ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(5)>> 923-931     doi: 10.3866/PKU.WHXB201403051         中文摘要
Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO2/CNTs-NH2 for the Synthesis of Methanol from Carbon Dioxide Hydrogenation
WANG Guan-Nan1, CHEN Li-Min1,2, GUO Yuan-Yuan1, FU Ming-Li1, WU Jun-Liang1, HUANG Bi-Chun1,2, YE Dai-Qi1,2
1 Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, P. R. China;
2 College of Environment and Energy, South China University of Technology, Guangzhou 510006, P. R. China
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A series of Cu/ZrO2/CNTs-NH2 catalysts with various chromium dopings were prepared using a coprecipitation method for the synthesis of methanol by the hydrogenation of CO2. The impact of the addition of chromium on the catalytic performance of the Cu/ZrO2/CNTs-NH2 catalyst was investigated in a fixed-bed plug flow reactor. When the chromium loading was set to 1% of the total amount of Cu2+ and Zr4+, the methanol yield increased to a maximum of 7.78% (reaction conditions: 3.0 MPa, 260 ℃, V(H2):V(CO2):V(N2)=69:23:8 and gaseous hourly space velocity (GHSV)=3600 mL·h-1·g-1). The catalysts were characterized by N2 physisorption, X-ray diffraction (XRD), temperature-programmed desorption of H2 (H2-TPD), X-ray photoelectron spectroscopy (XPS), temperature- programmed desorption of CO2 (CO2-TPD), differential thermal analysis (DTA), and scanning electron microscopy (SEM). The results of these analyses indicated that the introduction of chromium reduced the size of the Cu nanoparticles, enhanced the dispersion of the Cu species, inhibited the phase transformation and sintering of ZrO2, increased the specific surface area, enhanced the amount of CO2 adsorbed, and promoted the conversion of weakly adsorbed CO2 species to strongly adsorbed CO2 species. Taken together, these factors lead to a high methanol yield. However, when the chromium loading was greater than 1%, the amount Cu and Zr on the surface, as well as the size of the Cu nanoparticle reduced considerably, which led to a significant reduction in the adsorption of CO2 species. This effect also facilitated the formation of strongly adsorbed CO2 species, leading to lower methanol yields.

Keywords: CNTs-NH2   Chromium   Copper   Zirconia   Methanol synthesis   Carbon dioxide hydrogenation  
Received: 2014-01-08 Accepted: 2014-03-03 Publication Date (Web): 2014-03-05
Corresponding Authors: CHEN Li-Min, YE Dai-Qi Email:;

Fund: The project was supported by the National Natural Science Foundation of China (21207039, 51108187, 0978103), Natural Science Foundation of Guangdong Province, China (S2011010000737), Specialized Research Fund for the Doctoral Program of Higher Education, China (20110172120017), and Scientific Research Foundation for Returned Scholars, Ministry of Education of China (2012).

Cite this article: WANG Guan-Nan, CHEN Li-Min, GUO Yuan-Yuan, FU Ming-Li, WU Jun-Liang, HUANG Bi-Chun, YE Dai-Qi. Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO2/CNTs-NH2 for the Synthesis of Methanol from Carbon Dioxide Hydrogenation[J]. Acta Phys. -Chim. Sin., 2014,30 (5): 923-931.    doi: 10.3866/PKU.WHXB201403051

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55. HU Jian-Ping, WANG Jun, TANG Dian-Yong, FU Qin-Chao, ZHANG Yuan-Qin.Reaction Mechanisms of CO Oxidation Catalyzed by Binary Copper Group Cluster Anions[J]. Acta Phys. -Chim. Sin., 2011,27(02): 329-336
56. ZHENG Jing-Wu, LU Guo-Ying, QIAO Liang, JIANG Li-Qiang, JIANG Mei-Yan.Copper Electrodeposition from Non-Cyanide Alkaline Baths Containing Methylene Diphosphonic Acid as a Complexing Agent[J]. Acta Phys. -Chim. Sin., 2011,27(01): 143-148
57. LU Xue-Bin, GUO Zhao-Hui, HUANG Rong, CHEN Ming-An.Preparation of a (3-Mercaptopropyl)triethoxylsilane Film on Copper and Its Corrosion Protective Performance[J]. Acta Phys. -Chim. Sin., 2011,27(01): 108-112
58. WANG Rui, BAI Yan, LIANG Zhi-Hong, LIU Ying, HUANG Li-Li, ZHENG Wen-Jie.Interaction between Selenomethionine and Copper Ions[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3225-3229
