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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (2): 305-310    DOI: 10.3866/PKU.WHXB201312022
ELECTROCHEMISTRY AND NEW ENERGY     
Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials
WANG Jian-Tao, WANG Yao, HUANG Bin, YANG Juan-Yu, TAN Ao, LU Shi-Gang
R&D Center for Vehicle Battery and Energy Storage, General Research Institute for Nonferrous Metals, Beijing 100088, P. R. China
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Abstract  

A Si/SiOC/graphite composite structure with high efficiency and long-term cycling stability was synthesized using a cost- effective method. In this structure, a SiOC network with good chemical stability acts as a skeleton to support and segregate Si nanostructures. The graphite incorporated in the Si/SiOC composite is used as a conductive material to enhance the electrical conductivity. Such Si/SiOC/graphite composite anodes show excellent cycling stability, with a specific capacity of ~637.3 mAh·g-1 and ~86% capacity retention over 100 cycles at a rate of 0.3C. The design of this new structure has the potential to provide a basis for the development of other functional composite materials.



Key wordsSi/SiOC/graphite      Composite material      Lithium-ion battery      Anode      Long-term cycling     
Received: 24 October 2013      Published: 02 December 2013
MSC2000:  O646  
Fund:  

The project was supported by the National High Technology Research and Development Program of China (863) (2011AA11A256, 2013AA050903, 2013AA050906).

Corresponding Authors: LU Shi-Gang     E-mail: slu@grinm.com
Cite this article:

WANG Jian-Tao, WANG Yao, HUANG Bin, YANG Juan-Yu, TAN Ao, LU Shi-Gang. Silicon Supported on Stable Si-O-C Skeleton in High-Performance Lithium-Ion Battery Anode Materials. Acta Phys. Chim. Sin., 2014, 30(2): 305-310.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201312022     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I2/305

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