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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2014,Vol.30>> Issue(6)>> 1155-1162     doi: 10.3866/PKU.WHXB201401252         中文摘要
CATALYSIS AND SURFACE SCIENCE
Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol
GAO Peng1,2, LI Feng2, ZHAO Ning2, WANG Hui1, WEI Wei1, SUN Yu-Han2,3
1 Center for Greenhouse Gas and Environmental Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, P. R. China;
2 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China;
3 Chinese Academy of Sciences Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, P. R. China
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Cu/Zn/Al/(Zr)/(Y) hydrotalcite-like compounds with Cu:Zn:Al:Zr:Y atomic ratios of 2:1:1:0:0, 2:1: 0.8:0.2:0, 2:1:0.8:0:0.2, and 2:1:0.8:0.1:0.1 were prepared using the coprecipitation method. The mixed oxides were then obtained by the calcination of the precursors at 500 ℃ in air, and subsequently evaluated in terms of their catalytic performance for the synthesis of methanol from the hydrogenation of CO2. The asprepared samples were characterized by X-ray diffraction (XRD), thermogravimetric (TG) analysis, N2 adsorption, reactive N2O adsorption, H2 temperature-programmed reduction (H2-TPR), and H2/CO2 temperature-programmed desorption (H2/CO2 TPD) techniques. The results of these analyses showed that the BET specific surface area increased significantly with the introduction of Zr and Y, which was related to the amount of H2O and CO2 evolved from the precursors during calcination. The Cu specific surface area and Cu dispersion properties increased in the order of Cu/Zn/Al2 revealed that the CO2 conversion was dependent on the Cu specific surface area, and the CH3OH selectivity increased linearly as the proportion of strongly basic sites increased. The introduction of Zr and Y therefore favored the production of methanol and the maximum CH3OH yield was obtained over the Cu/Zn/Al/Zr/Y catalyst.



Keywords: Hydrotalcite-like precursor   Modifier   Cu/Zn/Al catalyst   CO2 hydrogenation   Methanol  
Received: 2014-02-10 Accepted: 2014-04-01 Publication Date (Web): 2014-04-02
Corresponding Authors: ZHAO Ning, WEI Wei Email: zhaoning@sxicc.ac.cn;weiwei@sari.ac.cn

Fund: The project was supported by the National Key Technology Research and Development Program of the Ministry of Science and Technology, China (2013BAC11B02) and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA05010109, XDA05010110, XDA05010204).

Cite this article: GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-Han . Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol[J]. Acta Phys. -Chim. Sin., 2014,30 (6): 1155-1162.    doi: 10.3866/PKU.WHXB201401252

(1) Choudhury, J. ChemCatChem 2012, 4 (5), 609. doi: 10.1002/cctc.201100495
(2) Olah, G. A.; Geoppert, A.; Prakash, G. K. S. Beyond Oil and Gas: the Methanol Economy, 1st ed.;Wiley-VCH:Weinheim, 2006; pp 173-187, 239-245.
(3) Pontzen, F.; Liebner,W.; Gronemann, V.; Rothaemel, M.; Ahlers, B. Catal. Today 2011, 171 (1), 242. doi: 10.1016/j.cattod.2011.04.049
(4) Yang, R. Q.; Yu, X. C.; Zhang, Y.; Li,W. Z.; Tsubaki, N. Fuel 2008, 87 (4-5), 443. doi: 10.1016/j.fuel.2007.06.020
(5) Jun, K.W.; Shen,W. J.; Rao, K. S. R.; Lee, K.W. Appl. Catal. A: Gen. 1998, 174, 231. doi: 10.1016/S0926-860X(98)00195-1
(6) Hong, Z. S.; Cao, Y.; Deng, J. F.; Fan, K. N. Catal. Lett. 2002, 82 (1-2), 37.