59. XIE Xiu-Juan, CHEN Wen-Kai, SUN Bao-Zhen, GUO Xin, ZHANG Yong-Fan.Adsorption Behavior of NO on Cu3Pt(111) Surface[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3047-3051
60. WU Wei-Gang, YANG Fang-Zu, LUO Ming-Hui, TIAN Zhong-Qun, ZHOU Shao-Min.Electrodeposition of Copper in a Citrate Bath and Its Application to a Micro-Electro-Mechanical System[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2625-2632
61. LIU Xiao-Fang, LI Xue-Qiang, YE Wu-Long, ZHOU Bin-Bin, LIU You-Nian.Synthesis of Ferrocenoyl-Labeled Tripeptide Fc-Gly-Pro-Arg(NO2)-OMe and Its Interaction with Cu(II)[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2381-2386
62. CHAO Wen-Liu, WAN Yong, WANG Yun-Xia, LIU Chang-Song.Tribological Properties of Cu-Doped TiO2 Films[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2317-2322
63. CHE Hong-Wei, HAN Shu-Hua, HOU Wan-Guo, LIU Ai-Feng.Novel Synthesis of Mesoporous Nanocrystalline Zirconia[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2177-2181
64. ZHANG Sheng-Hong, ZHANG Hong-Peng, LI Wei-Zhen, ZHANG Wei, HUANG Hua, LIU Hai-Chao.Effects of Zirconia Crystallite Phases on the Structures of MoOx/ZrO2 Catalysts and Their Properties in the Selective Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1879-1886
65. WANG Xiao-Lei, PAN Xiang-Min, LIN Rui, KOU Su-Yuan, ZOU Wei-Bing, MA Jian-Xin.Dimethyl Ether Steam Reforming for Hydrogen Production over Cu-Ni/γ-Al2O3 Bi-Functional Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1296-1304
66. ZHANG You-Fa, YU Xin-Quan, ZHOU Quan-Hui, LI Kang-Ning.Fabrication and Anti-Icing Performance of a Superhydrophobic Copper Surface with Low Adhesion[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1457-1462
67. YANG Shi-Guo, CHEN Qing-De, SHI Jian-Feng, SHEN Xing-Hai.Controllable Radiolytic Reduction of Cu2+ in Aqueous Solution by β-Cyclodextrin[J]. Acta Phys. -Chim. Sin., 2010,26(04): 805-810
68. ZHANG Tian-Yong, YANG Qiu-Sheng, SHI Hui-Xian, HAN Cong, LIU Xu.Adsorption of Naphthalene on a Viscose-Based Activated Carbon Fiber[J]. Acta Phys. -Chim. Sin., 2010,26(02): 367-372
69. HU Long-Xing, DANG Song-Tao, YANG Xia-Ping.Incorporation of CuO into Mesoporous Carbon CMK-3 and Its Adsorption and Catalytic Oxidation of Phenol[J]. Acta Phys. -Chim. Sin., 2010,26(02): 373-377
70. XU Hui-Yuan, CHU Wei, DENG Si-Yu.Preparation of Copper-Cobalt-Silicon Catalysts for Higher Alcohol Synthesis by Glow Discharge Plasma[J]. Acta Phys. -Chim. Sin., 2010,26(02): 345-349
71. LI Shu-Bai, NIE Hua-Li, ZHANG Hai-Tao, XUE Yong, CHRIS Branford White, ZHU Li-Min.Inhibitory Kinetics of a Trifluoromethyl-Containing 1,2,3-Triazole Derivative on Mushroom Tyrosinase Activity[J]. Acta Phys. -Chim. Sin., 2010,26(01): 215-220
72. TIAN Ying, WU Yan-Bo, WANG Jing-Ri, YANG Feng-Lin.Catalytic Reduction of Cu(II) by Polypyrrole[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2249-2255
73. LI Ben-Xia, WANG Yuan-Yuan, WANG Yan-Fen.Facile Synthesis and Photocatalytic Property of CuO Nanostructure Arrays[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2366-2372
74. LIAO Qiang-Qiang, YUE Zhong-Wen, ZHU Zhong-Wei, WANG Yi, ZHANG Yu, ZHOU Guo-Ding, ZHOU Qi.Corrosion Inhibition Effect of Self-Assembled Monolayers of Ammonium Pyrrolidine Dithiocarbamate on Copper[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1655-1661
75. WANG Xiao-Lei, PAN Xiang-Min, LIN Rui, REN Ke-Wei, KOU Su-Yuan, MA Jian-Xin.Dimethyl Ether Steam Reforming for Hydrogen Production on CuO/ZnO/Y2O3/γ-Al2O3 Bi-Functional Catalyst[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1097-1102
76. FAN Xiao-Yong, ZHUANG Quan-Chao, WEI Guo-Zhen, KE Fu-Sheng, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang.Fabrication and Performance of Cu6Sn5 Alloy Anode Using Porous Cu as Current Collector[J]. Acta Phys. -Chim. Sin., 2009,25(04): 611-616
77. YANG Hong-Yan, GUO Pan-Pan, LI Wei-Shan.Electrodeposition Preparation and Activity of CO-Resistant Catalyst Pt-HxWO3 for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(04): 719-723
78. XU Qun-Jie; LI Chun-Xiang; ZHOU Guo-Ding; ZHU Lv-Jun; LIN Chang-Jian.Copper Corrosion Inhibition and Adsorption Behavior of 3-Amino-1,2,4-triazole[J]. Acta Phys. -Chim. Sin., 2009,25(01): 86-90
