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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(1)>> 129-134     doi: 10.3866/PKU.WHXB201311201         中文摘要
CATALYSIS AND SURFACE SCIENCE
Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al):an Active Catalyst for CO Oxidation
LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China
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Pd nanoparticles (NPs) supported on a metal-organic framework (MOF), MIL-53(Al) (MIL: Materials of Institut Lavoisier), were prepared using the incipient wetness impregnation method. The structures of the synthesized Pd/MIL-53(Al) catalysts were determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The same peaks were observed in the XRD patterns of Pd/MIL-53(Al) before and after the catalytic reaction, confirming that the integrity of the MIL-53(Al) support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53(Al) favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The heterogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53(Al) were stable after several reaction runs.



Keywords: Metal-organic framework   MIL-53(Al)   Palladium nanoparticle   Heterogeneous catalysis   CO oxidation  
Received: 2013-08-26 Accepted: 2013-11-20 Publication Date (Web): 2013-11-20
Corresponding Authors: ZHAO Zhen, LIU Jian Email: zhenzhao@cup.edu.cn;liujian@cup.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (21073235, 21173270, 21177160) and National High-Tech Research and Development Program of China (863) (2013AA061902).

Cite this article: LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al):an Active Catalyst for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30 (1): 129-134.    doi: 10.3866/PKU.WHXB201311201

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