(7) Gao, P.; Li, F.; Zhang, L. N.; Zhao, N.; Xiao, F. K.;Wei,W.; Zhong, L. S.; Sun, Y. H. Journal of CO 2 Utilization 2013, 2, 16. doi: 10.1016/j.jcou.2013.06.003
(8) Wang, J.; Chen, H. B.; Yun, H.; Lin, J. D.; Yi, J.; Zhang, H. B.; Liao, D.W. Acta Phys. -Chim. Sin. 2003, 19 (1), 65. [王进, 陈鸿博, 云虹, 林敬东, 易军, 张鸿斌, 廖代伟. 物理化学学报, 2003, 19 (1), 65.] doi: 10.3866/PKU.WHXB20030115
(9) Gao, P.; Li, F.; Zhan, H. J.; Zhao, N.; Xiao, F. K.;Wei,W.; Zhong, L. S.;Wang, H.; Sun, Y. H. J. Catal. 2013, 298, 51. doi: 10.1016/j.jcat.2012.10.030
(10) An, X.; Li, J. L.; Zuo, Y. Z.; Zhang, Q.;Wang, D. Z.;Wang, J. F. Catal. Lett. 2007, 118 (3-4), 264. doi: 10.1007/s10562-007-9182-x
(11) Fernandez, J. M.; Barriga, C.; Ulibarri, M. A.; Labajos, F. M.; Rives, V. Chem. Mater. 1997, 9 (1), 312. doi: 10.1021/cm9603720
(12) Zhang, L. H.; Li, F.; Evans, D. G.; Duan, X. Mater. Chem. Phys. 2004, 87 (2-3), 402. doi: 10.1016/j.matchemphys.2004.06.010
(13) Alejandre, A.; Medina, F.; Salagre, P.; Correig, X.; Sueiras, J. E. Chem. Mater. 1999, 11 (4), 939. doi: 10.1021/cm980500f
(14) Zhang, L. H.; Zheng, C.; Li, F.; Evans, D. G.; Duan, X. J. Mater. Sci. 2008, 43 (1), 237. doi: 10.1007/s10853-007-2167-8
(15) Gao, P.; Li, F.; Zhao, N.; Xiao, F. K.;Wei,W.; Zhong, L. S.; Sun, Y. H. Appl. Catal. A: Gen. 2013, 468, 442. doi: 10.1016/j.apcata.2013.09.026
(16) Shannon, R. D. Acta Crystallogr. A 1976, 32, 751. doi: 10.1107/S0567739476001551
(17) Wu, G. D.;Wang, X. L.; Chen, B.; Li, J. P.; Zhao, N.;Wei,W.; Sun, Y. H. Appl. Catal. A: Gen. 2007, 329, 106. doi: 10.1016/j.apcata.2007.06.031
(18) Velu, S.; Sabde, D. P.; Shah, N.; Sivasanker, S. Chem. Mater. 1998, 10 (11), 3451. doi: 10.1021/cm980185x
(19) Zhang, L. H.; Li, F.; Evans, D. G.; Duan, X. Ind. Eng. Chem. Res. 2010, 49 (13), 5959. doi: 10.1021/ie9019193
(20) Gao, P.; Li, F.; Xiao, F. K.; Zhao, N.; Sun, N. N.;Wei,W.; Zhong, L. S.; Sun, Y. H. Catal. Sci. Technol. 2012, 2 (7), 1447. doi: 10.1039/c2cy00481j
(21) Cheng, J.; Yu, J. J.;Wang, X. P.; Li, L. D.; Li, J. J.; Hao, Z. P. Energy Fuels 2008, 22 (4), 2131. doi: 10.1021/ef8000168
(22) Xu, Z. P.; Zeng, H. C. J. Phys. Chem. B 2000, 104 (44), 10206. doi: 10.1021/jp001963n
(23) Trujillano, R.; Holgado, M. J.; Pigazo, F.; Rives, V. Physica B 2006, 373 (2), 267. doi: 10.1016/j.physb.2005.11.154
(24) Behrens, M.; Kasatkin, I.; Kuhl, S.;Weinberg, G. Chem. Mater. 2010, 22 (2), 386. doi: 10.1021/cm9029165
(25) Gao, P.; Li, F.; Xiao, F.; Zhao, N.;Wei,W.; Zhong, L. S.; Sun, Y. H. Catal. Today 2012, 194 (1), 9. doi: 10.1016/j.cattod.2012.06.012
(26) Guo, X. M.; Mao, D. S.; Lu, G. Z.;Wang, S.;Wu, G. S. J. Catal. 2010, 271, 178. doi: 10.1016/j.jcat.2010.01.009
(27) Guo, X. M.; Mao, D. S.; Lu, G. Z.;Wang, S. Acta Phys. -Chim. Sin. 2012, 28 (1), 170. [郭晓明, 毛东森, 卢冠忠, 王嵩. 物理化学学报, 2012, 28 (1), 170.] doi: 10.3866/PKU.WHXB201228170
(28) Arena, F.; Italiano, G.; Barbera, K.; Bordiga, S.; Bonura, G.; Spadaro, L.; Frusteri, F. Appl. Catal. A: Gen. 2008, 350, 16. doi: 10.1016/j.apcata.2008.07.028
(29) Guo, X.; Mao, D.; Lu, G.;Wang, S.;Wu, G. J. Mol. Catal. A: Chem. 2011, 345 (1-2), 60. doi: 10.1016/j.molcata.2011.05.019
(30) Wilmer, H.; Genger, T.; Hinrichsen, O. J. Catal. 2003, 215, 188. doi: 10.1016/S0021-9517(03)00003-4