79. HUANGFu, Shu-Jun, WANG Jia, HAN Xia, HU Jie-Zhen, ZHENG Ying-Ying.Electrochemical Distribution Behavior of the Galvanic Corrosion of Brass-16Mn Steel Couple in Aqueous NaCl Solution[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2275-2281
80. LI Wei-Zhen, LIU Hai-Chao.Solvent Effects on the Solvothermal Synthesis of PureMonoclinic and Tetragonal Zirconia Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2172-2178
81. LU Yong-Hong; XU Hai-Bo; WANG Jia; KONG Xiang-Feng; JIANG Jing.Size Effect on the Corrosion Behavior of Copper Wires in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1907-1911
82. LIU Ding, XU Yi-Ming.Reaction Mechanism on the Synergistic Photodegradation of Dye X3B and Photoreduction of Dichromate in the Presence of Polyoxometalate[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1584-1588
83. ZHENG Jing-Wu; JIANG Mei-Yan; QIAO Liang; JIANG Li-Qiang; SHENG Jia-Wei; ZHANG Cheng.Influence of CO2-3 on Copper Electrodeposion from 1-Hydroxyethylidene-1,1-diphosphonic Acid Baths[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1733-1738
84. XU Qun-Jie; ZHU Lv-Jun; CAO Wei-Min; WAN Zong-Yue; ZHOU Guo-Ding; LIN Chang-Jian.Inhibition Action and Adsorption Behavior of Environment-Friendly Inhibitor Poly-Aspartate on Copper[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1724-1728
85. YU Hui-Cheng; CHEN Bai-Zhen; SHI Xi-Chang; LI Bing; WU Hai-Ying.Preparation and Electrochemical Properties of Trivalent Chromium Coating on 6063 Aluminium Alloy[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1465-1470
86. LEE Shih-Fong, CHANG Yung-Ping, LEE Li-Ying.Enhancement of Field Emission Characteristics for Multi-Walled Carbon Nanotubes Treated with a Mixed Solution of Chromic Trioxide and Nitric Acid[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1411-1416
87. ZHANG Rui-Min; FAN Guang-Yin; LI Cheng; WANG Ying-Ying; LI Rui-Xiang; CHEN Hua; LI Xian-Jun.Hydrogenation of Quinoline over Ru/ZrO2·xH2O[J]. Acta Phys. -Chim. Sin., 2008,24(06): 965-970
88. GU Qin; REN Xiang-Xiang; LE Xue-Yi.Interaction of 1,4,8,9-Tetraazatriphenylene-Copper (II)-L-Serinate (L-Argininate) Complexes with DNA[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1068-1072
89. XU Hui-Yuan; CHU Wei; SHI Li-Min; ZHANG Hui; ZHOU Jun.Preparation of Copper-Cobalt Catalyst by Glow Discharge Plasma for Lower Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1085-1089
90. ZHU Lv-Jun; XU Qun-Jie; CAO Wei-Min; WAN Zong-Yue; ZHOU Guo-Ding; LIN Chang-Jian.Photoelectrochemical Study on the Complex of PASP and Tungstate as Inhibitors of Cupronickel B10’s Corrosion[J]. Acta Phys. -Chim. Sin., 2008,24(05): 805-809
91. GAN Ning; WANG Lu-Yan; LI Tian-Hua; WANG Feng; JIANG Qian-Li.Preparaton and Electrocatalytic Activities of Nano Pt/Dimercaptosuccinic Amide Copper Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(05): 915-920
92. ZHANG Xiu-Juan; LIU Rui-Quan; WANG Xian-Qun.Inhibition Action and Adsorption Behavior of POTAS and PDTAS on Copper in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 2008,24(02): 338-344
93. XU Qun-Jie; WAN Zong-Yue; YIN Ren-He; ZHU Lu-Jun; CAO Wei-Min; ZHOU Guo-Ding; LIN Chang-Jian.Inhibition Action of the Self-Assembled Monolayers of 3-Amino-1,2,4-triazole on Brass[J]. Acta Phys. -Chim. Sin., 2008,24(01): 115-120
94. HU Jing; YANG Mei-Ni; LU Feng-Ting; DING Li-Ping; ZHANG Shu-Juan; FANG Yu.Monolayer Assembly of Pyrene on Glass Plate Surface and Its Selective Sensing Performances to Organic Copper (II) Salts[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1839-1845
95. SUN Ming-Ming; ZHANG Shi-Chao.Preparation and Performance of a Three-dimensional Nano-Sn/SnSb Composite Anode for LithiumIon Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1937-1942
96. WANG Yi; JIANG Wei; CHENG Zhi-Peng; ZHANG Xian-Feng; AN Chong-Wei; SONG Xiao-Lan; LI Feng-Sheng.Thermal Performance Investigation of Core-Shell Cu/Al Micron-Nano Composites with WO3[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1753-1759
97. MA Li-Wen; CHEN Bai-Zhen; HE Xin-Kuai.Mechanismof Cr(III) Electrodeposition in Carboxylic Acid-Urea System[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1607-1611
