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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (3): 476-484    DOI: 10.3866/PKU.WHXB201401071
ELECTROCHEMISTRY AND NEW ENERGY     
Synthesis and Electrochemical Lithium Storage Performance of WO3 Nanorods/Graphene Nanocomposites
ZHANG Qing-Qing, LI Rong, ZHANG Meng-Meng, GOU Xing-Long
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637000, Sichuan Province, P. R. China
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Abstract  

WO3 nanorods/graphene nanocomposites (WO3/RGO) were prepared by the solvothermal treatment of tungsten hexachloride and graphene oxide in alcohol. The electrochemical performance of WO3/RGO as anode materials for lithium-ion batteries was investigated by galvanostatic charge-discharge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The discharge capacity of the composite at the first cycle was 761.4 mAh·g-1, and about 635 mAh·g-1 of reversible capacity remained after 100 cycles at a rate of 0.1C (1C=638 mA·g-1). The corresponding retention rate was 83.4%. The reversible capacity remained lager than 460 mAh·g-1 at a rate of 5C. WO3/RGO exhibited excellent cycling stability and rate performance, and has potential in advanced lithium-ion batteries.



Key wordsTungsten trioxide      Graphene      Nanocomposite      Lithium-ion battery      Anode material     
Received: 06 August 2013      Published: 07 January 2014
MSC2000:  O646  
Fund:  

The project was supported by the Natural Science Foundation of China (51071131) and Program for New Century Excellent Talents in University (NCET-10-0890).

Corresponding Authors: GOU Xing-Long     E-mail: gouxlr@126.com
Cite this article:

ZHANG Qing-Qing, LI Rong, ZHANG Meng-Meng, GOU Xing-Long. Synthesis and Electrochemical Lithium Storage Performance of WO3 Nanorods/Graphene Nanocomposites. Acta Phys. Chim. Sin., 2014, 30(3): 476-484.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201401071     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I3/476

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