(31) Waugh, K. C. Solid State Ionics 2004, 168 (3-4), 327. doi: 10.1016/j.ssi.2003.05.001
(32) Wu, G. D.;Wang, X. L.;Wei,W.; Sun, Y. H. Appl. Catal. A: Gen. 2010, 377, 107. doi: 10.1016/j.apcata.2010.01.023
(33) Liu, Y. X.; Sun, K. P.; Ma, H.W.; Xu, X. L.;Wang, X. L. Catal. Commun. 2010, 11 (10), 880. doi: 10.1016/j.catcom.2010.03.014
(34) Liu, X. M.; Lu, G. Q.; Yan, Z. F.; Beltramini, J. Ind. Eng. Chem. Res. 2003, 42 (25), 6518. doi: 10.1021/ie020979s
(35) Arena, F.; Barbera, K.; Italiano, G.; Bonura, G.; Spadaro, L.; Frusteri, F. J. Catal. 2007, 249, 185. doi: 10.1016/j.jcat.2007.04.003
(36) Gao, L. Z.; Au, C. T. J. Catal. 2000, 189, 1. doi: 10.1006/jcat.1999.2682

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57. DING Xiao-Chun, CHEN Xiu, ZHOU Jian-Hua, WANG Tao, SUN Dun, HE Jian-Ping.Pt-Ni Catalyst Supported on CMK-5 for the Electrochemical Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(03): 711-716
58. ZHAO Yan-Chun, ZHAN Lu, TIAN Jian-Niao, NIE Su-Lian, NING Zhen.N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(01): 91-96
59. GAO Hai-Li, LIAO Shi-Jun, ZENG Jian-Huang, LIANG Zhen-Xing, XIE Yi-Chun.Preparation and Characterization of Platinum-Decorated Ru/C Catalyst with High Performance and Superior Poison Tolerance[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3193-3198
60. TIAN Tao, QIAN Wei-Zhong, TANG Xiao-Ping, YUN Song, WEI Fei.Deactivation of Ag/ZSM-5 Catalyst in the Aromatization of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3305-3309
61. LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang.Effects of CH3OH and NH3 on the Hydrolytic Deamination Mechanismof Adenine[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3067-3072
62. GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen.Properties of SPES/PWA/SiO2 Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2967-2974
63. FU Jing, LIN Rui, LüHong, WANG Xiao-Lei, MA Jian-Xin, QIAO Jin-Li.Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2653-2658
64. YU Xiao-Chun, LIN Ke, HU Nai-Yin, ZHOU Xiao-Guo, LIU Shi-Lin.Effects of Salts on theMicrostructure ofMethanol[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2473-2480
65. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao.Effect of Magnesium Oxide Modification on the Catalytic Performance of Nanoscale HZSM-5 Zeolite for the Conversion of Methanol to Propylene[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2242-2248
66. ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2255-2260
67. XU Qun-Jie, ZHOU Xiao-Jin, LI Qiao-Xia, LI Jin-Guang.Preparation and Electrochemical Properties of Ternary Catalyst PtRuCo/C for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2135-2138
68. ZHAO Rong-Li, LIN Ke, ZHOU Xiao-Guo, LIU Shi-Lin.Solubility of Poly(N-isopropylacrylamide) in Aqueous Methanol from Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1915-1922
69. ZHANG Sheng-Hong, ZHANG Hong-Peng, LI Wei-Zhen, ZHANG Wei, HUANG Hua, LIU Hai-Chao.Effects of Zirconia Crystallite Phases on the Structures of MoOx/ZrO2 Catalysts and Their Properties in the Selective Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1879-1886