98. ZHAO Yan; LIN Chang-Jian; LI Yan; DU Rong-Gui; WANG Jing-Run.Electrochemical Corrosion Behavior of Copper Clad Laminate in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1342-1346
99. BULGAN G.; TENG Fei; LIANG Shu-Hui; YAO Wen-Qing; ZHU Yong-Fa.Effect of Cu Doping on the Structure and Catalytic Activity of LaMnO3 Catalyst[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1387-1392
100. XU Hui-Yuan; CHU Wei; CI Zhi-Min.Effect of Glow Discharge Plasma on Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1042-1046
101. FAN Xiao-Yong; ZHUANG Quan-Chao; JIANG Hong-Hong; HUANG Ling; DONG Quan-Feng; SUN Shi-Gang.Three-dimensional Porous Cu6Sn5 Alloy Anodes for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(07): 973-977
102. HE Yong-Jun; YU Xiang-Yang; ZHAO Xiao-Ling.Surface Modification and Assembly of Cu2(OH)2CO3 Microspheres[J]. Acta Phys. -Chim. Sin., 2007,23(05): 774-778
103. WANG Xian-Qun;LIU Rui-Quan;ZHU Li-Qin;GONG Jian-Wei.Inhibition Action and Adsorption Behaviors of BIT, BIOHT and BIMMT on Copper in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 2007,23(01): 21-26
104. QIU Kai-Dong;LI Wei-Bin.Adsorption of Hexavalent Chromium Ions on Multi-wall Carbon Nanotubes in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1542-1546
105. YANG Fang-Zu;YANG Bin;LU Bin-Bin;HUANG Ling;XU Shu-Kai;ZHOU Shao-Min .Electrochemical Study on Electroless Copper Plating Using Sodium Hypophosphite as Reductant[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1317-1320
106. JIA Li-Tao;FANG Ke-Gong;CHEN Jian-Gang;SUN Yu-Han .Effect of Pretreatment Atmosphere on the Structure of the Co-ZrO2 Catalyst Prepared by Precipitation Method[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1404-1408
107. SHEN Yong;WU Quan-Zhou;LI Yu-Guang.Three Dimensional Ordered Macroporous ZrO2 Prepared by Directly Calcining ZrOCl2[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1121-1125
108. YUAN Jie; ZHANG Xing-tang; JIANG Xiao-hong; LI Yun-cai; HUANG Ya-bin; DU Zu-liang.Preparation and Configuration of Copper Phthalocyanine LB Films[J]. Acta Phys. -Chim. Sin., 2005,21(09): 983-987
109. DENG Chao; SHI Peng-fei; ZHANG Sen.Effect of Nanometer CuO Additive on the Performance of Hydrogen Storage Alloy Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(08): 920-924
110. JIA Yu-Xiang; GUO Xiang-Yun.Monte Carlo Simulation of Adsorption Process of CO and H2 in Supercritical Fluids[J]. Acta Phys. -Chim. Sin., 2005,21(03): 306-309
111. MA Zhong-Yi;YANG Cheng;DONG Qing-Nian;WEI Wei;LI Wen-Huai;SUN Yu-Han.A Study of CO2/H2 Adsorption on Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2005,21(02): 225-228
112. LIU Jian;ZHAO Zhen;XU Chun-Ming.The Structures of VOx/ZrO2 and K-VOx/ZrO2 Catalysts and Their Catalytic Performances for Diesel Soot Oxidation[J]. Acta Phys. -Chim. Sin., 2005,21(02): 156-160
113. Liu Chang-Jian;Zhang Yi1.Phase Diagram Analysis of the Carbonation Process of Sodium Chromate and Ammonia Solution[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1335-1338
114. Li Song-Mei;Chen Dong-Mei;Liu Jian-Hua.

Preparation and Electromagnetic Performance of Cu/T-ZnO Whiskers Composite Powders by Electroless Copper Plating

[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1389-1393

115. Ma Zhong-Yi;Xu Run;Yang Cheng;Wei Wei;Li Wen-Huai;Sun Yu-Han.Preparation and Surface Properties of Different Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1221-1225
116. Song Ji-Guo;Shen Pei-Kang.Electrochemical Characterization of Copper Paratolylsulfonate[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1216-1220
117. Meng Xiang-Ju;Xiao Feng-Shou.Novel Copper Phosphates with High Catalytic Activities under Mild Conditions[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 939-945
118. Zhu Li-Qun;Zhang Wei.The Codeposition Mechanism and Function of Oil-containing Microcapsule Composite Copper Coating[J]. Acta Phys. -Chim. Sin., 2004,20(08): 795-800
119. Kong De-Sheng;Li Liang.The Semiconducting Properties of Oxide Films Formed on Chromium Studied by Capacitance Measurement[J]. Acta Phys. -Chim. Sin., 2004,20(06): 631-636
