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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (3): 535-543    DOI: 10.3866/PKU.WHXB201401032
CATALYSIS AND SURFACE SCIENCE     
Methanol to Propylene over Nanosheets of HZSM-5 Zeolite
ZHANG Shao-Long, ZHANG Lan-Lan, WANG Wu-Gang, MIN Yuan-Yuan, MATong, SONG Yu, GONG Yan-Jun, DOU Tao
State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry Engineering, China University of Petroleum-Beijing, Beijing 102249, P. R. China
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Abstract  

Nanosheets of HZSM-5 zeolite with different SiO2/Al2O3 molar ratios were synthesized, and their catalytic behavior in the methanol-to-propylene (MTP) reaction was evaluated in a fixed bed reactor. The effect of reaction conditions on catalytic performance was studied in detail. The catalytic performance of nanosheets of HZSM-5 zeolites in the MTP reaction was compared with that of the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite had higher propylene selectivity, total three olefins' selectivity (ethylene, propylene, C4 alkenes) , and a longer catalytic lifetime than the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite with a SiO2/Al2O3 molar ratio of 213 yielded a propylene selectivity of 46.7%, total three olefins' selectivity of 78.7% at 470 ℃, and a methanol weight hourly space velocity (WHSV) of 3 h-1. It also yielded a propylene/ethylene mass ratio of 6.5, which was double that of the nanosized HZSM-5 zeolite. The nanosheets of HZSM-5 zeolite had a lower aromatic selectivity than the nanosized HZSM-5 zeolite. The good MTP catalytic performance of the nanosheets of HZSM-5 zeolite was attributed to their wide (010) surface, high external surface area, and large mesoporous volume.



Key wordsNanosheet      HZSM-5 zeolite      Methanol      Propylene     
Received: 29 November 2013      Published: 03 January 2014
MSC2000:  O643  
Fund:  

The project was supported by the National Key Basic Research Program of China (973) (2012CB215002), National Natural Science Foundation of China (21276278, 21176255), and China National Petroleum Corporation (CNPC) Program (2011A-2101).

Corresponding Authors: GONG Yan-Jun     E-mail: gongyj@cup.edu.cn
Cite this article:

ZHANG Shao-Long, ZHANG Lan-Lan, WANG Wu-Gang, MIN Yuan-Yuan, MATong, SONG Yu, GONG Yan-Jun, DOU Tao. Methanol to Propylene over Nanosheets of HZSM-5 Zeolite. Acta Phys. Chim. Sin., 2014, 30(3): 535-543.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201401032     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I3/535

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