70. AN Xiao-Sha, CHEN De-Jun, ZHOU Zhi-You, WANG Qiang, FAN You-Jun, SUN Shi-Gang.Rare Earth Eu Doped PtRu/C Catalysts and Their Properties for Methanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1207-1213
71. LIU Bo-Jie, LI Xue-Yi, CHEN Wei, LIU Ren-Xiao, GE Guang-Lu.Surface Ligand Exchange and Phase Transfer of Iron Oxide Magnetic Nanoparticles[J]. Acta Phys. -Chim. Sin., 2010,26(03): 784-788
72. WU Yan-Ni, LIAO Shi-Jun.Shortened Carbon Nanotubes as Supports to Prepare High-Performance Pt/SCNT and PtRu/SCNT Catalysts for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 669-674
73. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao, LU Guan-Zhong.Effect of Hydrothermal Treatment on the Acidity and Catalytic Performance of Nanosized HZSM-5 Zeolites for the Conversion of Methanol to Propene[J]. Acta Phys. -Chim. Sin., 2010,26(02): 338-344
74. ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2050-2054
75. LANG Bao, LI Xiu-Jin, JI Sheng-Fu, FABIEN Habimana, LI Cheng-Yue.Effect of La Promoter on the Structure and Performance of Ni/SBA-15 Catalyst in the Reforming of Simulated Biogas to Syngas[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1611-1617
76. NI Zhe-Ming, MAO Jiang-Hong, PAN Guo-Xiang, XU Qian, LI Xiao-Nian.Mechanism of Palladium-Catalyzed Methanol Decomposition for Hydrogen Production[J]. Acta Phys. -Chim. Sin., 2009,25(05): 876-882
77. YANG Hong-Yan, GUO Pan-Pan, LI Wei-Shan.Electrodeposition Preparation and Activity of CO-Resistant Catalyst Pt-HxWO3 for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(04): 719-723
78. WANG Jian-She, GUO Xun, SONG Cheng-Ying, WANG Liu-Cheng, ZHAO Jian-Hong, QIU Xin-Ping.Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La2O3 Particles[J]. Acta Phys. -Chim. Sin., 2009,25(04): 767-772
79. XU Lei; WU Shu-Jie; ZHANG Wen-Xiang; JIA Ming-Jun; LIU Gang.Vapour Phase ortho-Selective Alkylation of Phenol with Methanol over Fe-Zr Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(02): 242-246
80. ZHANG Nuo-Wei, HUANG Chuan-Jing, KUANG Fei-Ping, GAO Xiao-Xiao, WENG Wei-Zheng, WAN Hui-Lin.Effect of a Mg Promoter on the Structure and Catalytic Performance of a Co/Mg/HZSM-5 Catalyst for the Partial Oxidation of Methane to Syngas[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2165-2171
81. LI Lai-Cai; WANG Yi-Wei; TIAN An-Min.Adsorption of Methanol on the Pt-Mo(111)/C Surface[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2013-2018
82. CHANG Xiao-Tu, WANG Jian-Ming, SHAO Hai-Bo, WANG Jun-Bo, ZENG Xiao-Xu, ZHANG Jian-Qing, CAO Chu-Nan.Corrosion and Anodic Behaviors of Pure Aluminumin a Novel Alkaline Electrolyte[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1620-1624
83. ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo.Supramolecular Complexation in Water-Methanol Mixtures[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1503-1506
84. LIN Ming-Gui; FANG Ke-Gong; LI De-Bao; SUN Yu-Han.Effect of Zn and Mn Promoters on Copper-Iron Based Catalysts for Higher Alcohol Synthesis[J]. Acta Phys. -Chim. Sin., 2008,24(05): 833-838
85. ZHENG Gen-Wen; GONG Chun-Li; WEN Sheng; XIE Xiao-Lin.Preparation and Performances of Sulfonated Poly(ether imide) and Poly (ether sulfone) Blends for Proton Exchange Membrane[J]. Acta Phys. -Chim. Sin., 2008,24(05): 855-860