120. Yun Hong;Chen Jian-Hua;Zhang Hui;Lin Jing-Dong;Chen Hong-Bo;Lin Chang-Jian.The Effects of ZrO2 on Cu-ZnO-ZrO2 Catalysts for Hydrogen Generation by Steam Reforming of Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(05): 550-553
121. Yun Hong;Zhang Hui;Chen Jian-Hua;Chen Hong-Bo;Lin Chang-Jian.The Intermediate State and Mechanism of the Steam Reforming of Methanol over CuO-ZnO-ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(05): 524-528
122. Liu Shou-Xin;Sun Cheng-Lin.Mechanism of Silver Modification for the Enhanced Photocatalytic Activity of Cr(VI) Reduction on TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2004,20(04): 355-359
123. Liu Cai-Hong;Li Hong;Zhu Wei.The Interaction of Cu(phen)22+ with 6-mercaptopurine on a Rotating Platinum Disk Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(04): 440-444
124. Zeng Li;Wang Chun-Ming;Wei Ji-Ying;Zhu Yue-Xiang;Xie You-Chang.Preparation and Characterization of CrOx/ZrO2 with High Thermal Stability and High Specific Surface Area[J]. Acta Phys. -Chim. Sin., 2004,20(03): 251-255
125. Gu Xin;Hu Guang-Hui;Wang Zhou-Cheng;Lin Chang-Jian.In situ Investigation on the Behavior of Mixed Potential in Electroless Copper Plating[J]. Acta Phys. -Chim. Sin., 2004,20(02): 113-117
126. Liu Jin-Ku;Wu Qing-Sheng;Ding Ya-Ping.Controlled Synthesis and Photics Properties of Nanorods of PbCrO4 and BaCrO4 with Artificial Active Membrane as Template[J]. Acta Phys. -Chim. Sin., 2004,20(02): 221-224
127. Zhang Hui;Meng Fan-Cheng;Yang Jun-Feng;Fang Liang;Liu Han-Xing;Yuan Run-Zhang.Structure and Dielectric Properties of New Niobates Sr5LnTi3Nb7O30[J]. Acta Phys. -Chim. Sin., 2003,19(10): 948-951
128. Wu Shu-Xin;Ma Zhi;Qin Yong-Ning;He Fei;Jia Li-Shan;Zhang Yan-Jun.XPS Study of Copper Doping TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2003,19(10): 967-969
129. Zhang Tao;Zhang Xiao-Ru;Wu Ai-Ling;Guan Li;Xu Chang-Ye.Molecular Dynamics Simulations of the Heating and Melting Processes of Metal Cu[J]. Acta Phys. -Chim. Sin., 2003,19(08): 709-713
130. Liao Chuan-Ping;Gu Ming-Yuan.Mechanism for the Reduction of Dichromate in the Polymerization of Aniline[J]. Acta Phys. -Chim. Sin., 2003,19(07): 580-583
131. Zhao Yong-Sheng;Pang Zheng-Zhi.The Action Mechanism of MMI as Corrosion Inhibitor of Copper for Hydrochloric Acid Pickling[J]. Acta Phys. -Chim. Sin., 2003,19(05): 419-422
132. Cheng Hu-Min;Ma Yu-Rong;Liao Fu-Hui;Ma Ji-Ming;Qi Li-Min.Synthesis of Mesoporous Zirconia with Hydrothermal Homogeneous Precipitation Method[J]. Acta Phys. -Chim. Sin., 2003,19(04): 326-328
133. Fang Liang;Zhang Hui;Yan Jun-Bing;Yang Wei-Ming.Structure and Dielectric Properties of New Tantalates Ba2LaTi2Ta3O15 (Ln=Y, La)[J]. Acta Phys. -Chim. Sin., 2003,19(01): 82-84
134. Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei.Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(01): 65-69
135. Nan Zhao-Dong;Tan Zhi-Cheng;Sun Li-Xian.Low Temperature Heat Capacities and Thermodynamic Functions of Potassium Dichromate[J]. Acta Phys. -Chim. Sin., 2002,18(10): 947-951
136. Huang Ling;Zhang Rui;Gu Min;Yang Fang-Zu;Xu Shu-Kai;Zhou Shao-Min.Effects of Nicotinic Acid on Copper Electrodeposition in Acid Sulphate[J]. Acta Phys. -Chim. Sin., 2002,18(07): 665-668
137. Li Xue-Liang;Lu Dao-Yong;He Jian-Bo;Wang Hua-Lin.The Time Delay Control of Current Oscillation of Potentiostatic Anodic Dissolution of Copper[J]. Acta Phys. -Chim. Sin., 2002,18(03): 218-222
138. Wei Wu-Ji;Fu Hai-Tao;Li Ying;Zhu Yi-Fan.SERS Study on Adsorption of AMT on Bronze[J]. Acta Phys. -Chim. Sin., 2002,18(02): 152-155
139. Yang Xu-Fei;Li Wei-Bin.Preparation of Zirconia Zanoparticles in Reverse Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(01): 5-9
140. Lei Jing-Lei;Li Ling-Jie;Cai Sheng-Min;Zhang Sheng-Tao;Li Di;Yang Mai-Zhi.Effect of Cl- on the Corrosion Behavior of Copper Electrode in Weak-alkaline Medium[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1107-1111
141. Li Ying;Gong Jiang-Hong;Tang Zi-Long;Xie Yu-Sheng.Temperature-Independent Activation Energy for Ionic Conduction of Zirconia Based Solid Electrolytes[J]. Acta Phys. -Chim. Sin., 2001,17(09): 792-796
