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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(2)>> 382-388     doi: 10.3866/PKU.WHXB201312032         中文摘要
PHYSICAL CHEMISTRY OF MATERIALS
Morphology-Controlled Synthesis of Co3O4 Nanocubes and Their Catalytic Performance in CO Oxidation
LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China
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Co3O4 nanocubes that were exclusively terminated with {100} facets of edge size 10 nm were solvothermally fabricated in a mixed solution of ethanol and triethylamine. Analyses of the structural evolution of the intermediates at different intervals during the synthesis, together with an examination of the influences of the cobalt precursor and solvent on the product structure, showed that the formation of Co3O4 nanocubes followed a dissolution-recrystallization mechanism. After calcination at 200 ℃, the as-synthesized Co3O4 material retained a cubic morphology with the same edge size, but calcination at 400 ℃ resulted in the formation of spherical Co3O4 particles of diameter about 13 nm. The Co3O4 nanocubes exhibited inferior activity in room-temperature CO oxidation compared with Co3O4 nanoparticles ({111} facets), primarily as a result of the exposure of the less- reactive {100} facets, demonstrating the morphology effect of Co3O4 nanomaterials.



Keywords: Co3O4   Solvothermal synthesis   Morphology-dependence   Nanocube   CO oxidation  
Received: 2013-10-14 Accepted: 2013-12-02 Publication Date (Web): 2013-12-03
Corresponding Authors: SHEN Wen-Jie Email: shen98@dicp.ac.cn

Fund: The project was supported by the National Natural Science Foundation of China (20923001, 21025312).

Cite this article: LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie. Morphology-Controlled Synthesis of Co3O4 Nanocubes and Their Catalytic Performance in CO Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30 (2): 382-388.    doi: 10.3866/PKU.WHXB201312032

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