86. LIANG Ying; LIAO Dai-Wei.Effects of pH on the PtRu/C Catalyst Prepared by Microwave-assisted Ethylene Glycol Process[J]. Acta Phys. -Chim. Sin., 2008,24(02): 317-322
87. DENG Hui-Ning; WANG Yu-Xin.Preparation and Properties of Proton Conducting Composite Membranes from Sulfonated Poly(phthalazinone ether keton) and Phosphotungstic Acid[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1235-1240
88. XU Hui-Yuan; CHU Wei; CI Zhi-Min.Effect of Glow Discharge Plasma on Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1042-1046
89. ZHENG Hai-Tao; LI Yong-Liang; LIANG Jian-Ying; SHEN Pei-Kang.Methanol Oxidation on Pd-based Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 993-996
90. YAN Zong-Cheng; CHEN Li; WANG Hong-Lin.Glow Discharge Plasma Electrolysis of Methanol Solutions[J]. Acta Phys. -Chim. Sin., 2007,23(06): 835-840
91. LI Lan-Lan; WEI Zi-Dong; YAN Can; LUO Yi-Hui; YIN Guang-Zhi; SUN Cai-Xin.Methanol Oxidation on a Pt ElectrodeModified by Underpotential Deposition of Ru[J]. Acta Phys. -Chim. Sin., 2007,23(05): 723-727
92. ZHAO Wen-Xia; HU Man-Cheng; LI Shu-Ni; JIANG Yu-Cheng; ZHANG Xiao-Lei; HU Lei; CHEN Huai-Jun.The Solubility of Ternary SystemRbBr/CsBr-CH3OH/C2H5OH-H2O at Different Temperatures[J]. Acta Phys. -Chim. Sin., 2007,23(05): 695-700
93. WU Wei; CAO Jie-Ming; CHEN Yu; LU Tian-Hong.Preparation of High-alloying Pt-Ru/CMK-3 Catalysts in THF-H2O-EtOH Ternary Solution System[J]. Acta Phys. -Chim. Sin., 2007,23(04): 559-564
94. ZHANG Cheng-Gen;LI Wen-Zuo;HUANG Ming-Bao.Reaction of Methyl Alcohol with Thionyl Chloride in Solution[J]. Acta Phys. -Chim. Sin., 2007,23(03): 399-403
95. ZHANG Shu-Dong;ZHU Xiang-Jun;WANG Yan;KONG Xiang-He.Multiphoton Ionization Mass Spectrum of Methanol Clusters and Ab Initio Calculations[J]. Acta Phys. -Chim. Sin., 2007,23(03): 379-383
96. DENG Hui-Ning;WANG Yu-Xin .Sulfonated Poly(phthalazinones) Membranes For Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2007,23(02): 187-191
97. HUANG Mian-Yan;CHEN Hua-Yan;GUO Jian-Zhao;WANG Zhi-Tao;XU Li;WANG Yu-Xin.Methanol Resistant Poly(Ether Sulfone)/Sulfonated Poly(Ether Ether Ketone) Blend Proton Exchange Membrane for DMFC[J]. Acta Phys. -Chim. Sin., 2007,23(01): 44-49
98. SHEN Pei-Kang;WANG Sheng-Long;HU Zhi-Yi;LI Yong-Liang;ZENG Rong;HUANG Yue-Qiang.Hydrogen Production by Alcohol Electrolysis[J]. Acta Phys. -Chim. Sin., 2007,23(01): 107-110
99. ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun.Synthesis and Application of Ce-doped Mesoporous TiO2[J]. Acta Phys. -Chim. Sin., 2006,22(05): 532-537
100. CHEN Ling; WANG Xin-dong; GUO Min.The Effect of NdOx as Co-catalyst for the Electro-oxidation of Methanol on PtRu/C[J]. Acta Phys. -Chim. Sin., 2006,22(02): 141-145
101. CHEN Yu; TANG Ya-wen; Kong Ling-yong; LIU Chang-peng; XING Wei; LU Tianhong.Effect of Surface Modification Extent of Carbon Nanotubes on Electrocatalytic Performance of Carbon Nanotubes Supported Pt catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(01): 119-123
102. WANG Zhen-bo; YIN Ge-ping; SHI Peng-fei.The Influence of Three Groups of Pt-Ru/C Catalyst’s Precursors on Its Performance for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1156-1160