142. Zhang Hui;Fang Liang;Yuan Run-Zhang.Structure and Dielectric Properties of A New Tantalate Ba3TiTa4O15[J]. Acta Phys. -Chim. Sin., 2001,17(08): 747-749
143. Zhou Guo-Ding;Kamkin A N;Liao Qiang-Qiang.Photoelectrochemical Study of Copper-Nickel and Copper-Cobalt Electrodes in Alkaline Solution[J]. Acta Phys. -Chim. Sin., 2001,17(07): 614-618
144. Fu Hai-Tao;Li Ying;Wei Wu-Ji;Zhu Yi-Fan.The Inhibition of AMT on Bronze Corrosion in 5% Citric Acid[J]. Acta Phys. -Chim. Sin., 2001,17(07): 604-608
145. Zhao Feng;Liu Ying-Jun;Li Neng;Lin Bing-Xiong.CO-NO Reaction over ABO2 Complex Oxides with Dalofossite Structure[J]. Acta Phys. -Chim. Sin., 2001,17(06): 511-515
146. Fang Liang;Zhang Hui;Wu Bo-Lin;Yuan Run-Zhang.Structural and Dielectric Properties of a Niobate Ba3NaBiNb10O30[J]. Acta Phys. -Chim. Sin., 2001,17(05): 457-459
147. Shi Wei-Liang;Chen De-Yu.Synthesis and EPR Spectra of Cu(Ⅱ) Complexe with Salicylidene Tyrosine Schiff Base[J]. Acta Phys. -Chim. Sin., 2001,17(02): 181-184
148. Gao Bai-Jiao, Gao Jian-Feng, Jiang Hong-Mei, Zhang Zhong-Xing.Plating Structure and Antioxygention of Micron Cu-Ag Bimetallic Powder[J]. Acta Phys. -Chim. Sin., 2000,16(04): 366-369
149. Liang Jian, Huang Hui-Zhong, Liu Zai-Wei, Wang Zhuo.SEELFS Study on Surface Structure of Several Substances[J]. Acta Phys. -Chim. Sin., 2000,16(02): 101-104
150. Cui Jin-Lan, Zhang Yi, Liu Chang-Jian.Phase Diagrams of Na2CrO4-(NH4)2CrO4-H2O System[J]. Acta Phys. -Chim. Sin., 2000,16(01): 70-75
151. Gao Xiao-Hui, Li Jie, Xiao Shen-Xiu, Chen Tian-Lang.Structure and Superconductivity of 1223 Phase in F-doped Hg-based Superconductor[J]. Acta Phys. -Chim. Sin., 1999,15(10): 877-882
152. Wu Gui-Sheng, Ren Jie, Sun Yu-Han.The Effect of Calcination Temperature on The Performance of Cu/ZrO2 and Cu-La2O3/ZrO2[J]. Acta Phys. -Chim. Sin., 1999,15(06): 564-567
153. Zheng Kang-Cheng, Chen Zhong-Ning, Huang Jia-Duo, Liu Han-Qin.Ab Initio Calculation on Oxamidato-bridged Binuclear Copper(II) Complex as Structural Unit[J]. Acta Phys. -Chim. Sin., 1999,15(03): 204-209
154. Zhang Ji-Jun, Liu Ying-Jun, Li Neng, Lin Bing-Xiong.Synergistic Effect between CuO and CeO2 for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(01): 15-21
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156. Guo Ming-Lin, Zhang Yu-Ting.Preparation of Uniform Particles of Copper(II) and Chromium(VI) Compounds[J]. Acta Phys. -Chim. Sin., 1998,14(10): 877-880
157. Yang Ru, Hu Tian-Dou, Liu Tao, Xiang Hong-Wei, Zhong Bing, Xu Yao, Wu Dong.Characterization of CuO-BaO/SiO2 Catalysts Structure[J]. Acta Phys. -Chim. Sin., 1998,14(07): 590-596
158. Chen Hong-Bo, Yu La-Jia, Liao Dai-Wei, Lin Guo-Dong, Zhang Hong-Bin, Cai Qi-Rui.The Effect of Cr2O3 over Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(06): 534-539
159. Li Ying, Cao Chu-Nan, Lin Hai-Chao, Zhu Yi-Fan, Li Da-Gang, Shi Bing-Bing, Wan Li, Xu Fei, Tao bao-Cheng.Study on the Protection Film of AMT Formed on Bronze by Scanning Tunneling Microsecopy[J]. Acta Phys. -Chim. Sin., 1998,14(04): 365-368
160. Wang Gui-Chang, Sun Yu-Han, Zhong Bing.Simulation to the Structure Sensitive of Cu Based catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 337-342
161. Zhou Zhi-Fen, Lin Hua-Kuan, Li Su-Qi, Zhu Shou-Rong, Chen Rong-Ti.Study of Thermochemical Properties of Cu(II)-α,α'-bipyridyl-macrocyclic Dioxotetraamine Ternary Systems[J]. Acta Phys. -Chim. Sin., 1998,14(04): 343-348
162. Gan Li-Hua, Yue Tian-Yi, Chen Long-Wu, Li Guang-Ming, Zhu Da-Zhang, Zhou En-Xuan.Studies on the Preparation of Cupric Oxalate Uniform Colloidal Particles by the Method of Microemulsion Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(02): 97-102
163. Zhou Ren-Xian, Chen Fang, Jiang Xiao-Yuan, Zheng Xiao-Ming.The Dispersed States of Manganese Species on Mn-O/ZrO2 Catalysts and its Influents on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1998,14(02): 178-180
164. Zhang Ping, Hu Xiao-Li, Chen De-Yu.EPR Spectral Studies of Cu(II) Complexes with Methionine Schiff Bases[J]. Acta Phys. -Chim. Sin., 1998,14(01): 73-77
165. Hou Xiang-Lin,Gao Yin-Ben,Chen Song-Ying.Temperature-Programmed Sulfiding Studies of Cu-based H2S Sorbents[J]. Acta Phys. -Chim. Sin., 1997,13(11): 1044-1048
