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Acta Phys. Chim. Sin.  2014, Vol. 30 Issue (4): 789-796    DOI: 10.3866/PKU.WHXB201402123
PHYSICAL CHEMISTRY OF MATERIALS     
Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption
YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China
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Abstract  

Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane (BTME) as a silica source. E-SNTs were modified with polyethylenimine (PEI) as sorbents for CO2 adsorption. These new composite sorbents were characterized by transmission electron microscopy (TEM), nitrogen adsorption/desorption, Fourier transform infrared (FTIR) spectroscopy, and thermal gravimetric analysis (TGA). We found that 75 ℃ is the optimal temperature for CO2 adsorption. E-SNTs with a 50% (w) PEI loading (E-SNTs-50) exhibited a higher CO2 adsorption capacity (3.32 mmol·g-1) than the other materials. The E-SNTs-based sorbents show better CO2 capture performance than the SBA-15-based sorbents. Additionally, CO2 uptake was further enhanced to 3.75 mmol·g-1 in the presence of moisture. Cyclic CO2 adsorption-desorption test results indicated that the composite sorbents are stable and can be regenerated.



Key wordsMesoporoussilica nanotube      Polyethylenimine      Adsorption      CO2 capture     
Received: 30 December 2013      Published: 12 February 2014
MSC2000:  O643  
Fund:  

The project was supported by the National Natural Science Foundation of China (21203167).

Corresponding Authors: HU Geng-Shen     E-mail: gshu@zjnu.edu.cn
Cite this article:

YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei. Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO2 Adsorption. Acta Phys. Chim. Sin., 2014, 30(4): 789-796.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201402123     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2014/V30/I4/789

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