103. ZHANG Wen-yu; DONG Qing-nian; ZHAO Ning; WEI Wei; SUN Yu-han.The Reaction Mechanism for the Synthesis of 1-methoxy-2-propanol on MgO Catalyst[J]. Acta Phys. -Chim. Sin., 2005,21(06): 653-657
104. CHEN Yu; TANG Ya-Wen; LIU Chang-Peng; XING Wei; LU Tian-Hong.Research Progress on Proton Exchange Membranes for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(04): 458-462
105. JIA Yu-Xiang; GUO Xiang-Yun.Monte Carlo Simulation of Adsorption Process of CO and H2 in Supercritical Fluids[J]. Acta Phys. -Chim. Sin., 2005,21(03): 306-309
106. Deng Hui-Ning;Li Lei;Xu Li;Wang Yu-Xin.Comparison on Properties of Membranes for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1372-1375
107. Hu Ji-Ming;Zhang Jian-Qing;Zhang Jin-Tao;Cao Chu-Nan.Electrochemical Activities of IrO2 Electrodes in Small Organic Molecules Containing Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2004,20(07): 740-744
108. Yun Hong;Chen Jian-Hua;Zhang Hui;Lin Jing-Dong;Chen Hong-Bo;Lin Chang-Jian.The Effects of ZrO2 on Cu-ZnO-ZrO2 Catalysts for Hydrogen Generation by Steam Reforming of Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(05): 550-553
109. Yun Hong;Zhang Hui;Chen Jian-Hua;Chen Hong-Bo;Lin Chang-Jian.The Intermediate State and Mechanism of the Steam Reforming of Methanol over CuO-ZnO-ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(05): 524-528
110. Peng Cheng;Cheng Xuan;Zhang Ying;Chen Ling;Fan Qing-Bai.Comparison of Methanol Electrooxidation on Carbon Supported Pt and PtRu Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(04): 436-439
111. Zhou Hai-Hui;Jiao Shu-Qiang;Chen Jin-Hua;Wei Wan-Zhi;Kuang Ya-Fei.Electrocatalytic Oxidation of Methanol on Nano-fibular Polyaniline Electrode Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 2004,20(01): 9-14
112. Zhang Xin;Wan Hui-Lin;Weng Wei-Zheng;Yang Le-Fu;Yi Xiao-Dong.Role of Ce on Selective Oxidation of Propane to Acrolein over Ce-Ag-Mo-P-O Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(06): 492-497
113. Xu Run;Ma Zhong-Yi;Yang Cheng;Wei Wei;Sun Yu-Han.Effect of Manganese Promoter on the CuFeZrO2 Catalyst for Higher Alcohols Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(05): 423-427
114. Chen Wei;Sun Shi-Gang;Si Di;Chen Sheng-Pei.Electrocatalytic Properties of Agglomerates of Pt Nanoparticles in Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2003,19(05): 441-444
115. Li Xu-Guang;Han Fei;Xing Wei;Tang Ya-Wen;Lu Tian-Hong.Influence of Methanol on the Kinetics of Oxygen Reduction on Pt/C and CoPcTc/C[J]. Acta Phys. -Chim. Sin., 2003,19(04): 380-384
116. Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei.Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(01): 65-69
117. Zhang Xin-Rong;Shi Peng-Fei.Catalytic Production of Hydrogen from Steam Reforming of Methanol on CeO2 Promoted Cu/Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(01): 85-89
118. Chen Song-Zhe;Zhong Shun-He.The Photo Stimulated Surface Reaction of Synthesis of Methanol from Carbon Dioxide and Water on Cu/TiO2-NiO[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1099-1103