166. Zheng Hua-Gui,Li Ya-Dong,Li Cheng-Wei,Zhao Hua-Zhang,Liu Yuan-Hui,Qian Yi-Tai.Prepration of Copper Colloid and it's Absorption Spectrum[J]. Acta Phys. -Chim. Sin., 1997,13(11): 974-977
167. Qi Xue-Yong,Wang Ya-Juan,Yang Kong-Zhang.XRD Studies on the Interaction between CrO3 and NaY、NaM Zeolites[J]. Acta Phys. -Chim. Sin., 1997,13(10): 938-941
168. Lin Hua-Kuan,Zhu Shou-Rong,Appolin,B.Kondiano,Kou Fu-Ping,Chen Rong-Ti.Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems[J]. Acta Phys. -Chim. Sin., 1997,13(05): 417-424
169. Ding Han-Ming,Yuan Xun-Dao,Zhang Yin,Xi Shi-Quan.Study of Multiple Films of Copper Phthalocyanine Embedded SnO2 Ultrafine Particles[J]. Acta Phys. -Chim. Sin., 1997,13(05): 413-416
170. Fu Hong-Xiang,Lv Gong-Xuan,Li Shu-Ben.Photocatalytic Reduction of Cr6+ ion in the Presence of Organics[J]. Acta Phys. -Chim. Sin., 1997,13(02): 106-112
171. Wang Rui,Jin Xin-Yu,Cheng Kang-Sheng,Liang Su-Zhen.Study of Organic Silicon Protection Film by Magnetic-Controlling Plasma Polymerization on the Y-Ba-Cu-O Superconductor[J]. Acta Phys. -Chim. Sin., 1996,12(09): 769-772
172. Zhuang Hong-Hui,Wu Ding-Ming,Huang Jian-Quan,Huang Jin-Ling.Synthesis and Crystal Structure of [Cu4Cl4(TTTA)2][J]. Acta Phys. -Chim. Sin., 1996,12(08): 761-765
173. Wang Ya-Juan,Qi Xue-Yong,Li Xiao-Yan.Studies on the Non-isothermal Kinetics of Thermal Decomposition of Benzimidazolyl-bontaining Dicopper(I) Complexes[J]. Acta Phys. -Chim. Sin., 1996,12(07): 668-672
174. Lin Cheng-Zhi,Cai Xiao-Hai,Xie You-Chang.Study of Dispersion State of CuCl2 onto the Surface of NaY Zeolite[J]. Acta Phys. -Chim. Sin., 1996,12(06): 523-526
175. Zhou Ren-Xian,Chen Ping,Zheng Xiao-Ming,Chen Lin-Shen.The Lnteraction between Active Phase and Support and the TPR Characteristics on CuO/ZrO2 Catalyst[J]. Acta Phys. -Chim. Sin., 1996,12(05): 464-467
176. Ma Chen-Sheng, Li Hai-Yang, Zhang Xiao-Guang, Bai Ji-Ling, Wang Xiu-Yan, Zhang Gui-Qiu, Wang Li, He Guo-Zhong, Lou Nan-Quan.Production of Copper Oxide Negative Cluster Ions[J]. Acta Phys. -Chim. Sin., 1996,12(02): 185-189
177. Wang Bao-Hui,Wang De-Jun,Cao Yun-Wei,Zhang Jie,Li Tie-Jin.Investigation of Photo-induced Interfacial Charge Transfer of CuPc-modified Q-CdS Ultrafine Particle Films[J]. Acta Phys. -Chim. Sin., 1996,12(02): 177-180
178. Jin Xiang-Lin,Jiang Yi-Jia,Zhang Shi-Wei,Tang You-Qi.Synthesis and Crystal Structure of the Imidazale-bridged Dicopper(II) Complex with Tetraaza Macrocycles[J]. Acta Phys. -Chim. Sin., 1995,11(10): 932-936
179. Liu Shu-Lan,Guo He Tong,Tan Qi-Xian,Cheng Dan-Hong.The Effect of Ce4+ Ion on the Electrodeposition of Metallic Chromium[J]. Acta Phys. -Chim. Sin., 1995,11(10): 921-924
180. Liu Yuan,Zhong Bing,Peng Shao-Yi,Wu Dong,Fan Wen-Hao.The Preparation and Characterization of Ultrafine ZrO2[J]. Acta Phys. -Chim. Sin., 1995,11(09): 781-784
181. Yao Su-Wei,Zhang Guo-Qing,Guo He-Tong,Gong Zheng-Lie.An Investigation on the Process of Laser Induced Electrodeposition of Copper on ρ-type Silicon[J]. Acta Phys. -Chim. Sin., 1995,11(08): 730-733
182. Ji Hong-Wei,Zhang Zheng-Bin,Liu Lian-Sheng,Xin Hui-Zhen.Ionic Strength Effect on Interfacial Interaction between Copper and Illite[J]. Acta Phys. -Chim. Sin., 1995,11(08): 694-698
183. Gu Ren-Ao,Zhang Zhe-Ru,Hu Xiao-Kun,Deng Zheng-Fa.Raman Spectro-Electrochemistry Study of Corrosion on Copper Surface[J]. Acta Phys. -Chim. Sin., 1995,11(05): 473-476
184. Zhang Wen-Min, Dong Ji-Xi, Xiong Yan-Lin.Mechanism of Periodic Presepitation in a Lead Chromate System Containing Agar-agar Gel[J]. Acta Phys. -Chim. Sin., 1995,11(05): 390-394
185. Xu Bo-Qing,Yamaguchi Tsutomu.Characterization of Acid-base Property of ZrO2 by Thermal Desorption:III.Dual Adsorption of Phenol and NH3 or CO2[J]. Acta Phys. -Chim. Sin., 1995,11(04): 337-341
186. Zhou Guo-Ding, Modestov A D, Pan Chuan-Zhi, Yang Mai-Zhi, Cai Sheng-Min.Origin of Photoresponse Transition of Copper Electrode from p-Type to n-Type[J]. Acta Phys. -Chim. Sin., 1995,11(01): 51-55
187. Shan Jin-Huan, Liu Yie-Ying, Wang An-Zhou.Kinetics and Mechanism of Oxidation of α-alanine Bydiperiodatocuprate(III) in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 1994,10(12): 1110-1115
