetrammine-μ-dihydroxo-cobaltium(III)] Cobaltium(III) Sulfate Ennea-Hydrate[J]. Acta Phys. -Chim. Sin., 1995,11(03): 262-265
122. Hong San-Guo, Wang Shen.Study of the Thermolysis of RC(X)OC(O)CH3 Using MIVDO/3[J]. Acta Phys. -Chim. Sin., 1994,10(09): 779-784
123. Hong San-Guo, Wang Shen.The Theoretical Study of the Thermolysis of Acetylacetone[J]. Acta Phys. -Chim. Sin., 1994,10(05): 424-427
124. Wang Han-Zhang; Zhang De-Cheng; Guo Song-Shan; Bao Han-Bing; Yang Li; Lu Zhen-Rong.The Kinetics on Thermal Decomposition Reaction of Palladium Complexes with Thioether p-CH3C6H4SR[J]. Acta Phys. -Chim. Sin., 1993,9(01): 103-106
125. JIN Cheng-Wei, WANG Ye, XU Su-Ling, ZHANG Jian-Jun.Synthesis, Crystal Structures and Thermochemical Properties of Ternary Rare Earth Complexes Based on 3,4-Diethoxybenzoic Acid and 2,2'-Bipyridine[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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