119. Wei Zi-Dong;Miki Atsushi;Ohmori Tadayoshi;Osawa Masatoshi.Methanol Electroxidation on Upd - Sn Modified Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1120-1124
120. Guo Xia;Xu Hui;Guo Rong.The Fluorescence Quenching of Anthracene by Phenothiazine in Sodium Dodecyl Sulfate / Benzyl Alcohol / Water Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(06): 500-503
121. Zhang Jun-Ling;Ren Jie;Chen Jian-Gang;Sun Yu-Han.Effect of Manganese Promoter on the Performance of Co/Al2O3 Catalysts for FischerTropsch Synthesis[J]. Acta Phys. -Chim. Sin., 2002,18(03): 260-263
122. Yang Cheng;Dong Qing-Nian;Zhang Jing;Ren Jie;Sun Yu-Han;Xie Ya-Ning;Hu Tian-Dou.The Structural Effect of CeO2 and La2O3 Modified Pd/γ-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2002,18(02): 170-174
123. Xi Jing-Yu;Wang Zhi-Fei;Wang Wei-Ping;Lü Gong-Xuan.In-situ XPS Study for Reaction Mechanism of Methanol Decomposition over Cu-Ni/Zn Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(01): 82-86
124. Xi Jing-Yu;Lv Gong-Xuan;Wang Zhi-Fei.Partial Oxidation of Methanol to Hydrogen over Cu/Zn and Cu/Zn/Ni Catalysts[J]. Acta Phys. -Chim. Sin., 2001,17(07): 655-658
125. Li Han-Sheng;Zhong Shun-He;Wang Jian-Wei;Xiao Xiu-Fen.Effect of K2O on Properties of Cu-Ni/V2O5-SiO2 Catalyst for the Synthesis of Dimethyl Carbonate[J]. Acta Phys. -Chim. Sin., 2001,17(06): 552-554
126. Chen Jian-Gang;Xiang Hong-Wei;Dong Qing-Nian;Wang Xiu-Zhi;Sun Yu-Han.H2 or CO Chemsorption on Co-based Catalysts for F-T Synthesis[J]. Acta Phys. -Chim. Sin., 2001,17(02): 161-164
127. Zhong Shun-He, Gao Feng, Ye Xiu-Qiang, Xiao Xiu-Fen.Study on Laser Stimulated Surface Reaction of Methanol Oxidative Coupling[J]. Acta Phys. -Chim. Sin., 2000,16(07): 601-607
128. Zhong Shun-He, Li Han-Sehng, Wang Jian-Wei, Xiao Xiu-Fen.Cu-Ni/V2O5-SiO2 Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol[J]. Acta Phys. -Chim. Sin., 2000,16(03): 226-231
129. Zhang Xiao-Gang, Li Yong-Wang, Zhong Bing, Peng Shao-Yi.Molecular Simulation in Hydrogen,Carbon Monoxide,Methanol and Hexane System[J]. Acta Phys. -Chim. Sin., 1999,15(11): 1036-1040
130. Deng Guo-Yang, Jes Henningsen.Quantitative Measurement of Adsorption of CH3OH on Commonly Used Mterials by Photoacoustic Method[J]. Acta Phys. -Chim. Sin., 1999,15(08): 764-768
131. Zhang Rong, Sun Yu-Han, Peng Shao-Yi.Effect of Surface Properties on the Catalytic Performance of Cu/SiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 1999,15(07): 652-656
132. Wu Gui-Sheng, Ren Jie, Sun Yu-Han.The Effect of Calcination Temperature on The Performance of Cu/ZrO2 and Cu-La2O3/ZrO2[J]. Acta Phys. -Chim. Sin., 1999,15(06): 564-567
133. Jin Rong-Chao, Chen Yan-Xin, Li Wen-Zhao, Ji Ya-Ying, Qin Yong-Sheng, Jiang Yi.Ni/α-Al2O3 Catalyst for the Partial Oxidation of Methane to Syngas[J]. Acta Phys. -Chim. Sin., 1998,14(08): 737-741
134. Chen Hong-Bo, Yu La-Jia, Liao Dai-Wei, Lin Guo-Dong, Zhang Hong-Bin, Cai Qi-Rui.The Effect of Cr2O3 over Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(06): 534-539
135. Wang Gui-Chang, Sun Yu-Han, Zhong Bing.Simulation to the Structure Sensitive of Cu Based catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 337-342
136. Li Ji-Tao, Zhang Wei-De, Qu Ze-Tang.Effect of CO on Methanol Synthesis from CO2 Hydrogenation[J]. Acta Phys. -Chim. Sin., 1998,14(03): 275-277