188. Shan Jin-Huan, Liu Tie-Ying.Kinetics and Meckanism of Oxidation of Ethanolamine by Diperiodatocuprate(III)Ion in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 1994,10(10): 947-949
189. Wang Han-Ming, Wang Er-Kang.Cupric (II)-2,2'-Biquinoline Transfer Across the Liquid/Liquid Interface and Kinetics of Complexation[J]. Acta Phys. -Chim. Sin., 1994,10(05): 418-423
190. Feng Yi-Qi, Zhou Guo-Ding.Study on Diffusion Mechanism for Copper in Low-conductivity Solution[J]. Acta Phys. -Chim. Sin., 1994,10(05): 472-475
191. Yu Zhong-De, Zhang Nan, Gao Zhen, Kong Fan-Ao, Zhu Qi-He.The Formation and Photodissociation of Copper-Sulfur Cluster Ions[J]. Acta Phys. -Chim. Sin., 1994,10(02): 97-99
192. Xu Bai-Qing, Yamaguchi Tsutomu, Tanabe Kozo, Liang Juan, Zheng Lu-Bin.Characterization of Acid-base Property of ZrO2 by Thermal Desorption: I. TPD Studies of Acid and Base Probes[J]. Acta Phys. -Chim. Sin., 1994,10(02): 107-113
193. Xu Bai-Qing, Yamaguchi Tsutomu, Tanabe Kozo, Liang Juan, Zheng Lu-Bin.Characterization of Acid-Base Property of ZrO2 by Thermal Desorption: II. Dual Adsorption of NH3 and CO2[J]. Acta Phys. -Chim. Sin., 1994,10(02): 114-120
194. Ji Wei-Jie; Shen Shi-Kong; Li Shu-Ben; Wang Hong-Li.Dispersion State of Ferric Oxide on ZrO2 and its Influence on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1993,9(03): 311-318
195. Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong.The Catalytic Oxidation of Co Over Ba2-xSrxYCu3O7-a[J]. Acta Phys. -Chim. Sin., 1993,9(02): 206-210
196. Pan Chuan-Zhi; Yang Mai-Zhi; Cai Sheng-Min; Zhou Guo-Ding.Influence of Chloride Ions Upon Semiconductor Properties of Oxide Films on Copper and Brass[J]. Acta Phys. -Chim. Sin., 1993,9(01): 99-102
197. Liu Yi-Fan; Yu Hui-Rong; Zhu Chang-Cui; Chen Zong-Qi; Zhang Yu-Ling.The Preparation of Monodisperse Sol of Cu2O[J]. Acta Phys. -Chim. Sin., 1993,9(01): 107-110
198. Zeng Guang-Fu; Guo Xin; Wang Cui-Ying; Lin Yong-Hua; Li Han.Infrared Spectra and Crystal Structure of BIS-(Dimethoxylphosphato) Copper[J]. Acta Phys. -Chim. Sin., 1992,8(06): 778-782
199. Cai Sheng-Min; Kan Jin-Qing; Tian Wei-Fu; Mu Shao-Lin.In-Situ Electroluminescence Study of Copper Electrode Surface[J]. Acta Phys. -Chim. Sin., 1992,8(05): 609-612
200. Fan Chong-Zheng; Wang Chang-Sui; Zhao Hua-Zhang; Wang Sheng-Jun.A Preliminary Approach to the Chemical Kinetics of CuCl Oxidization[J]. Acta Phys. -Chim. Sin., 1992,8(05): 685-689
201. Tan Qi-Xian; Liu Shu-Lan; Cheng Dan-Hong; Guo He-Tong.The Mechanism of Chromium Electrodeposition From Chromic Acid Solution[J]. Acta Phys. -Chim. Sin., 1992,8(04): 571-574
202. Dong Qing-Hua; Kong Wei-He; Wu Bing-Liang.Photoelectrochemical Studies of Intercalation Reaction[J]. Acta Phys. -Chim. Sin., 1992,8(04): 555-557
203. Zhang Yu-Gen; Li Jian-Min.The Electronic Absorption Spectra of Divalent Copper and Nickel Edta Complex Crystals[J]. Acta Phys. -Chim. Sin., 1992,8(02): 251-254
204. Lin Zhong-Hua; Wang Feng-Chun; Tian Zhong-Qun.Inhibition Mechanism of 2-Aminopyrimidine for Copper Corrosion[J]. Acta Phys. -Chim. Sin., 1992,8(01): 87-93
205. Zhao Liang-Zhong.The Chemical Interaction of YBCO High-Tc Superconductor with Oxide Substrate Materials[J]. Acta Phys. -Chim. Sin., 1991,7(06): 648-650
206. Xu Bai-Qing; Liang Juan; Zheng Lu-Bin; Yamaguchi Tsutomua; Tanabe Kozoa.TPD and IR Studies on the Decomposition of Formic Acid Adsorbed on ZrO2[J]. Acta Phys. -Chim. Sin., 1991,7(06): 712-715
207. Zhu Zhi-Ang; Xia Xin; Chen Rong-Ti.Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions[J]. Acta Phys. -Chim. Sin., 1991,7(04): 456-461
208. Jin Xiang-Lin; Tong You-Zhi; Xu Xiao-Jie; Tang You-Qi.The Synthesis and Crystal Structure of Thiocyanate-Bridged Bi-Copper(II) Macrocyclic Complex of 1,4,7,12,15,18-Hexaazacyclodocosane [Cu2(SCN)3(C16H38N6)]2(ClO4)2[J]. Acta Phys. -Chim. Sin., 1991,7(03): 323-328
209. YE Juan, SUN Kai, TAO Min-Long, TU Yu-Bing, XIE Zheng-Bo, WANG Ya-Li, HAO Shao-Jie, XIAO Hua-Fang, WANG Jun-Zhong.Chiral feature of the achiral Copper Phthalocyanine on Bi(111) Surface[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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