137. Zhong Chong-Min, Wang-De-Zheng, Takashi Ushikubo, Keisuke Wada.The Adsorption of Methanol,Water and Ethylene on a Niobium Oxide Thin Film[J]. Acta Phys. -Chim. Sin., 1998,14(03): 219-225
138. Zhang Xiao-Gang,Guo Xiang-Yun,Zhong Bing,Peng Shao-Yi.Monte Carlo Study of Methanol Clusters in Supercritical Cyclohexane System[J]. Acta Phys. -Chim. Sin., 1997,13(10): 898-903
139. Li Ji-Tao,Gao Li-Zhen,Zhang Wei-De.CO Adsorption and Hydrogenation on Crystalline YBa2Cu3Ox Thin Films[J]. Acta Phys. -Chim. Sin., 1997,13(08): 700-705
140. Yang Hui,Li Chang-Zhi,Lu Tian-Hong,Xue Kuan-Hong,Sun Shi-Gang,Lu Guo-Qiang,Chen.Electrocatalytic Oxidation of Methanol on Polythionine Film Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 1997,13(06): 542-547
141. Chen Kai-Dong,Yan Qi-Jie.Influence of Ceria on the Structure and Catalytic Property of F-T Synthesis Fe/ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 1996,12(11): 990-994
142. Zhang Suo-Jiang,Han Shi-Jun,Jin Yin-Dong.Molar Conductances of NaCl and KCl in Aqueous Methanol Mixtures at 298.15K[J]. Acta Phys. -Chim. Sin., 1996,12(01): 75-80
143. Li Qing-Shui, Lin Yu-Qin, Liao Yuan-Yan.Studies on Catalytic Dehydrogenation of Methanol to Formaldehyde[J]. Acta Phys. -Chim. Sin., 1995,11(05): 442-446
144. Zhang Ya-Ming, Wang Yan-Ru, Shi Jun.Enthalpies of Dilution of Calcium Chloride in Aqueous Solution of Alcohols[J]. Acta Phys. -Chim. Sin., 1994,10(06): 555-559
145. Bian Guo-Zhu; Jiang Ming; Fu Yi-Lu; Ji Ming-Rong.Chemical States and Composition of the Surface Species of K-MoO3/γ-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 1993,9(05): 650-656
146. Zhao Bi-Ying; Wang Qiu-Xia; Tang You-Qi.Study on Dispersion of V2O5 on Surface of SiO2 and the Effect of Promoter K2SO4[J]. Acta Phys. -Chim. Sin., 1993,9(02): 187-192
147. Wang Yi-Xuan; Zhao Jian-Ping; Dai Ming.Vapor-Liquid Equilibrium for Some Polar Aprotic Solvents with Methanol or 1,2-Dichloroethane[J]. Acta Phys. -Chim. Sin., 1992,8(05): 636-641
148. Zhou Zhi-Hua; Hu Wei-Dong; Lu Wen-Qing; Zhou Yi-Ming; Xue Kuan-Hong.Effect of Supporting Electrolyte on the Electrochemical Oxidation Pathways of Anhydrous Methanol at Gold Electrode[J]. Acta Phys. -Chim. Sin., 1992,8(05): 707-711
149. Wang Hai-You; Liu Jin-Bo; Fu Jin-Kun; Cai Qi-Rui.The Mechanism of Syngas Conversion to Ethanol[J]. Acta Phys. -Chim. Sin., 1991,7(06): 681-687
150. Li Xin-Sheng; Hou Zhen-Shan; Wei Zhao-Bin; Xin Qin.Study on Promotion of Cobalt and Ruthenium in Reduced Catalysts for Hydrodesulfurization by IR-Spectroscopy and Chemisorption[J]. Acta Phys. -Chim. Sin., 1991,7(06): 673-680
151. Su Wen-Duan; Zhou Shao-Min; Zhou Xiao-Lin.Statistical Mechanical Treatment of Adsorbed Monolayer at Electrode/Solution Interface III. The Structure of Inner Layer Formed at the Interface of Hg/(H2O+CH3OH) Solution[J]. Acta Phys. -Chim. Sin., 1991,7(04): 443-448
152. CHENG Xiao-Meng, LI Yu, CHEN Zong, LI Hong-Ping, ZHENG Xiao-Fang.A Comparative Study on the NMR Relaxation of Methanol in Sub- and Super-critical Mixtures of CO2 and Methanol[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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